Relationship between detonation characteristics and15N NMR chemical shifts of nitramines
Source abstract
Abstract
Abstract The paper presents 15N NMR chemical shifts δ of twenty three nitramines out of which 1-nitro-1-azaethylene (DIGEN), 1,3-dinitro-1,3-diazacyclobutane (TETROGEN) and 1,3,5,7,9-pentanitro-1,3,5,7,9-pentaazacyclodecane (DECAGEN) have not been synthesized yet. The corresponding δ values of these three substances have been predicted. The relationship has been confirmed between squares of detonation velocities or, as the case may be, the detonation heats and δ values of nitrogen atoms in nitro group of the nitramines. This relationship represents a certain form of Evans-Polanyi-Semenov equation and such it directly specifies the most reactive nitro group of nitramine molecule in the detonation and, hence, the N-NO2 bond primarily split in this process.
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Research context
OpenAlex topics: Energetic Materials and Combustion · Combustion and Detonation Processes · Thermal and Kinetic Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
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