journal article·2003-07

Synthesis of a New-type Carbonific and Its Application in Intumescent Flame-retardant (IFR)/Polyurethane Coatings

Wang Jincheng, Yang Shenglin, Li Guang, Jiang Jianming

Journal of Fire Sciences· Volume 21· Issue 4
Publisher page

Abstract

This work deals in the first part, with the synthesis and characterization of a new-type carbonific. Two steps were used in the synthesis of the carbonific. Meanwhile, the structure was characterized by Fourier transform infrared spectroscopy (FTIR), magic-angle spinning nuclear magnetic resonance (MAS-NMR) 13 C spectroscopy and elemental analysis. The addition of ammonium-polyphosphate (APP) and the carbonific into polyurethane (PU) varnish leads to a great improvement in its carbonization and flame-retardant (FR) performances. The second part deals with choosing the most effective combination of APP, carbonific and PU varnish. The last part deals with the evaluation of characteristic performances such as FR property, thermal stability of IFR/PU-based coatings, rheology of IFR/PU-based coating solutions and mechanical properties such as hardness, adhesion, flexibility of IFR/PU-based dry coating films.
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Research context

OpenAlex topics: Flame retardant materials and properties · Carbon dioxide utilization in catalysis · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory for Modification, of Chemical Fibers and Polymer Materials, Donghua University, Shanghai, 200051, P.R. China

References (29)

Show source-provided references
1. 1. Kuryla, W.C. and Papa, A.J. (1975). Flame Retardancy of Polymeric Materials, Vol. 3, Chapter 1, Marcel Dekker, New York .
2. 10.1002/app.218510.1002/app.2185 ↗
3. 3. Woods, G. (1990). The ICI Polyurethane Book, ICI Polyurethanes and Wiley, Chichester .
4. 4. Hatat, D. (1995). In Techniques de I'ingenieur, Les Techniques de I'ingenieur, Paris .
5. 5. Kirk, R.E. and Othman, D.F. (1997). Encylopedia of Chemical Technology, Wiley-Interscience, New York .
6. 10.1016/S0300-9440(00)00123-510.1016/S0300-9440(00)00123-5 ↗
7. 10.1002/1097-0126(200010)49:10<1115::AID-PI430>3.0.CO;2-910.1002/1097-0126(200010)49:10<1115::AID-PI430>3.0.CO;2-9 ↗
8. 8. Bourbigot, S., Le Bras, M. and Bugajny, M. (1998). Intumescence and Polymer Blending: an Approach for Flame Retardancy , NIST Annual Conference, Gaithersburg.
9. 10.1039/ft996920014910.1039/ft9969200149 ↗
10. 10. Mamleev, V.Sh. and Gibov, K.M. (1998). In Fire Retardancy of Polymers: The Use of Intumescence, The Royal Chemical Society, Cambridge .
11. 10.1016/0141-3910(84)90004-110.1016/0141-3910(84)90004-1 ↗
12. 10.1002/(SICI)1097-4628(19980207)67:6<989::AID-APP4>3.0.CO;2-I10.1002/(SICI)1097-4628(19980207)67:6<989::AID-APP4>3.0.CO;2-I ↗
13. 10.1002/(SICI)1099-1018(199607)20:4<191::AID-FAM577>3.0.CO;2-S10.1002/(SICI)1099-1018(199607)20:4<191::AID-FAM577>3.0.CO;2-S ↗
14. 14. Fontanelli, R., Landoni, G., Legnani, G. and Saronno. (1985). Self-extinguishing Polymeric Compositions, U.S. Pat. 4, 504, 610.
15. 10.1163/156856197X0034510.1163/156856197X00345 ↗
16. 16. Zongming, W., Xianxiang, H. and Dianqing, S. (1982). Useful Analysis of Infrared Spectrum of Polymers, Petroleum Industry Publication, Beijing .
17. 17. Katritzky, A.R. (1963). Physical Methods in Hetrocyclic Chemistry, Academic Press, New York and London .
18. 18. West, W. (1956). Chemical Applications of Spectroscopy, Rochester Eastman Kodak Company, New York .
19. 19. Yongcheng, N. (2000). Structural Identification of Organic Compounds and Organic Spectroscopy, Science Publication, Beijing .
20. 10.1177/07349041900080020210.1177/073490419000800202 ↗
21. 21. Fengchang, Z. and Yueliang, L. (1988). Functional Coatings, Chemical Industry Publication, Beijing .
22. 10.1002/(SICI)1097-4628(19980705)69:1<115::AID-APP13>3.0.CO;2-Z10.1002/(SICI)1097-4628(19980705)69:1<115::AID-APP13>3.0.CO;2-Z ↗
23. 10.1002/apmc.1989.05169011210.1002/apmc.1989.051690112 ↗
24. 24. Bertelli, G., Marchetti, E., Camino, G., Costa, L. and Locattli, R. (1990). Intumescent Fire Retardant Systems , Angew Makromol Chem., 172: 156-163 .10.1002/apmc.1989.051720113 ↗
25. 10.1002/fam.81018050610.1002/fam.810180506 ↗
26. 10.1016/S0141-3910(96)00190-510.1016/S0141-3910(96)00190-5 ↗
27. 10.1177/07349041970150050210.1177/073490419701500502 ↗
28. 28. Lambonrne, R. (1987). Paint and Surface Coatings: Theory and Practice, Ellis Horwood Limited, Chichester .
29. 29. Hegedus, C.R. and Kamel, I.L. (1993). Polymer-Filler Interaction Effects on Coating Properties , Journal of Coatings Technology, 822(65): 37-43 .