Multiferroic BiFeO3 dithizone functionalized as optical sensor for detection and determination of some heavy metals in environmental samples
Source abstract
Abstract
A new optical sensor was designed for sensitive, selective detection and determination of Cd2+, Cr3+, Ni2+ and Pb2+ based on immobilization of dithizone (DZ) on a BiFeO3 (BFO) nanopowder. The sol–gel technique has been used for the synthesis of nano-multiferroic BiFeO3 in a pure form. The effect of DZ concentration, stirring time, pH and BFO molar concentration for immobilization of DZ as an indicator on BFO nanoparticles was developed. Highly sensing and colour change of the optical sensor of the studied metals Cd2+, Cr3+, Ni2+ and Pb2+ showed detection limits of 1.65 × 10−4, 1.5 × 10−4, 3 × 10−4 and 7.8 × 10−5 M, respectively. The optical sensor’s response time to studied metals varies with the concentration of metals. The prepared optical sensor was used to analyse the industrial wastewater sample qualitatively and quantitatively. Atomic absorption spectrometer analysis verified the assayed levels of Cd2+, Cr3+, Ni2+ and Pb2+. The sensor efficiencies for Cd2+, Cr3+, Ni2+ and Pb2+ were 95.27, 84.56, 84.99 and 104.73%, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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