Radical Copolymerization of Ferulic Acid Derivatives with Ethylenic Monomers
Source abstract
Abstract
Bio‐based ferulic acid (FA), (E)‐3‐(4‐hydroxy‐3‐methoxyphenyl)prop‐2‐enoic acid was converted to 1,2‐disubstituted ethylenic monomer (FA1) via methyl esterification followed by silylation with tert‐butyldimethylsilyl chloride. Radical copolymerization of FA1 with styrene (St), methyl methacrylate (MMA), and 4‐acetoxy‐3‐methoxystyrene (FA2) prepared from FA were carried out using azobisisobutyronitrile as an initiator at 80℃. It is found that FA1 was copolymerized with St and FA2, but not with MMA. The formation of copolymers was confirmed by 1H‐ and 13C‐NMR analyses. The reactivity ratios of FA1 and St estimated by the Fineman‐Ross method are rFA1=0.12 and rSt=2.46. In the case of the copolymerization of FA1 with FA2, the reactivity ratios, rFA1=0.13 and rFA2=2.66 were determined.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Biochemical and biochemical processes · Carbon dioxide utilization in catalysis · Oxidative Organic Chemistry Reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Graduate School of Bio‐Applications and Systems Engineering, Tokyo University of Agriculture and Technology
Department of Advanced Material and Chemical Engineering, Faculty of Engineering, Halla University
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