XRD and optical microscopic studies of Co(III) complexes containing 5-cyano-6-(4-pyridyl)-2-thiouracil, thymine and adenine bases
Source abstract
Abstract
Multifunctional ligand 5-cyano-6-(-4-pyridyl)-2-thiouracil (L) was prepared and allowed to react withtrans [Co(en)2Cl2]+Cl‡ resulting into [Co(en)2LCl]2+.2Cl- which upon further reaction with equimolar ratio of ligand [L] gave the complex [Co(en)2L2]3+.3Cl−. These metal complexes were then separately reacted with thymine and adenine bases. Complexes thus prepared after characterization by their elemental analysis, FAB mass and spectral (IR,1 HNMR, UV-visible) data were studied for their powder X-ray diffraction and optical microscopic characteristics.
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Research context
OpenAlex topics: Metal complexes synthesis and properties · Crystal structures of chemical compounds · X-ray Diffraction in Crystallography
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References (11)
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