Chemical and Rheological Characteristics of Thermally Stable Kraft Lignin Polycondensates Analyzed by Dielectric Properties

In light of the difficulties and disagreements in determining the property-processing structure relations of lignin-based polymers, dielectric analysis was used to identify the thermal and rheological characteristics of a lignin-based polycondensate and the pristine lignin. Using dielectric analysis, the pristine lignin with M w =6000 g/mol, was clearly identified as giving the wet glass transition temperature (T g,wet ) and the evolution of gases (i.e., burning) at around 80 o C to 125 o C followed by subsequent cross-linking reactions over 150 o C to give the dry glass transition temperature (T g,dry ) of lignin at around 130 o C to 140 o C. Connecting the lignin macromers using sequential condensation reactions with caprolactone and sebacoyl chloride, the lignin based polycaprolactone (LigPCL) polycondensates were synthesized as a thermoplastic polymer composed of lignin macromers and aliphatic polyester chains with M w =10500 g/mol. The synthesized LigPCL presented good thermal stability and rheological melting behavior without evolving odor or fumes. In particular, the T 2% (defined at 2% of weight loss) of the LigPCL and pristine lignin were 200 o C and 80 o C, respectively. The melt viscosity was measured at 10 3 Pa . s at 120 o C, ensuring facile melt-blending processing with various commodity polymers to be used in ecofriendly polymer composite development.