Improving the properties of the polyester fabrics by grafting with 3-chloro-2-hydroxypropyl acrylate
Source abstract
Abstract
3-chloro-2-hydroxypropyl acrylate obtained by the esterification of epichlorohydrin with acrylic acid in the presence of zirconium silicate as a catalyst was used for grafting of the polyester fabric in order to improve some of its properties. The grafting was performed in the presence of (NH 4 ) 2 S 2 O 8 as a polymerization initiator. The grafted samples were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy analyses. The effect of grafting on the comfort indices (hygroscopicity and vapor permeability) and the tinctorial properties (color intensity and dyeing fastness) were analyzed. Further addition of AgNO 3 in the final reaction mixture used for grafting of polyester fabric confers antibacterial effect to the treated samples. The properties of the polyester fabric were highly improved by grafting with 3-chloro-2-hydroxypropyl acrylate.
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Research context
OpenAlex topics: biodegradable polymer synthesis and properties · Advanced Polymer Synthesis and Characterization · Antimicrobial agents and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Gheorghe Asachi Technical University of Iasi, Iasi, Romania
Petru Poni Institute of Macromolecular Chemistry, Iasi, Romania
Funding
TUIASI research grant
References (31)
Show source-provided references
1. 10.1002/app.1982.07027113510.1002/app.1982.070271135 ↗
2. 10.1002/app.1987.07033021510.1002/app.1987.070330215 ↗
3. 10.1007/s10692-005-0061-110.1007/s10692-005-0061-1 ↗
4. 10.1002/app.2806110.1002/app.28061 ↗
5. Jantas R, Stefan P. Modifying of polyester fabric surface with polyelectrolyte nanolayers using the layer-by-layer deposition technique. Fib Text East Eur 2007; 15(2): 97–99.
6. Natarajan S, Jeyakodi Moses S. Surface modification of polyester fabric using polyvinyl alcohol in alkaline medium. Indian J Fibre Text 2012; 37: 287–291.
7. Gupta D, Chaudhary H, Gupta C. Sericin-based polyester textile for medical applications. J Text I 2014; 10(5): 1–11.
8. 10.1007/BF0287576410.1007/BF02875764 ↗
9. 10.1177/20412479140050030310.1177/204124791400500303 ↗
10. 10.1016/0032-3861(78)90197-010.1016/0032-3861(78)90197-0 ↗
11. 10.1007/s12221-010-1159-510.1007/s12221-010-1159-5 ↗
12. 10.1080/0040500100367236610.1080/00405001003672366 ↗
13. 10.1016/j.jmatprotec.2005.11.02210.1016/j.jmatprotec.2005.11.022 ↗
14. 10.1002/app.3061810.1002/app.30618 ↗
15. 10.1021/i300017a01810.1021/i300017a018 ↗
16. Khalifa IB, Ladhari N. Enhancement of poly(ethylene terephtalate) adsorption using a green process. Int J New Technol Res 2016; 2(3): 49–53.
17. Azizinejad F, Talu M, Abdouss M, et al. An investigation of the grafting of acrylic acid/methyl methacrylate mixture onto poly(ethylene terephthalate) fibres. Iran Polym J 2005; 14(1): 33–38.
18. 10.1002/(SICI)1097-4628(19981128)70:9<1701::AID-APP7>3.0.CO;2-K10.1002/(SICI)1097-4628(19981128)70:9<1701::AID-APP7>3.0.CO;2-K ↗
19. Azizinezhad F. Kinetic investigation of grafting of acrylamide/2-hydroxypropyl methacrylate mixture onto poly (ethylene terephthalate) fibers. B Environ Pharmacol Life Sci 2014; 3(6): 176–183.
20. 10.1016/j.eurpolymj.2007.01.00210.1016/j.eurpolymj.2007.01.002 ↗
21. 10.1007/s00289-006-0719-810.1007/s00289-006-0719-8 ↗
22. 10.1016/j.reactfunctpolym.2008.09.00810.1016/j.reactfunctpolym.2008.09.008 ↗
23. Abdolahifard M, Hajir Bahrami S, Malek RMA. Surface modification of PET fabric by graft copolymerization with acrylic acid and its antibacterial properties. Int Scholar Res Notic 2011; 2: 1–8.
24. El-Gendiy EH. Modification of polyester fabric via radiation grafting with methacrylic acid. Indian J Fibre Text 2004; 29(6): 129–137.
25. 10.1007/BF0236105810.1007/BF02361058 ↗
26. Chinta SK, Kumar R. Processing problems of polyester and its remedies. Int J New Technol Res 2012; 1(7): 1–19.
27. El-Sheemy NS, El-Hawary NS, El-Sayed H. Basic and reactive-dyeable polyester fabrics using lipase. J Chem Eng Process Technol 2016; 7(1): 1–5.
28. 10.2298/CICEQ101205022H10.2298/CICEQ101205022H ↗
29. Najafzadeh N, Habibi S, Ghasri MA. Dyeing of polyester with reactive dyestuffs using nano-chitosan. J Eng Fib Fab 2018; 47(13): 47–51.
30. 10.1016/j.apcata.2018.02.02410.1016/j.apcata.2018.02.024 ↗
31. 10.1093/ajcp/45.4_ts.49310.1093/ajcp/45.4_ts.493 ↗