A facile synthesis of MInSe2 (M = Cu, Ag) via low temperature pyrolysis of single source molecular precursors, [(R3P)2MIn(SeCOAr)4]
Source abstract
Abstract
The reaction of KSeCOAr with InCl3 and (MCl(PR3)2) in benzene afforded bimetallic complexes, ((R3P)2MIn(SeCOAr)4) (PR3 = PEt3 or PPh3; M = Cu or Ag; Ar = -C6H5 (phenyl) or 4-MeC6H4 (tolyl)). The triethylphosphine complexes decomposed rapidly when M = Ag while slowly when M = Cu. All these com- plexes were characterized by elemental analysis, IR, UV-VIS, NMR ( 1 H, 31 P) spectral data. Pyrolysis in a furnace at 300°C gave tetragonal MInSe2 (M = Cu, Ag) structure. Solvothermal decomposition of ((PPh3)2CuIn(SeCOAr)4) in boiling ethylene glycol gave nanorods of CuInSe2 which were characterized by XRD, EDAX, SEM and TEM.
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Research context
OpenAlex topics: Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties · Nanocluster Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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