Resolución de la ecuación integral de adsorción mediante el algoritmo EDCAIS

espanolEn este articulo se presenta la resolucion de la ecuacion integral de adsorcion mediante nuestra version del algoritmo EDCAIS (Energy Distribution Computation from Adsorption Isotherm Utilizing the Smoothing Spline Functions). Este algoritmo resuelve la ecuacion integral de adsorcion de forma numerica para isotermas locales Cuasi-Langmuir con correccion a la multicapa. Tambien se muestra la fiabilidad del metodo mediante el calculo de la funcion de distribucion de energias a partir de tres isotermas teoricas consistentes en uno, tres y cinco picos gaussianos. El metodo EDCAIS se ha aplicado a tres sistemas experimentales correspondientes a la adsorcion de benceno sobre fibras de carburo de silicio, vidrio E y vidrio E organofilizado con y-aminopropiltrietoxisilano. Las funciones de distribucion obtenidas se han comparado con las determinadar por otros metodos aproximados. Los resultados han demostrado que el metodo EDCAIS permite diferencias mayor cantidad de centros de adsorcion en las superficies estudiadas EnglishIn this work the resolution of the integral equation for the overall adsorption isotherm is presented that resolution is made according to our procedure of the EDCAIS algorithm (Energy Distribution Computation from Adsorption Isotherm Utilizing the Smoothing Spline Functions). This algorithms solves the integral equation by numerical methods using the quasi Langmuir isotherm corrected on the multilayer as the local adsorption isotherm. This method has been proved using three theoretical isotherms consisting on one, three and five guassian peaks. The EDCAIS method has been applied to three experimental systems, consisting of benzene as adsorbate and silicon carbide fibres, E-glass and E-y-APS as adsorbents. Energy Distribution Functions have been tested with those obtained using other methods. Results have shown that EDCAIS method gives distribution functions of best resolution of adsorption sites.