journal article·2013-06

Electrodeposition of dicalcium phosphate dihydrate coatings on stainless steel substrates

BELAVALLI E PRASAD, P VISHNU KAMATH

Bulletin of Materials Science· Volume 36· Issue 3
Publisher page

Abstract

Cathodic reduction of an aqueous solution containing dissolved calcium and phosphate ions results in the deposition of micrometer thick CaHPO4·2H2O (dicalcium phosphate dihydrate) coatings on stainless steel substrates. The coating obtained at a low deposition current (8 mA cm − 2) comprises lath-like crystallites oriented along 020. The 020 crystal planes are non-polar and have a low surface energy. At a high deposition current (12 mA cm − 2), platelets oriented along 121 are deposited. CaHPO4·2H2O is an important precursor to the nucleation of hydroxyapatite, the inorganic component of bones. Differently oriented CaHPO4·2H2O coatings transform to hydroxyapatite with different kinetics, the transformation being more facile when the coating is oriented along 121. These observations have implications for the development of electrodeposited biocompatible coatings for metal endoprostheses for medical applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Bone Tissue Engineering Materials · Calcium Carbonate Crystallization and Inhibition · Dental materials and restorations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Chow L C and Brown W E 1982 Proc. of third annual conf. on foods, nutrition and dental health 2 217
2. Constantz B R et al 1998 J. Biomed. Mater. Res. 43 45110.1002/(SICI)1097-4636(199824)43:4<451::AID-JBM13>3.0.CO;2-Q ↗
3. Corrigan D A and Bendert R M 1989 J. Electrochem. Soc. 136 72310.1149/1.2096717 ↗
4. Curry N A and Jones D W 1971 J. Chem. Soc. (A) 372510.1039/j19710003725 ↗
5. Dobos D 1975 Electrochemical data (Amsterdam: Elsevier Scientific)
6. Dorozhkin S V 2007 J. Mater. Sci. 42 106110.1007/s10853-006-1467-8 ↗
7. Drissens F C M, Boltong M G, Bermudez O, Planell J A, Ginebra M P and Fernandez E 1994 J. Mater. Sci. Mater. Med. 5 16410.1007/BF00053338 ↗
8. Hesse A and Heimabch D 1999 World J. Urol. 17 30810.1007/s003450050152 ↗
9. Huaxia J I, Ponton C B and Marquis P M 1992 J. Mater. Sci. Mater. Med. 3 28310.1007/BF00705294 ↗
10. Johnsson M S and Nancollas G H 1992 Crit. Rev. Oral. Biol. Med. 3 6110.1177/10454411920030010601 ↗
11. Lecomte J, Boulle A and Lang-Dupont M 1955 Comp. Rend. 241 1927
12. Legeros R Z 1991 Calcium phosphates in oral biology and medicine, (ed.) H M Myers (Basel: Karger) Chap. 6, p. 15410.1159/000419240 ↗
13. Legeros R Z 1994 in Hydroxyapatite and related materials (eds) P W Brown and B Constantz (Boca Raton: CRC Press) p. 3
14. Morancho R, Ghommidh J, Constant G, Moyen B, Comtet J J, Santini R and Buttazzoni B 1983 Mater. Sci. Monogr. 17 1983
15. Mostashari S M, Haddadi H and Hashempoor Z 2006 Asian J. Chem. 18 2388
16. Petrov I, Soptrajanov B, Fuson N and Lawson J R 1967 Spectrochim. Acta 23A 263710.1016/0584-8539(67)80155-7 ↗
17. Raemdonk W V, Ducheyne P and Meester P D 1984 J. Am. Ceram. Soc. 67 38110.1111/j.1151-2916.1984.tb19721.x ↗
18. Rukenstein E, Gourisankar S and Baier R E 1983 J. Colloid. Interf. Sci. 96 24510.1016/0021-9797(83)90026-7 ↗
19. Sainz-Diaz C I, Villacampa A and Otalor F 2004 Am. Miner. 89 30710.2138/am-2004-2-308 ↗
20. Spoto G, Ciliberto E and Allen G C 1994 J. Mater. Chem. 4 184910.1039/jm9940401849 ↗
21. Therese G H A, Kamath P V and Subbanna G N 1998 J. Mater. Chem. 8 40510.1039/a706079c ↗
22. Tlili M M, Benomar M, Gabbrielli C, Perrot H and Tribollet B 2003 J. Electrochem. Soc. 150 C76510.1149/1.1613294 ↗
23. Yamamoto H, Niwa S, Hori M, Hattori T, Sawai K, Akoi S, Hirano M and Takeuchi H 1998 Biomaterials 19 158710.1016/S0142-9612(97)00121-X ↗
24. Yamashita K and Kanazawa T 1989 in Inorganic phosphate materials (ed.) T Kanazawa (Amsterdam: Elsevier)
25. Zhitomirsky I, Gal-Or L, Khon A and Hennicke W H 1995 J. Mater. Sci. 30 530710.1007/BF00356086 ↗