journal article·2010-06-16

Synthesis and Characterization of Furazan Energetics ADAAF and DOATF

Jacqueline M. Veauthier, David E. Chavez, Bryce C. Tappan, Damon A. Parrish

Journal of Energetic Materials· Volume 28· Issue 3
Publisher page

Abstract

The synthesis and structural characterization of bis[4-aminofurazanyl-3-azoxy]azofurazan (ADAAF) and 3,4:7,8:11,12:15,16-tetrafurazano-1,2,5,6,9,10,13,14-octaazacyclohexadeca-1,3,5,7,9,11,13,15-octaene-1,10-dioxide (DOATF) are described. Explosive sensitivity properties of both materials were determined. The heat of formation of ADAAF was measured to be 300 kcal/mol and the detonation velocity and pressure of ADAAF were measured to be 7.88 km/s and 299 kbar, respectively, at 94% theoretical maximum density. We also investigated the burning rate characteristics of ADAAF.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Energetic Materials and Combustion · Thermal and Kinetic Analysis · Chemical Thermodynamics and Molecular Structure

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

a Chemistry and Weapon Experiments Materials Divisions, Los Alamos National Laboratory , Los Alamos, New Mexico, USA

b Naval Research Laboratory, Laboratory for the Structure of Matter , Washington, DC, USA

References (24)

Show source-provided references
1. Coburn M. D. · Journal of Heterocyclic Chemistry · 1968 · 5 · 8310.1002/jhet.5570050114 ↗
2. Solodyuk G. D. · Zh. Org. Khim. · 1981 · 17 · 756
3. Novikova T. S. · Mendeleev Communications · 1994 · 4 · 13810.1070/MC1994v004n04ABEH000386 ↗
4. 10.1002/jhet.557032045210.1002/jhet.5570320452 ↗
5. Batog L. V. · Mendeleev Communications · 1996 · 5 · 19310.1070/MC1996v006n05ABEH000641 ↗
6. Batog L. V. · Russian Chemical Bulletin · 1996 · 45 · 118910.1007/BF01431618 ↗
7. Eman V. E. · Mendeleev Communications · 1996 · 2 · 6610.1070/MC1996v006n02ABEH000583 ↗
8. Batog L. V. · Chemistry of Heterocyclic Compounds · 1996 · 32 · 35210.1007/BF01169258 ↗
9. Eman V. A. · Mendeleev Communications · 1997 · 7 · 510.1070/MC1997v007n01ABEH000672 ↗
10. 10.1080/0737065000821612110.1080/07370650008216121 ↗
11. Sheremetev , A. B. N. S. Aleksandrova , and V. O. Kulagina . 2005. Method for preparing 4,4′-bis-[4-aminofurazan-3-yl-N(O)N-azoxy]-3,3′-azofurazine and its applying as thermostable explosive substance. Russian Patent Application RU2248354.
12. Sheremetev A. B. · Russian Chemical Bulletin, International Edition · 2002 · 51 · 153310.1023/A:1020931511013 ↗
13. Li Z. · Hanneng Cailiao · 2007 · 15 · 6
14. Chen F.-E. · Synthesis · 2003 · 17 · 262910.1055/s-2003-42431 ↗
15. (a) Gilardi , R. 1999 . Private communication. The Cambridge Structural Database. (b) Allen, F.H. Acta Crystallographica, B58: 380–388, 2002 .
16. Beal R. W. · Propellants, Explosives, Pyrotechnics · 2000 · 25 · 27710.1002/1521-4087(200012)25:6<277::AID-PREP277>3.0.CO;2-P ↗
17. 10.1107/S0365110X6500107X10.1107/S0365110X6500107X ↗
18. Fried E. · 2004
19. 10.1002/prep.20060002310.1002/prep.200600023 ↗
20. Bruker . 2001a. SMART, v5.625. Madison , WI : Bruker AXS Inc.
21. Bruker · 2002
22. Bruker . 2001b . XPREP, v6.14 . Madison , WI : Bruker AXS Inc .
23. Bruker · 2000
24. Bruker · 2000