journal article·2008-09Open access

Nanoclay Reinforced Fibers and Nonwovens

Gajanan Bhat, Raghavendra R. Hegde, M.G. Kamath, Bhushan Deshpande

Abstract

In this research, polypropylene fibers and nonwoven samples were produced with the commercial samples of nanoclay additives in semi-commercial processing machinery. Influence of two different types of nanoclay additives, at different add on levels on processing, structure and morphology of nonwovens is studied. The WAXD and DSC data showed some change in crystallinity and melting behavior indicating changes in the fiber morphology towards improved mechanical properties. Presence and extent of exfoliation of nanoclay in the polymer was verified using transmission electron microscopy (TEM). TEM image reveals intercalated and exfoliated morphology of nanocomposites. About 10 to 20 % increase in tensile strength and modulus in both machine and cross directions is observed. This increase in strength is not accompanied by a decrease in breaking elongation as is the case for most of the fibers. Similarly 10 to 25 % increase in web stiffness and 20 to 80 % increase in web burst strength was observed. Furthermore there is improvement in other performance properties of the spunbond nonwovens. SEM images showed improved thermal bonding in the presence of nanoclay additives. The main advantage of this process is that these fabrics can be produced without any need for change in the processing equipment. This study has shown that by using a suitable compounding method, nanoparticle reinforced fibers and fibrous products with improved performance properties can be produced using conventional production machinery.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Natural Fiber Reinforced Composites · Textile materials and evaluations

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

The University of Tennessee, Knoxville, Tennessee USA

Techmer PM, Clinton, Tennessee USA

References (42)

Show source-provided references
1. Khanna S. N. · Handbook of Nanophase Materials · 1997 · 12
2. Huber C. A. · Handbook of Nanophase Materials · 1997 · 317
3. 10.1177/002199830606732110.1177/0021998306067321 ↗
4. Nanoclays, Technical Physical Properties Bulletin-Closite 15A, Retrieved from, http://www.nanoclay.com/products.html February 2005.
5. Commercial, Retrieved from, http://www.nanocor.com/nanoclays.asp, February 2005.
6. Nanoclays, Technical Physical Properties Bulletin, Retrieved from http://www.nanoclay.com/product_bulletins. asp March 19, 2008
7. Nanoclays, Technical Physical Properties Bulletin, Retrieved from http://www.nanoclay.com/product_bulletins.asp March 19, 2008.
8. US Patent #6462122, Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants, October 2002.
9. 10.1021/cm00059a02310.1021/cm00059a023 ↗
10. 10.1016/S0032-3861(02)00400-710.1016/S0032-3861(02)00400-7 ↗
11. 10.1016/S0032-3861(00)00414-610.1016/S0032-3861(00)00414-6 ↗
12. 10.1016/S0032-3861(01)00473-610.1016/S0032-3861(01)00473-6 ↗
13. 10.1016/S0032-3861(02)00638-910.1016/S0032-3861(02)00638-9 ↗
14. 10.1021/ma960550a10.1021/ma960550a ↗
15. 10.1016/S0032-3861(03)00344-610.1016/S0032-3861(03)00344-6 ↗
16. Industry News, Nanocomposite alternative to traditional PP, Retrieved from, http://www.specialchem4polymers.com/resources.asp, May 2007.
17. Stewart, Richard, Nanocomposites: microscopic reinforcements boost polymer performance, Plastics engineering, 01-MAY-04 Retrieved from http://goliath.ecnext.com/coms2/gi_0199-396198/Nanocomposites-microscopic-reinforcements-boost-polymer.html April 9, 2008.
18. 10.1016/S0032-3861(01)00561-410.1016/S0032-3861(01)00561-4 ↗
19. Zhang X. · JAPS · 2004 · 92 · 552
20. BhatG.S., and HegdeR. R., Effect of Nanoclay Reinforcement on Polymer Structure and Properties, poster presented at Fiber society Spring 2007 conference.
21. 10.1557/JMR.1993.118510.1557/JMR.1993.1185 ↗
22. 10.1002/app.1993.07049071510.1002/app.1993.070490715 ↗
23. 10.1016/S0169-1317(99)00013-710.1016/S0169-1317(99)00013-7 ↗
24. 10.1016/j.polymer.2004.06.02510.1016/j.polymer.2004.06.025 ↗
25. Nanoclays, Retrieved from, http://www.nanoclay.com/main2.html February (2005).
26. INDA Book of Standard Test Methods, INDA, 2001.
27. DSC evaluations, METTLER TOLEDO DSC 822e STARe Software user manual.
28. 10.1002/pi.190110.1002/pi.1901 ↗
29. Annul Book of ASTM Standards Vol. 7.01 (1999).
30. 10.1021/ma000565f10.1021/ma000565f ↗
31. 10.1002/app.1994.07054080810.1002/app.1994.070540808 ↗
32. Hatzikiriakos S. G. · Polymer Engineering and Science · 2005 · 1099
33. Mezghani K. · MS Thesis · 1995 · 12
34. 10.1016/0032-3861(61)90021-010.1016/0032-3861(61)90021-0 ↗
35. 10.1002/macp.1964.02075011310.1002/macp.1964.020750113 ↗
36. Kojima M. · J. Polym. Sci. · 1968 · 2 · 1255
37. Maiti Pralay · Volume 42 · 2002 · 9 · 1864
38. 10.1016/j.polymer.2004.06.02510.1016/j.polymer.2004.06.025 ↗
39. BhatG.S., and HegdeR.R., Thermal Bonding of Polypropylene Films and Fibers, in press in JAPS.
40. 10.1016/S0927-796X(00)00012-710.1016/S0927-796X(00)00012-7 ↗
41. 10.1016/S0040-6031(00)00672-910.1016/S0040-6031(00)00672-9 ↗
42. Bhat G.S. · Vol. · 2004 · 92 · 3593