journal article·2018-04

Studies of thermally assisted interactions of polysulphide polymer with ionic liquids

Nandkishor B Shirsath, Gaurav R Gupta, Vikas V Gite, Jyotsna S Meshram

Bulletin of Materials Science· Volume 41· Issue 2
Publisher page

Abstract

The present paper, for the first time, reports analysis regarding the structural interactions of polysulphide polymer with ionic liquids (ILs), which have been studied by thermo-gravimetry analysis (TGA). A systematic thermal analysis of polysulphide polymer has been carried out, based on polymerization and series of ILs like tetrabutyl ammonium hexa-fluorophosphate [TBA][ $$\hbox {PF}6$$ ], N-butylpyridinium bromide [Bpy][Br] and 1-butyl-3-methyl imidazolium bromide [Bmim][Br] using a thermal gravimetry analyser. The plausible mechanism of the interactions and thermally induced reactions of polysulphide polymer with ILs has been advanced and discussed. The probable interactions of polysulphide polymer with [Bmim][Br] and [TBA][ $$\hbox {PF}6$$ ] are also discussed. The interactions between polysulphide polymer and ILs were confirmed by Fourier transform-infrared spectroscopy, TGA–differential thermo-gravimetry analysis and field emission scanning electron microscopy analysis.
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Research context

OpenAlex topics: Thermal and Kinetic Analysis · Ionic liquids properties and applications · Chemical Thermodynamics and Molecular Structure

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