journal article·2005-05

GC/MS Identification of Pyrolysis Products from Fire-retardant Brominated Epoxy Resin

A. I. Balabanovich, M. P. Luda, L. Operti

Journal of Fire Sciences· Volume 23· Issue 3
Publisher page

Abstract

Brominated epoxy resins cured with diaminodiphenyl sulfone are thermally less stable than nonbrominated analogs. This thermal instability is likely to be caused by the formation of hydrogen bromide which destabilizes the epoxy network. As a result of the reaction of HBr with the epoxy resin, bromine-containing aromatics (brominated phenols, alkenyl aryl ether, hydroxyalkyl aryl ethers), as well as nonbromine-containing compounds form high-boiling decomposition products. The mass spectra of the brominated products collected from pyrolysis at 300 C in the open system under helium are presented and discussed.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Flame retardant materials and properties · Toxic Organic Pollutants Impact · Polymer crystallization and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Dipartimento di Chimica IFM dell’Università Via P. Giuria 7 10125 Torino, Italy and Guest researcher from Research Institute for Physical Chemical Problems of the Belarusian State University, ul. Leningradskaya 14 220050 Minsk, Belarus,

Dipartimento di Chimica IFM dell’Università Via P. Giuria 7 10125 Torino, Italy

Dipartimento di Chimica Generale ed Organica Applicata dell’Università C.so Massimo d’Azeglio 48 10125 Torino, Italy

References (29)

Show source-provided references
1. 10.1021/es00146a01510.1021/es00146a015 ↗
2. 10.1016/0045-6535(92)90553-410.1016/0045-6535(92)90553-4 ↗
3. 10.1016/0045-6535(91)90143-210.1016/0045-6535(91)90143-2 ↗
4. 10.1016/S0165-2370(03)00049-410.1016/S0165-2370(03)00049-4 ↗
5. Nara, S. · Rev. Elec. Comm. Lab. · 1972 · 20 · 159
6. Yuan, J. · Proc.-Electron. Compton. Technol. Conf. · 1993 · 43 · 330
7. Nakao, M. · 421
8. 10.1002/app.1994.07052091810.1002/app.1994.070520918 ↗
9. 10.1016/0032-3861(92)90404-K10.1016/0032-3861(92)90404-K ↗
10. 10.1016/S0165-2370(01)00175-910.1016/S0165-2370(01)00175-9 ↗
11. 10.1002/bms.120014081410.1002/bms.1200140814 ↗
12. 10.1002/bms.120018100810.1002/bms.1200181008 ↗
13. 10.1016/0045-6535(91)90125-W10.1016/0045-6535(91)90125-W ↗
14. 10.1021/es990226610.1021/es9902266 ↗
15. 10.1006/taap.1996.021710.1006/taap.1996.0217 ↗
16. 10.1016/S0165-2370(02)00035-910.1016/S0165-2370(02)00035-9 ↗
17. 10.1016/S0165-2370(01)00144-910.1016/S0165-2370(01)00144-9 ↗
18. 10.1016/S0165-2370(01)00145-010.1016/S0165-2370(01)00145-0 ↗
19. 10.1016/S0165-2370(02)00020-710.1016/S0165-2370(02)00020-7 ↗
20. 10.1177/073490410404119710.1177/0734904104041197 ↗
21. 10.1002/pat.38910.1002/pat.389 ↗
22. 10.1177/073490410302100400310.1177/0734904103021004003 ↗
23. 10.1021/ac60181a00410.1021/ac60181a004 ↗
24. 10.1021/ac60156a06110.1021/ac60156a061 ↗
25. 10.1016/j.polymdegradstab.2004.02.01210.1016/j.polymdegradstab.2004.02.012 ↗
26. 10.1016/0141-3910(95)00084-Y10.1016/0141-3910(95)00084-Y ↗
27. Luda, M.P. · 2004
28. March, J. · 1992
29. 10.1002/apmc.1992.05198010510.1002/apmc.1992.051980105 ↗