High Performance Polyesters Prepared from Bio‐Based 2,5‐Furandicarboxylic Acid
Source abstract
Abstract
Aromatic polyesters were synthesized by the polymerization of bio‐based 2,5‐furandicarboxylic acid (FDCA) with petroleum‐based 1,3‐ and 1,4‐diacetoxybenzene (DAB) from the viewpoint of the suppression of the petroleum consumption to develop the sustainable development society. Polyesters prepared at the molar ratio of 1,4‐DAB in DAB (χ) of less than 60 mol％ showed meltability under decomposition temperature. When the value of χ was 20‐60 mol％, the polyesters exhibited optical anisotropicity in melt phase, suggesting the thermotropic liquid crystallinity. The phase transition temperature of these polyesters depended on the composition and it was tunable by the χ value. The film of the polyesters prepared at χ of 20 mol％ possessed 1.2 GPa of the modulus, 26.0 MPa and 2.9％ of the strength and elongation at break, respectively. Polyesters based on FDCA possessed good thermal stability and mechanical properties comparable to common aromatic polyesters.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis for Biomass Conversion · biodegradable polymer synthesis and properties · Biofuel production and bioconversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Graduate School of Environmental and Life Science, Okayama University
References (26)
Show source-provided references
1. [1] J. K. Fink, “HIGH PERFORMANCE POLYMERS", William Andrew: New York, Chapter 16, pp. 521‐550 (2008).
2. [2] R. B. Seymour, G. S. Kirshenbaum, “High Performance Polymers; Their Origin and Development", Elsevier: New York, pp. 235‐257 (1986).10.1007/978-94-011-7073-4 ↗
3. [3] H. G. Elias, `'Macromolecules; Vol. 3, Physical Stuructures and Properties", Wiley‐VCH, Chapter 8, pp. 239‐271.
4. [4] D. Plackett, “BIOPOLYMERS; New Materials for Sustainable Films and Coating", John Wiley ＆ Sons, 1st Ed., Chapter 9, pp. 179‐209 (2011).10.1002/9781119994312 ↗
5. [5] Y. Roman‐Leshkov, J. N. Chheda, J. A. Dumesic, Science, 312, 1933 (2006).10.1126/science.1126337 ↗
6. [6] M. L. Ribeiro, U. Schuchardt, Catal. Commun., 4, 83 (2003).10.1016/S1566-7367(02)00261-3 ↗
7. [7] Y. R. Leshkov, C. J. Barrett, Z. Y. Liu, J. A. Dumesic, Nature, 447, 982 (2007).10.1038/nature05923 ↗
8. [8] T. Werpy, G. Petersen, “Top Value Added Chemicals from Biomass; Energy Efficiency and Renewable Energy", 1, pp. 26‐28 (2004).
9. [9] M. Gomes, A. Gandini, A. Silvestre, B. Reis, J. Polym. Sci. Part A, 49, 3759 (2011).10.1002/pola.24812 ↗
10. [10] A. Gandini, D. Coelho, M. Gomes, B. Reis, A. Silvestre, J. Mater. Chem., 19, 8656 (2009).10.1039/b909377j ↗
11. [11] C. H. R. M. Wilsens, B. A. J. Noordver, S. Rastogi, Polymer, 55, 2432 (2014).10.1016/j.polymer.2014.03.033 ↗
12. [12] R. J. I. Knoop, W. Vogelzang, J. V. Haveren, D. S. V. Es, J. Polym. Sci., Part A, 51, 4191 (2013).10.1002/pola.26833 ↗
13. [13] A. Gandini, M. N. Belgacem, Prog. Polym. Sci., 22, 1203 (1997).10.1016/S0079-6700(97)00004-X ↗
14. [14] J. A. Moore, J. E. Kelly, Macromolecules, 11, 568 (1978).10.1021/ma60063a028 ↗
15. [15] J. A. Moore, J. E. Kelly, Macromolecules, 20, 627 (1979).10.1016/0032-3861(79)90178-2 ↗
16. [16] R. Storbeck, M. Ballauff, Polymer, 34, 5003 (1993).10.1016/0032-3861(93)90037-B ↗
17. [17] A. Khrouf, S. Boufi, R. E. Gharbi, N. M. Belgacem, A. Gandini, Polym. Bull., 37, 589 (1996).10.1007/BF00296603 ↗
18. [18] A. F. Sousa, M. Matos, C. S. R. Freire, A. J. D. Silvestre, J. F. J. Coelho, Polymer, 54, 513 (2013).10.1016/j.polymer.2012.11.081 ↗
19. [19] H. Hopff, A. Krieger, Helvetica Chimica Acta, 44, 1058 (1961).10.1002/hlca.19610440425 ↗
20. [20] S. Kohama, K. Kimura, Y. Yamashita, J. Polym. Sci., Part A, 43, 1757 (2005).10.1002/pola.20651 ↗
21. [21] E. E. Riecke, F. L. Hamb, J. Polym. Sci., Part A, 15, 593 (1977).10.1002/pol.1977.170150308 ↗
22. [22] J. Huang, J. P. Leblanc, H. K. Hall Jr., J. Polym. Sci., Part A, 30, 345 (1992).10.1002/pola.1992.080300301 ↗
23. [23] H. R. Kricheldolf, G. Schwarz, Macromol. Rapid. Commun., 24, 359 (2004).10.1002/marc.200390063 ↗
24. [24] G. Costa, A. Gandini, S. Morinelli, B. Valenti, Heterocycles, 36, 1225 (1993).10.3987/COM-92-6126 ↗
25. [25] J. Cao, G. Karayannidis, J. E. Mclntyre, J. G. Tomka, Polymer, 34, 1471 (1993).10.1016/0032-3861(93)90864-7 ↗
26. [26] R. Cai, J. Preston, E. T. Samulski, Macromolecules, 25, 563 (1992).10.1021/ma00028a012 ↗