Sonochemically synthesized Na2Ti6O13 nanorod: an efficient electrode material for Na-ion battery
Source abstract
Abstract
A simple cost-effective wet synthesis route has been proposed for synthesis of Na2Ti6O13, which is an efficient anode material that can be used for 1–3 volt batteries. The material has been synthesized by sonochemical route, which offers two distinct features: (1) energy-savvy (green) synthesis by significantly lowering the final calcination temperature and duration, and (2) formation of uniform and nano-scale particles suitable for battery application. The sonochemical synthesis was carried out at 20 kHz–500 W by applying sonication for 30 min at 25°C, using precursors (NaOH:TiO2) in a molar ratio of 6:1 followed by calcination at 750°C for 1 h in air. This material showed excellent reversible electrochemical performance (up to 93% retention) and offers reversible capacity around 40 mAh g−1 acting to be 0.82 V anode for Na-ion battery.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Ferroelectric and Piezoelectric Materials
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References (42)
Show source-provided references
1. Stevens D A and Dahn J R 2000 J. Electrochem. Soc. 147 127110.1149/1.1393348 ↗
2. Stevens D A and Dahn J R 2001 J. Electrochem. Soc. 148 A80310.1149/1.1379565 ↗
3. Prosini P P, Mancini R, Petrucci L, Contini V and Villano P 2001 Solid State Ion. 144 18510.1016/S0167-2738(01)00891-8 ↗
4. Ge P and Fouletier M 1988 Solid State Ion. 30 117210.1016/0167-2738(88)90351-7 ↗
5. Ponrouch A, Marchante M, Courty E, Tarascon J M and Palacín M R 2012 Energy Environ. Sci. 5 857210.1039/c2ee22258b ↗
6. Rudola A, Saravanan K, Mason C W and Balaya P 2013 J. Mater. Chem. A 1 265310.1039/c2ta01057g ↗
7. Senguttuvan P, Rousse G, Seznec V, Tarascon J-M and Palacin M R 2011 Chem. Mater. 23 410910.1021/cm202076g ↗
8. Xiao L, Cao Y, Xiao J, Wang W, Kovarik L, Nie Z et al 2012 Chem. Commun. 48 332110.1039/c2cc17129e ↗
9. Xiong H, Slater M D, Balasubramanian M, Johnson C S and Rajh T 2011 J. Phys. Chem. Lett. 2 256010.1021/jz2012066 ↗
10. Rudola A, Saravanan K, Devaraj S, Gong H and Balaya P 2013 Chem. Commun. 49 745110.1039/c3cc44381g ↗
11. Peramunage D and Abraham K M 1998 J. Electrochem. Soc. 145 260910.1149/1.1838689 ↗
12. Jansen N, Kahaian A J, Kepler K D, Nelson P A, Amine K, Dees D W et al 1999 J. Power Sources 81/82 90110.1016/S0378-7753(99)00268-2 ↗
13. Ohzuku T, Ueda A, Yamamoto N and Iwakoshi Y 1995 J. Power Sources 54 9910.1016/0378-7753(94)02047-7 ↗
14. Ghosh S, Daya Mani A, Kishore B, Munichandraiah N, Rao R P, Wong L L et al 2017 J. Electrochem. Soc. 164 A188110.1149/2.0641709jes ↗
15. Zhu G-N, Wang Y-G and Xia Y-Y 2012 Energy Environ. Sci. 5 665210.1039/c2ee03410g ↗
