journal article·2025-02Open access

High-energy storage properties over a broad temperature range in La2O3-modified intermediate shell of BSZT-based lead-free ceramics

Rong Ma, Tongyao Pang, Min Xi, Shuo Song, Jinhong Li, Shuhua Liu, Bin Cui, Dongmei Wang, Weiwei Zhao, Weixing Zhao, Zhuonan Huang, Dengwei Hu

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Dielectric materials and actuators · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Ye W, Zhu C, Xiao Y, Bai X, Zheng P, Zhang J, Bai W, Fan Q, Zheng L, Zhang Y (2023) Remarkable energy-storage performances and excellent stability in CaTiO3-doped BiFeO3-BaTiO3 relaxor ferroelectric ceramics. J Eur Ceram Soc 43:900–908. https://doi.org/10.1021/acsami.7b0417510.1021/acsami.7b04175 ↗
2. Deng T, Zhang YL, Zeng XY, Chen FK, Yan Y, Li Y, Tang MY, Zhang LY, Jin L, Liu G (2023) Excellent dielectric energy storage properties of barium titanate based Pb-free ceramics through composition modification and processing improvement. Ceram Int 49:19003–19011. https://doi.org/10.1016/j.ceramint.2023.03.02510.1016/j.ceramint.2023.03.025 ↗
3. Bai M, Qiao W, Mei J, Kang R, Gao Y, Wu Y, Hu Y, Li Y, Hao X, Zhao J, Hu H (2024) High-performance energy storage in BaTiO3-based oxide ceramics achieved by high-entropy engineering. J Alloy Compd 970:172671. https://doi.org/10.1016/j.jallcom.2023.17267110.1016/j.jallcom.2023.172671 ↗
4. Lan D, Wang Y, Wang Y, Zhu X, Li H, Guo X, Ren J, Guo Z, Wu G (2023) Impact mechanisms of aggregation state regulation strategies on the microwave absorption properties of flexible polyaniline. J Colloid Interface Sci 651:494–503. https://doi.org/10.1016/j.jcis.2023.08.01910.1016/j.jcis.2023.08.019 ↗
5. Liu Y, Cui B, Wang Y, Ma R, Shangguan MQ, Zhao XT, Wang SH, Li QY, Wang YY (2016) Core-shell structure and dielectric properties of Ba0.991Bi0.006TiO3@Nb2O5-Co3O4 Ceramics. J Am Ceram Soc 99:1664–1670. https://doi.org/10.1016/j.jallcom.2023.17267110.1016/j.jallcom.2023.172671 ↗
6. Fei B, Yang H, Yang J, Wang D, Guo H, Hou H , Melhi S, Xu B, Thabet H, Guo Z , Shi Z (2025) Sustainable compression-molded bamboo fibers/poly (lactic acid) green composites with excellent UV shielding performance. J Mater Sci Technol 247–257. https://doi.org/10.1016/j.jmst.2024.03.07410.1016/j.jmst.2024.03.074 ↗
7. Chu B, Zhou X, Ren K, Neese B, Lin M, Wang Q, Bauer F, Zhang Q (2006) A dielectric polymer with high electric energy density and fast discharge speed. Science 313:334–336. https://doi.org/10.1126/science.112779810.1126/science.1127798 ↗
8. Lang R, Chen Q, Gao T, Zhu J, Xing J, Chen Q (2024) BaTiO3-based lead-free relaxor ferroelectric ceramics for high energy storage. J Eur Ceram Soc 44:3916–3925. https://doi.org/10.1016/j.jeurceramsoc.2024.01.00410.1016/j.jeurceramsoc.2024.01.004 ↗
9. Ma R, Cui B, Hu D, El-Bahy SM, Wang Y, Azab IHE, Elnaggar AY, Gu H, Mersal GA, Huang M, Murugadoss V (2022) Enhanced energy storage of lead-free mixed oxide core double-shell barium strontium zirconate titanate@magnesium aluminate@zinc oxide-boron trioxide-silica ceramic nanocomposites. Adv Compos Hybrid Mater 5:1477–1489. https://doi.org/10.1007/s42114-022-00509-z10.1007/s42114-022-00509-z ↗
10. Lu DY, Sun XY, Toda M (2007) A novel high-k ‘Y5V’ barium titanate ceramics co-doped with lanthanum and cerium. J Phys Chem Solids 68:650–664. https://doi.org/10.1016/j.jpcs.2007.02.01810.1016/j.jpcs.2007.02.018 ↗
