Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by tert-butyl hydroperoxide over Pt/oxide catalysts
Source abstract
Abstract
Heterogeneous oxidation of cyclohexane with tertiobutyl hydroperoxide was carried out on Pt/oxide (Al2O3, TiO2 and ZrO2) catalysts in the presence of different solvents (acetic acid and acetonitrile). The catalysts were prepared using Pt(NH3)2(NO2)2 as a precursor and characterized by chemical analysis using the ICP–AES method, XRD, TEM, FTIR and BET surface area determination. The oxidation reaction was carried out at 70°C under atmospheric pressure. The results showed the catalytic performance of Pt/Al2O3 as being very high in terms of turnover frequency.
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Research context
OpenAlex topics: Catalysis and Oxidation Reactions · Catalytic Processes in Materials Science · Oxidative Organic Chemistry Reactions
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References (36)
Show source-provided references
1. Anisia K S and Kumar A 2004 Appl. Catal. A: Gen. 273 19310.1016/j.apcata.2004.06.031 ↗
2. Bellifa A, Lahcene D, Technar Y N, Choukchou-Braham A, Bachir R, Bedrane S and Kappenstein C 2006 Appl. Catal. A: Gen. 305 110.1016/j.apcata.2006.01.010 ↗
3. Carballo L, Serrano C, Wolf E E and Carberry J 1978 J. Catal. 52 50710.1016/0021-9517(78)90356-1 ↗
4. Corma F, Sepulveda-Escribano A, Fierro J L and Rodriguez-Reinoso F 1997 Appl. Catal. A: Gen. 150 16510.1016/S0926-860X(96)00301-8 ↗
5. Du Y, Xiong Y, Li J and Yang X 2009 J. Mol. Catal. A: Chem. 298 1210.1016/j.molcata.2008.09.020 ↗
6. Ebadi A, Safari N and Peyrovi M H 2007 Appl. Catal. A: Gen. 321 13510.1016/j.apcata.2007.01.040 ↗
7. Garetto T F and Apesteguia C R 2000 Catal. Today 62 18910.1016/S0920-5861(00)00420-X ↗
8. Ingold K U 1989 Aldrichim. Acta 22 69
9. Kobayashi M, Kanno T, Konishi A and Takeda H 1988 React. Kinet. Catal. Lett. 37 8910.1007/BF02061715 ↗
10. Kumar R, Sithambarama S and Suib S L 2009 J. Catal. 262 30410.1016/j.jcat.2009.01.007 ↗
11. Kuznetsova N I, Kirillova N V, Kuznetsova L I and Likholobov V A 2003 J. Mol. Catal. A: Chem. 204–205 59110.1016/S1381-1169(03)00342-X ↗
12. Labalme V, Garbowsky E, Ghilhaume N and Primet M 1996 Appl. Catal. A: Gen. 138 9310.1016/0926-860X(95)00248-0 ↗
13. Lu G, Zhao R, Qian G, Qi Y, Wang X and Suo J 2004 Catal. Lett. 97 11510.1023/B:CATL.0000038571.97121.b7 ↗
14. Lu G, Ji D, Qian G, Qi Y, Wang X and Suo J 2005 Appl. Catal. A: Gen. 280 17510.1016/j.apcata.2004.10.034 ↗
15. Marecot P, Fakche A, Kellali B, Mabilon G, Prigent M and Barbier J 1994 Appl. Catal. B: Environ. 3 28310.1016/0926-3373(94)00003-4 ↗
16. Masters A F, Beattie J K and Roa A L 2001 Catal. Lett. 75 15910.1023/A:1016763224751 ↗
17. Papaefthimiou P, Ioannides T and Verykios X E 1998 Appl. Catal. B: Environ. 15 7510.1016/S0926-3373(97)00038-6 ↗
18. Perkas N, Minh D P, Gallezot P, Gedanken A and Besson M 2005 Appl. Catal. B: Environ. 59 12110.1016/j.apcatb.2005.01.009 ↗
19. Pires E L, Magalhaes J C and Schuchardt U 2000 Appl. Catal. A: Gen. 203 23110.1016/S0926-860X(00)00496-8 ↗
20. Pliangos C, Yentekakis I V, Papadakis V G, Vayenas C G and Verykios X E 1997 Appl. Catal. B: Environ. 14 16110.1016/S0926-3373(97)00020-9 ↗
21. Radic N, Grbic B and Terlecki-Baricevic A 2004 Appl. Catal. B: Environ. 50 15310.1016/j.apcatb.2004.01.011 ↗
22. Rasband W and Image J 1997–2005 U.S. National Institutes of Health, Bethesda, MD, USA http://rsb.info.nih.gov/ij/
23. Reddy J S and Sivasanker S 1991 Catal. Lett. 11 24110.1007/BF00764090 ↗
24. Sakthivel A and Selvam P 2002 J. Catal. 211 13410.1016/S0021-9517(02)93711-5 ↗
25. Sawatari N, Yokota T, Sakaguchi S and Ishii Y 2001 J. Org. Chem. 66 788910.1021/jo0158276 ↗
26. Schuchardt U, Carvalho W A and Spinace E V 1993 Synlett. 71310.1055/s-1993-22583 ↗
27. Schuchardt U et al 2001 Appl. Catal. A: Gen. 211 110.1016/S0926-860X(01)00472-0 ↗
28. Shulpin G B, Fink G S and Smith J R 1999 Tetrahedron 55 534510.1016/S0040-4020(99)00233-1 ↗
29. Silva A C et al 2007 Appl. Catal. A: Gen. 317 15410.1016/j.apcata.2006.10.012 ↗
30. Sooknoi T and Limtrakul J 2002 Appl. Catal. A: Gen. 233 22710.1016/S0926-860X(02)00196-5 ↗
31. Wangcheng Z, Guanzhong L, Yanglong G, Yun G, Yanqin W, Yunsong W, Zhigang Z and Xiaohui L 2008 J. Rare Earths 26 51510.1016/S1002-0721(08)60129-5 ↗
32. Xu L X, He C H, Zhu M Q and Fang S 2007 Catal. Lett. 114 20210.1007/s10562-007-9058-0 ↗
33. Yao W, Chen Y, Min L, Fang H, Yan Z, Wang H and Wang J 2006 J. Mol. Catal. A: Chem. 246 16210.1016/j.molcata.2005.10.029 ↗
34. Yuan H X, Xia Q H, Zhan H J, Lu X H and Su K X 2006 Appl. Catal. A: Gen. 304 17810.1016/j.apcata.2006.02.037 ↗
35. Zhao R, Wang Y, Guo Y, Guo Y, Liu X, Zhang Z, Wang Y, Zhan W and Lu G 2006 Green Chem. 8 45910.1039/b517656e ↗
36. Zhou L, Xu J, Miau H, Wang F and Li X 2005 Appl. Catal. A: Gen. 292 22310.1016/j.apcata.2005.06.018 ↗