journal article·2005-02

Hydrothermal synthesis, structure and characterization of new NASICON related potassium iron (III) pyrophosphate

G. S. Gopalakrishna, B. H. Doreswamy, M. J. Mahesh, M. Mahendra, M. A. Sridhar, J. Shashidhara Prasad, K. G. Ashamanjari

Bulletin of Materials Science· Volume 28· Issue 1
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Abstract

A new potassium iron (III) pyrophosphate was synthesized by hydrothermal technique and characterized by X-ray studies. The compound crystallizes in a monoclinic space group,P2 1/c, with cell parameters,a = 7 365(2) A,b = 10017(2) A,c = 8.214(1) A,β = 106.50(1)° andZ = 4. The structure has tunnel-type cavities and are congenial for ion transportation through them. The compound exhibits moderate thermal stability.
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OpenAlex topics: Inorganic and Organometallic Chemistry · Chemical Synthesis and Characterization · Metal complexes synthesis and properties

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