Functionalized polymer networks: synthesis of microporous polymers by frontal polymerization
Source abstract
Abstract
A series of glycidyl methacrylate (GMA)-ethylene dimethacrylate (EGDM) copolymers of varying compositions were synthesized by free-radically triggered thermal frontal polymerization (FP) as well as by suspension polymerization (SP) using azobisisobutyronitrile [AIBN] as initiator. The two sets of copolymers were characterized by IR spectroscopy and mercury intrusion porosimetry, for determination of epoxy number and specific surface area. Frontal polymerization was more efficient, yielding greater conversions at much shorter reaction times. The self-propagating frontal polymerization also generates microporous material with narrow pore size distribution. It yields higher internal pore volume and surface area than suspension polymerization, surface morphologies are, however, inferior.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Photopolymerization techniques and applications · Advanced Photocatalysis Techniques · Pigment Synthesis and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (54)
Show source-provided references
1. Akolekar D B, Hind A R and Bhargava S K 1998J. Colloid. Interface. Sci. 70 1629
2. Bhave R R 1991Inorganic membranes; Synthesis, characteristics and application (New York: Van Nostrand Reinhold)10.1007/978-94-011-6547-1 ↗
3. Chechilo N M and Enikolopyan N S 1975Dokl. Phys. Chem. 221 392
4. Chechilo N M, Khvilivitskii R J and Enikolopyan N S 1972Dokl. Akad. Nauk SSSR 204 1180
5. Davtyan S P,Arutiunian K A, Rozenberge B A and Enikolopyan N S 1975Dokl. Akad. Nauk. 223 687
6. Davtyan S P,Surkov N F, Rozenberge B A and Enikolopyan N S 1976Dokl. Phys. Chem. 228 435
7. Davtyan S P,Surkov N F, Rozenberge B A and Enikolopyan N S 1977Dokl. Phys. Chem. 232 64
8. Davtyan S P, Zirakov P V and Volison S A 1984Russian Chem. Rev. 53 15010.1070/RC1984v053n02ABEH003035 ↗
9. Davtyan S P, Begishev V P, Volpert V A and Molkin A Y 1985Dokl. Akad. Nauk. 279 909
10. Davtyan S P, Volpert V A, Megrabova I M and Begishev V P 1986Combust. Expl. Shockwaves 21 443
11. Davtyan S P, Babadzhahyan A S, Volpert V A and Megrabova I M 1989Combust. Expl. Shockwaves 25 2310.1007/BF00758230 ↗
12. Deleuze H, Schultze X and Sherrington D C 1998Polymer 39 610910.1016/S0032-3861(98)00080-9 ↗
13. Enikolopyan N S, Kozhushner M A and Khaunkaev B B 1974Dokl. Phys. Chem. 217 676
14. Fiori S and Mariani A 2003Macromolecules 36 267410.1021/ma0211941 ↗
15. Fulton S P, Afeyan N B and Regnier F E 1991J. Chromatogr. 547 45210.1016/S0021-9673(01)88671-4 ↗
16. Hamid M A, Naheed R, Fuzail M and Rehman E 1999Eur. Polym. J. 35 179910.1016/S0014-3057(98)00267-5 ↗
17. Hodge P and Sherrington D C 1980Polymer supported reactions in organic synthesis (New York: Wiley)
18. Horak D, Svec F, Ilavsky M, Bleha M, Baldrian J and Kalal J 1981Angew. Makromol. Chem. 95 109, 11710.1002/apmc.1981.050950108 ↗
19. Khaunkaev B B, Kozhushner M A and Enikolopyan N S 1974Dokl. Phys. Chem. 214 84
20. Koike Y, Takezawa Y and Ohtsuka Y 1988Appl. Opt. 27 48610.1364/AO.27.000486 ↗
21. Lee H and Neville K 1967Handbook of epoxy resins (New York: McGraw-Hill Book Company) p. 4
22. Lewandowski K, Murer P, Svec F and Fretchet J M J 1998aAnal. Chem. 70 162910.1021/ac971196x ↗
23. Lewandowski K, Svec F and Fréchet J M J 1998bJ. Appl. Polym. Sci. 67 59710.1002/(SICI)1097-4628(19980124)67:4<597::AID-APP2>3.0.CO;2-F ↗
