Correlation between ionic conductivity and fluidity of polymer gel electrolytes containing NH4CF3SO3
Source abstract
Abstract
Nonaqueous polymer gel electrolytes containing ammonium triflate (NH4CF3SO3) and dimethylacetamide (DMA) with polymethylmethacrylate (PMMA) as the gelling polymer have been synthesized which show high value of conductivity (~ 10-2 S/cm) at 25°C. The conductivity of polymer gel electrolytes containing different concentrations of NH4CF3SO3 shows a small decrease with the addition of PMMA and this has been correlated with the variation of fluidity of these gel electrolytes. The small decrease in conductivity with PMMA addition shows that polymer plays the role of stiffener and this is supported by FTIR results which also indicates the absence of any active interaction between polymer and NH4CF3SO3 in these gel electrolytes.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Fuel Cells and Related Materials · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (24)
Show source-provided references
1. Abraham K M and Alamgir M 1990J. Electrochem. Soc. 137 165710.1149/1.2086749 ↗
2. Ansari S M, Browdwin M, Stainer M, Druger S D, Ratner M A and Shriver D F 1985Solid State Ionics 17 10110.1016/0167-2738(85)90056-6 ↗
3. Bohnke O, Frand G, Rezrazi M, Rousselot C and Truche C 1993aSolid State Ionics 66 10510.1016/0167-2738(93)90033-Y ↗
4. Bohnke O, Frand G, Rezrazi M, Rousselot C and Truche C 1993bSolid State Ionics 66 9710.1016/0167-2738(93)90032-X ↗
5. Chandra S, Maurya K K and Hashmi S A 1990 inRecent advances in fast ion conducting materials and devices (eds) B V R Chowdari, Q Liu and L Chen (Singapore: World Scientific) p. 549
6. Colomban P (ed.) 1992Proton conductors: solids, membranes and gels—materials and devices (Cambridge: Cambridge University Press)
7. Cronin J P, Gudgel T J, Kennedy S R, Agrawal A and Uhlmann D R 1999Mater. Res. 2 110.1590/S1516-14391999000100002 ↗
8. Daniel M F, Desbat B and Lassegues J C 1988Solid State Ionics 28-30 63210.1016/S0167-2738(88)80115-2 ↗
9. Feuillade G and Perche Ph 1975J. Appl. Electrochem. 5 6310.1007/BF00625960 ↗
10. Kumar M and Sekhon S S 2002Eur. Polym. J. 38 129710.1016/S0014-3057(01)00310-X ↗
11. Laforgue A, Simon P, Sarrazin C and Fauvarque J 1999J. Power Sources 80 14210.1016/S0378-7753(98)00258-4 ↗
12. Oradd G, Furlani M and Ferry A 2000Solid State Ionics 136-137 45710.1016/S0167-2738(00)00563-4 ↗
13. Paoli D R, Nogueira A F, Machado D A and Longo C 2001Electrochim. Acta 46 424310.1016/S0013-4686(01)00684-3 ↗
14. Perry M L and Fuller T F 2002J. Electrochem. Soc. 149 S5910.1149/1.1488651 ↗
15. Prusinowska D, Wieczorek W, Wycislik H and Przyluski J 1994Solid State Ionics 72 15210.1016/0167-2738(94)90140-6 ↗
16. RatnerM A 1987 inPolymer electrolyte reviews (eds) J R MacCallum and C A Vincent (London: Elsevier Applied Science)Vol. 1 p. 173
17. Sekhon S S, Pradeep, Agnihotry S A 1998in Solid state ionics: Science and Technology (eds) B V R Chowdariet al (Singapore: World Scientific) p. 217
18. Silverstein R M and Webster F X 1997Spectroscopic identification of organic compounds (New York: John Wiley and Sons) 6th ed., Ch. 4
19. Slade R C T, Hardwick A and Dickens P G 1983Solid State Ionics 9-10 109310.1016/0167-2738(83)90136-4 ↗
20. Socrates G 1998Infrared and Raman characteristic group frequencies: Tables and charts (London: Wiley Science) 2nd ed.
21. Southall J P, Hubbard H V St A, Johnston S F, Rogers V, Davies G R, McIntyre J E and Ward I M 1996Solid State Ionics 85 5110.1016/0167-2738(96)00040-9 ↗
22. Stainer M, Hardy L C, Whitmore D H and Shriver D F 1984J. Electrochem. Soc. 131 78410.1149/1.2115699 ↗
23. Tsuchida E, Ohno H and Tsunemi K 1983Electrochim. Acta 28 59110.1016/0013-4686(83)85049-X ↗
24. Webber A 1991J. Electrochem. Soc. 138 258610.1149/1.2087287 ↗