Synthesis of hierarchical CuS flower-like submicrospheres via an ionic liquid-assisted route
Source abstract
Abstract
A facile, ionic liquid-assisted route was developed to synthesize hierarchical CuS flower-like submicrospheres at 80°C for 24 h. The method was based on a reaction between CuCl2 and thioacetamide (TAA) in aqueous solution with using ionic liquid 1-n-butyl-3-methylimidazolium chloride ([BMIM]Cl) as an assisted agent. The chemical composition, morphology and size of CuS product were characterized by XRD, SEM and TEM. The result shows that the as-prepared CuS consists of flowery spheres with a diameter of 0·6 ∼ 1·0 μm, and these submicrospheres are, in fact, built by numerous nanoflakes with a thickness of 10 ∼ 20 nm. The optical property of CuS product was examined by UV-Vis. In general, we suggested an ecologically and environmentally friendly route for the syntheses of hierarchical metal chalcogenides structures in this paper.
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Research context
OpenAlex topics: Quantum Dots Synthesis And Properties · Copper-based nanomaterials and applications · Chalcogenide Semiconductor Thin Films
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. Anthony J L, Maginn E J and Brennecke J F 2001 J. Phys. Chem. B105 1094210.1021/jp0112368 ↗
2. Bar G, Parsons A F and Thomas C B 2001 Chem. Commun. 135010.1039/b103544b ↗
3. Cordova R et al 2002 Langmuir 18 864710.1021/la025711k ↗
4. Cui Y and Lieber C M 2001 Science 291 85110.1126/science.291.5505.851 ↗
5. Dixit S G, Mahadeshwar A R and Haram S L 1998 Colloids Surf. A133 6910.1016/S0927-7757(97)00126-X ↗
6. Duan X F, Huang Y, Cui Y, Wang J and Liber C M 2001 Nature 409 6610.1038/35051047 ↗
7. Dzyuba S V and Bartsch R A 2003 Angew. Chem. Int. Ed. 42 14810.1002/anie.200390070 ↗
8. Haram S K, Mahadeshwar A R and Dixit S G 1996 J. Phys. Chem. 100 586810.1021/jp952391n ↗
9. Hardacre C, Holbrey J D, McCormac P B, McMath S E J, Nieuwenhuyzen M and Seddon K R 2001 J. Mater. Chem. 11 34610.1039/b008091h ↗
10. Huang H M et al 2001 Science 292 189710.1126/science.1060367 ↗
11. Huddleston J G, Willauer H D, Swatloski R P, Visser A E and Rogers R D 1998 Chem. Commun. 176510.1039/A803999B ↗
12. Lee C K, Han P H and Lin I J B 2004 Chem. Mater. 16 53010.1021/cm030296i ↗
13. Lee S, Park J H, Kang J and Lee J K 2001 Chem. Commun. 169810.1039/b104967b ↗
14. Liao X H, Chen N Y, Xu S, Yang S B and Zhu J J 2003 J. Cryst. Growth 252 59310.1016/S0022-0248(03)01030-3 ↗
15. Lin Y F and Sun I W 1999 Electronchim. Acta 44 277110.1016/S0013-4686(99)00003-1 ↗
16. Liu B and Zeng H C 2004 J. Am. Chem. Soc. 126 1674410.1021/ja044825a ↗
17. Murray C B, Kagan C R and Bawendi M G 1995 Science 270 133510.1126/science.270.5240.1335 ↗
18. Neve F, Francescangeli O, Crispini A and Charmant J 2001 Chem. Mater. 13 203210.1021/cm000804d ↗
19. Nomura R, Miyawaki K, Toyosaki T and Matsuda H 1996 Chem. Vap. Depos. 2 17410.1002/cvde.19960020504 ↗
20. Parkin I P 1996 Chem. Soc. Rev. 25 19910.1039/cs9962500199 ↗
21. Potdar M K, Mohile S S and Salunkhe M M 2001 Tetrahedron Lett. 42 928510.1016/S0040-4039(01)02041-X ↗
22. Shen G Z, Bando Y and Golberg D 2007 Cryst. Growth Des. 7 3510.1021/cg060224e ↗
23. Tang K B, Chen D, Liu Y F, Shen G Z, Zheng H G and Qian Y T 2004 J. Cryst. Growth 263 23210.1016/j.jcrysgro.2003.11.045 ↗
24. Teng X W and Yang H 2005 Nano. Lett. 5 88510.1021/nl0503072 ↗
25. Tsuda T, Nohira T and Ito Y 2001 Electrochim. Acta 46 189110.1016/S0013-4686(01)00434-0 ↗
26. Visser A E, Swatloski R P, Reichert W M, Griffin S T and Rogers R D 2000 Ind. Eng. Chem. Res. 39 359610.1021/ie000426m ↗
27. Wang H, Zhang H R, Xiao X N, Xu S and Zhu J J 2002 Mater. Lett. 55 25310.1016/S0167-577X(01)00656-5 ↗
28. Wu C, Shi J B, Chen C J, Chen Y C, Lin Y T, Wu P F and Wei S Y 2008 Mater. Lett. 62 107410.1016/j.matlet.2007.07.046 ↗
29. Xie S H and Zhao D Y 2002 Adv. Mater. 14 153710.1002/1521-4095(20021104)14:21<1537::AID-ADMA1537>3.0.CO;2-Q ↗
30. Xu C, Wang L, Zou D B and Ying T K 2008 Mater. Lett. 62 318110.1016/j.matlet.2008.02.014 ↗
31. Xu H L, Wang W Z and Zhu W 2006 Mater. Lett. 60 220310.1016/j.matlet.2005.12.098 ↗
32. Yu S H and Chen S F 2006 Curr. Nanosci. 2 8110.2174/157341306776875767 ↗
33. Yu X L, Cao C B, Zhu H S, Li Q S, Liu C L and Gong Q H 2007 Adv. Funct. Mater. 17 139710.1002/adfm.200600245 ↗
34. Zhang J and Zhang Z K 2008 Mater. Lett. 62 227910.1016/j.matlet.2007.11.069 ↗
35. Zhang Z, Sun H, Shao X, Li D, Yu H and Han M 2005 Adv. Mater. 17 4210.1002/adma.200400401 ↗