journal article·2011-12Open access

Enhanced activity of hierarchical zeolitic material with ZSM-5 structure for the tert-butylation of phenol

Hsiu-Ling Hsu, L. Selva Roselin, Rosilda Selvin, Mohamed Bououdina

Abstract

Nanocrytsalline phase of hierarchical zeolite structure with ZSM-5 was successfully synthesised via a facile and new method using NR latex as a polymer macrotemplate for the liquid phase alkylation of phenol with tert-butanol. X-ray diffraction pattern, FT-IR spectrum and TEM observations confirm the formation of pure and nanocrystalline zeolite ZSM-5 phase. Catalysis measurements show that the prepared zeolite ZSM-5 phase leads to high phenol conversion and 2,4-di-TBP selectivity which is mainly due to the presence of the hierarchical porosity within the zeolite ZSM-5 phase as confirmed by FESEM and pore size analyses.
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Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Mesoporous Materials and Catalysis · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

a Department of Chemical and Materials Engineering , Lunghwa University of Science and Technology , 300 Sector 1, Wanshou Road, Kueishan , Taoyuan , Taiwan (ROC)

b Innovation Centre , Don Bosco Institute of Technology , Kurla (W) , Mumbai 400070 , India

c Nanotechnology Center , University of Bahrain , PO Box 32038, Sakhir , Kingdom of Bahrain

d Department of Physics , College of Science, University of Bahrain , PO Box 32038, Sakhir , Kingdom of Bahrain

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