16. Trinh N D, Crosnier O, Schougaard S B and Brousse T 2011 ECS Trans. 35 9110.1149/1.3655691 ↗
17. Baughman H, Zakhidov A A and de Heer W A 2002 Science 297 78710.1126/science.1060928 ↗
18. Sugimoto W, Iwata H, Yasunaga Y, Murakami Y and Takasu Y 2003 Angew. Chem. Int. Ed. 42 409210.1002/anie.200351691 ↗
19. Li D L, Zhou H S and Honma I 2004 Nat. Mater. 3 6510.1038/nmat1043 ↗
20. Hughes M, Shaffer M, Renouf N C, Singh C, Chen G Z, Fray D J et al 2002 Adv. Mater. 14 38210.1002/1521-4095(20020304)14:5<382::AID-ADMA382>3.0.CO;2-Y ↗
21. Raimondi F, Scherer G G, Ko¨tz R and Wokaun A 2005 Angew. Chem. Int. Ed. 44 219010.1002/anie.200460466 ↗
22. Dong W, Rollison D R and Dunn B 2000 Electrochem. Solid State Lett. 3 45710.1149/1.1391178 ↗
23. Wang Y, Lee J Y and Deivaraj T C 2004 J. Phys. Chem. B10 1358910.1021/jp048454w ↗
24. Wang Y, Lee J Y and Zeng H C 2005 Chem. Mater. 17 389910.1021/cm050724f ↗
25. Wang Y, Zeng H C and Lee J Y 2006 Adv. Mater. 18 64510.1002/adma.200501883 ↗
26. Zhao Z W, Guo Z P, Wexler D, Ma Z F, Wu Z and Liu H K 2007 Electrochem. Commun. 9 69710.1016/j.elecom.2006.11.001 ↗
27. Armstrong G, Armstrong A R, Canales J and Bruce P G. 2006 Electrochem. Solid State Lett. 9 A13910.1149/1.2162327 ↗
28. Gao X P, Lan Y, Zhu H Y, Liu J W, Ge Y P, Wu F et al 2005 Electrochem. Solid State Lett. 8 A2610.1149/1.1833632 ↗
29. Wang Q, Wen Z and Li J 2006 Inorg. Chem. 45 694410.1021/ic060477x ↗
30. Armstrong A R, Armstrong G, Canales J and Bruce P G 2004 Angew. Chem. Int. Ed. 43 228610.1002/anie.200353571 ↗
31. Hu Y-S, Kienle L, Guo Y-G and Maier J 2006 Adv. Mater. 18 142110.1002/adma.200502723 ↗
32. Armstrong A R, Armstrong G, Canales J, Garcia R and Bruce P G 2005 Adv. Mater. 17 86210.1002/adma.200400795 ↗
33. Lee Y, Kim M G and Cho J 2008 Nano Lett. 8 95710.1021/nl0731466 ↗
34. Rambabu A, Senthilkumar B, Sada K, Krupanidhi S B and Barpanda P 2018 J. Colloid Interf. Sci. 514 11710.1016/j.jcis.2017.12.023 ↗
35. Xu H, Zeiger B W and Suslick K S 2013 Chem. Soc. Rev. 42 255510.1039/C2CS35282F ↗
36. Ghosh S, Kee Y, Okada S and Barpanda P 2015 J. Power Sources 296 27610.1016/j.jpowsour.2015.07.057 ↗
37. Zhang Y, Hou H, Yang X, Chen J, Jing M, Wu Z et al 2016 J. Power Sources 305 20010.1016/j.jpowsour.2015.11.101 ↗
38. Cech O, Castkova K, Chladil L, Dohnal P, Cudek P, Libich J et al 2017 J. Energy Storage 14 39110.1016/j.est.2017.07.008 ↗
39. Wu C, Hua W, Zhang Z, Zhong B, Yang Z, Feng G et al 2018 Adv. Sci. 5 180051910.1002/advs.201800519 ↗
40. Ho C K, Vanessa Li C Y and Chan K Y 2016 Ind. Eng. Chem. Res. 55 1006510.1021/acs.iecr.6b01867 ↗
41. Luo L, Zhen Y, Lu Y, Zhou K, Huang J, Huang Z et al 2020 Nanoscale 12 23010.1039/C9NR08003A ↗
42. Fagundes N G, Nobre F X, Basilio L A L, Melo A D, Bandeira B, Sales J C C et al 2019 Solid State Sci. 88 6310.1016/j.solidstatesciences.2018.11.014 ↗