24. Liang Y C, Svec F and Fréchet J M J 1997J. Polym. Sci. Part A: Polym. Chem. 35 263110.1002/(SICI)1099-0518(19970930)35:13<2631::AID-POLA10>3.0.CO;2-C ↗
25. Masere J, Lewis L L and Pojman J A 2001J. Appl. Polym. Sci. 80 68610.1002/1097-4628(20010425)80:4<686::AID-APP1145>3.0.CO;2-Y ↗
26. Maugh T M 1984Science 223 47410.1126/science.223.4635.474 ↗
27. Mikhail R S and Robens E 1983Microstructure and thermal analysis of solid surfaces (New York: Wiley Hyden Publications Ltd.) p. 161
28. Palm A and Novotny M V 1997Anal. Chem. 69 449910.1021/ac970626g ↗
29. Perry M F, Volpert V A, Lewis L L, Nichols H A and Pojman J A 2003Macromol. Theory Simul. 12 27610.1002/mats.200390028 ↗
30. Pojman J A 1991J. Am. Chem. Soc. 113 628410.1021/ja00016a063 ↗
31. Pojman J A, Craven R, Khan A and West W 1992J. Phys. Chem. 96 746610.1021/j100197a062 ↗
32. Pojman J A, Nagy I P and Salter C 1993J. Am. Chem. Soc. 115 1104410.1021/ja00076a094 ↗
33. Pojman J A, Nagy I P and Sike L 1995aJ. Am. Chem. Soc. 117 361110.1021/ja00117a030 ↗
34. Pojman J A, Willis J, Fortenberry D V, Ilyashenko V M and Khan A 1995bJ. Polym. Sci. Part A: Polym. Chem. 33 64310.1002/pola.1995.080330406 ↗
35. Pojman J A, Curtis G and Ilyashenko V M 1996aJ. Am. Chem. Soc. 118 378310.1021/ja9600688 ↗
36. Pojman J A, Ilyashenko V M and Khan A M 1996bJ. Chem. Soc. Faraday Trans. 92 282510.1039/ft9969202825 ↗
37. Pojman J A, Elcan W, Khan A M and Mathias L M 1997J. Polym. Sci. Part A: Polym. Chem. 35 22710.1002/(SICI)1099-0518(19970130)35:2<227::AID-POLA4>3.0.CO;2-P ↗
38. Pojman J A, Willis J, Fortenberry D V, Ilyashenko V M and Khan A 1998Solvent-free synthesis by free-radical frontal polymerization (eds) T E Long and M O Hunt,ACS Symposium series 713 (Washington, DC: American Chemical Society) p. 140
39. Pojman J A, Willis J, Khan A M and West W W 2000J. Polym. Sci. Part-A: Polym. Chem. 38 112910.1002/(SICI)1099-0518(20000401)38:7<1129::AID-POLA10>3.0.CO;2-A ↗
40. Pojman J A, Popwell S, Fortenberry D I, Volpert V A (I) and Volpert V A (II) 2003Nonlinear dynamics in frontal polymerization (eds) J A Pojman and Q Tran-Cong-Miyata,ACS symposium series 869 (Washington, DC: American Chemical Society) p. 106
41. Pujari N S, Vishwakarma A R, Pathak T S, Mule S A and Ponrathnam S 2004Polym. Int. (to be published)
42. Sherrington D C 1998Chem. Commun. 21 227510.1039/a803757d ↗
43. Svec F and Frechet J M J 1995Macromolecules 28 758010.1021/ma00126a044 ↗
44. Tanev P T, Chibwe M and Pinnavaia T J 1994Nature 368 32110.1038/368321a0 ↗
45. Tennikov M B, Gazdina N V, Tennikova T B and Svec F 1998J. Chromatogr. A798 5510.1016/S0021-9673(97)00873-X ↗
46. Tredici A, Pecchini R and Morbidelli M 1998J. Polym. Sci. Part A: Polym. Chem. 36 111710.1002/(SICI)1099-0518(199805)36:7<1117::AID-POLA11>3.0.CO;2-A ↗
47. Vivaldo-Lima E, Wood P E, Hamielec A E and Penlidis A 1997Ind. Eng. Chem. Res. 36 93910.1021/ie960361g ↗
48. Washington R P and Steinbock O 2001J. Am. Chem. Soc. 123 793310.1021/ja0161103 ↗
49. White S R and Kim C 1992Int. Sample Symp. Exhib. 37 240
50. White S R and Kim C 1993J. Reinforced Plastics Comp. 12 52010.1177/073168449301200503 ↗
51. Wijnhoven J E and Vos W L 1998Science 281 80210.1126/science.281.5378.802 ↗
52. Xie S, Svec F and Frechet J M J 1997J. Chromatogr. A775 6510.1016/S0021-9673(97)00254-9 ↗
53. Yuan H G, Kalfas G and Ray W H 1991J. Macromol. Sci. Rev. Macromol. Chem. Phys. C31 21510.1080/15321799108021924 ↗
54. Zhang Q, Wang P and Zhai Y 1997Macromolecules 30 787410.1021/ma970379i ↗