Fire risk assessment of cypress wood coated with metal oxide and metal silicate flame retardant using cone calorimeter
Source abstract
Abstract
This study investigated the fire risk properties of cypress wood for the construction of interiors, especially focusing on heat and smoke hazard properties in fire scenarios. Fire risk characteristics were measured using a cone calorimeter (ISO 5660-1). The external heat flux was maintained at 50 kW/m 2 . The flame retardants used were metal oxide and metal silicate; they were mixed with a water glass solution. Flame retardants and the silicon compound were dispersed in a concentration of 20 wt% versus 80 wt%, respectively, during 24 h using a magnetic stirrer. The fire performance indexes of the specimens increased by 3–16 times, compared with uncoated specimen and the fire growth index of the specimens increased by 70%–92%. The smoke performance index of the specimens increased by 9–66 times, compared with uncoated specimens. The smoke risk as shown by the smoke performance index increased in the following order: SnO < mica < Co 3 O 4 < ZrSiO 4 < cypress. The smoke growth index decreased from 93% to 98%, compared with uncoated wood. The smoke risk due to smoke growth index increased in the following order: SnO < mica < ZrSiO 4 ≈ Co 3 O 4 < cypress. The smoke intensity decreased from a minimum of 85% to a maximum of 99%, compared with uncoated wood. The concentration of CO gas generated after combustion was decreased by 24%–67%. They increased in the following order: mica ≈ ZrSiO 4 < SnO < Co 3 O 4 < cypress. A comprehensive assessment of fire performance shows that flame retardants decreased heat hazards, smoke hazards, and CO toxicity.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Flame retardant materials and properties · Fire dynamics and safety research · Polymer Nanocomposites and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Fire & Disaster Prevention Research Center, Kangwon National University, Samcheok, Republic of Korea
Department of Fire and Protection Engineering, Kangwon National University, Samcheok, Republic of Korea
Funding
national research foundation of korea
References (39)
Show source-provided references
1. 10.1515/HF.2011.13810.1515/HF.2011.138 ↗
2. 10.1016/j.polymdegradstab.2004.08.01710.1016/j.polymdegradstab.2004.08.017 ↗
3. Oberley WJ · US4010296A patent, USA · 2011
4. 10.1016/S0141-3910(96)00045-610.1016/S0141-3910(96)00045-6 ↗
5. Lee CH, Lee CW, Kim JW, et al. Organic phosphorus-nitrogen compounds, manufacturing method and compositions of flame retardants containing organic phosphorus nitrogen compounds. 2011-0034978, Korean Patent, 2011.
6. Gilman JW, Kashiwagi T, Harris R, et al. Char enhancing approaches to flame retarding polymers. In: Al-Malaika S, Golovoy A, Wilkie CA (eds) Chemistry and technology of polymer additives. Malden, MA: Blackwell Science, 1999, p. 135.
7. 10.1021/cr800398310.1021/cr8003983 ↗
8. 10.1021/cm000560x10.1021/cm000560x ↗
9. 10.1002/adma.1996008010410.1002/adma.19960080104 ↗
10. 10.1039/b505177k10.1039/b505177k ↗
11. 10.1007/s10971-006-9322-610.1007/s10971-006-9322-6 ↗
12. 10.1177/1420326X1351665510.1177/1420326X13516655 ↗
13. 10.1016/S0300-9440(03)00127-910.1016/S0300-9440(03)00127-9 ↗
14. 10.1002/app.1214210.1002/app.12142 ↗
15. 10.1002/(SICI)1099-1018(199803/04)22:2<69::AID-FAM640>3.0.CO;2-U10.1002/(SICI)1099-1018(199803/04)22:2<69::AID-FAM640>3.0.CO;2-U ↗
16. 10.1021/es049493o10.1021/es049493o ↗
17. 10.1016/0379-7112(93)90052-R10.1016/0379-7112(93)90052-R ↗
18. 10.1016/0010-2180(87)90013-710.1016/0010-2180(87)90013-7 ↗
19. ISO 5660-1: 2015. Reaction-to-fire tests-heat release, smoke production and mass loss rate-part 1: heat release rate (cone calorimeter method) and smoke production rate (dynamic measurement).
20. 10.1016/j.carbon.2019.05.00210.1016/j.carbon.2019.05.002 ↗
21. 10.1016/j.porgcoat.2019.05.04310.1016/j.porgcoat.2019.05.043 ↗
22. Babrauskas V · 1986 · 78
23. 10.1021/bk-2001-0797.ch02310.1021/bk-2001-0797.ch023 ↗
24. Chung YJ · Appl Chem Eng · 2018 · 29 · 670
25. Simpson WT · 2010
26. 10.1007/s10853-007-2241-210.1007/s10853-007-2241-2 ↗
27. 10.1002/fam.243110.1002/fam.2431 ↗
28. Wang B · ACS Appl Mater Interf · 2011 · 3 · 375410.1021/am200940z ↗
29. 10.1177/073490410910203310.1177/0734904109102033 ↗
30. 10.1016/j.polymdegradstab.2010.03.01510.1016/j.polymdegradstab.2010.03.015 ↗
31. Bermejo JS · Jacobs J Nanomed Nanotechnol · 2015 · 1 · 1
32. 10.1016/B978-0-12-703780-6.50013-410.1016/B978-0-12-703780-6.50013-4 ↗
33. 10.1016/S0141-3910(98)00152-910.1016/S0141-3910(98)00152-9 ↗
34. 10.1007/s00226-004-0246-410.1007/s00226-004-0246-4 ↗
35. 10.1016/S0010-2180(00)00162-010.1016/S0010-2180(00)00162-0 ↗
36. 10.1016/j.firesaf.2009.07.00410.1016/j.firesaf.2009.07.004 ↗
37. 10.1016/j.compositesa.2005.01.03010.1016/j.compositesa.2005.01.030 ↗
38. OSHA · Federal Register · 1989 · 54 · 2331
39. MSHA · Mine rescue team training metal and nonmetal · 2008 · 1