Polymerization and Characterization of a Bio-Based Vinyl Polymer Based on 5-Hydroxymethylfurfural Including a Benzoyl Group as a Side Chain
Source abstract
Abstract
Synthesis of a vinyl polymer with a benzoyl substituent in its side chain based on 5-(hydroxymethyl) furfural (HMF) was accomplished via free radical polymerization. The HMF derivative, 5-(benzoyloxymethyl) furfural, was efficiently converted to its vinyl derivative by the Wittig reaction. Then, vinyl polymer was synthesized by free radical polymerization using azobisisobutyronitrile (AIBN) initiator in a solution polymerization process. The structures of the obtained vinyl monomer and resulting polymer were confirmed byusingFouriertransforminfrared,1Hnuclearmagneticresonance(NMR),and13CNMRspectroscopy.The productwassubjectedtoGPC,thermogravimetricanalysis,differentialscanningcalorimetry,andX-raydiffractometry.
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Research context
OpenAlex topics: Catalysis for Biomass Conversion · Biofuel production and bioconversion · Enzyme Catalysis and Immobilization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
United Graduate School ofAgricultural Science, Tokyo University ofAgriculture and Technology
Graduate School ofAgricultural Science, Tokyo University of Agriculture and Technology
References (25)
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