11. Aly KA, Athikesavan V, Kumar ER, Ebrahium MM (2024) Preparation and study of La-doped bismuth sodium potassium titanate-strontium titanate piezoelectric ceramics to enhance energy storage properties. Ceram Int 50:11676–11687. https://doi.org/10.1016/j.ceramint.2024.01.07110.1016/j.ceramint.2024.01.071 ↗
12. Lu DY, Yue Y, Sun XY (2014) Novel X7R BaTiO3 ceramics co-doped with La3+ and Ca2+ ions. J Alloy Compd 586:136–141. https://doi.org/10.1016/j.jallcom.2013.10.05510.1016/j.jallcom.2013.10.055 ↗
13. Kishi H, Okino Y, Honda M, Iguchi Y, Imaeda M, Takahashi Y, Ohsato H, Okuda T (1997) The effect of MgO and rare-earth oxide on formation behavior of core-shell structure in BaTiO3. Jpn J Appl Phys 36:5954. https://doi.org/10.1143/JJAP.36.595410.1143/JJAP.36.5954 ↗
14. Kishi H, Kohzu N, Sugino J, Ohsato H, Iguchi Y, Okuda T (1999) The effect of rare-earth (La, Sm, Dy, Ho and Er) and Mg on the microstructure in BaTiO3. J Eur Ceram Soc 19:1043–1046. https://doi.org/10.1016/S0955-2219(98)00370-710.1016/S0955-2219(98)00370-7 ↗
15. Alkathy MS, Gatasheh MK, Zabotto FL, Kassim HA, Raju KC, Eiras JA (2024) Enhancing energy storage performance in BaTiO3 ceramics via Mg and La co-doping strategy. J Mater Sci: Mater Electron 35:1–11. https://doi.org/10.1007/s10854-024-12816-w10.1007/s10854-024-12816-w ↗
16. Lu DY, Toda M, Sugano M (2006) High-permittivity double rare-earth-doped barium titanate ceramics with diffuse phase transition. J Am Ceram Soc 89:3112–3123. https://doi.org/10.1111/J.1551-2916.2006.00893.X10.1111/J.1551-2916.2006.00893.X ↗
17. Chu B, Hao J, Li P, Li Y, Li W, Zheng L, Zeng H (2022) High-energy storage properties over a broad temperature range in La-modified BNT-based lead-free ceramics. ACS Appl Mater Interfaces 14:19683–19696. https://pubs.acs.org/doi/https://doi.org/10.1021/acsami.2c01863.10.1021/acsami.2c01863 ↗
18. Kim D, Kim J, Noh T, Ryu J, Kim YN, Lee H (2012) Dielectric properties and temperature stability of BaTiO3 co-doped La2O3 and Tm2O3. Curr Appl Phys 12:952–956. https://doi.org/10.1016/j.cap.2011.12.01610.1016/j.cap.2011.12.016 ↗
19. Zhou Y, Zhang Q, Luo J, Tang Q, Du J (2013) Structural optimization and improved discharged energy density for niobate glass-ceramics by La2O3 addition. J Am Ceram Soc 96:372–375. https://doi.org/10.1111/jace.1215910.1111/jace.12159 ↗
20. Aliouane K, Guehria-Laidoudi A, Simon A, Ravez J (2005) Study of new relaxor materials in BaTiO3/BaZrO3/La2/3TiO3 system. Solid State Sci 7:1324–1332. https://doi.org/10.1016/j.solidstatesciences.2005.06.01010.1016/j.solidstatesciences.2005.06.010 ↗
21. Wang Y, Cui B, Liu Y, Zhao X, Hu Z, Yan Q, Wu T, Zhao L, Wang Y (2014) Fabrication of submicron La2O3-coated BaTiO3 particles and fine-grained ceramics with temperature-stable dielectric properties. Scripta Mater 90:49–52. https://doi.org/10.1016/j.scriptamat.2014.07.01410.1016/j.scriptamat.2014.07.014 ↗
22. Wang J, Jiang S, Jiang D, Tian J, Li Y, Wang Y (2012) Microstructural design of BaTiO3-based ceramics for temperature-stable multilayer ceramic capacitors. Ceram Int 38:5853. https://doi.org/10.1016/j.ceramint.2012.04.03610.1016/j.ceramint.2012.04.036 ↗
23. Shangguan MQ, Cui B, Ma R, Wang YY (2016) Production of Ba0.991Bi0.006TiO3@ZnO-B2O3-SiO2 ceramics with a high dielectric constant, a core-shell structure, and a fne-grained microstructure by means of a sol-precipitation method. Ceram Int 42:7397–7405. https://doi.org/10.1016/j.ceramint.2016.01.14310.1016/j.ceramint.2016.01.143 ↗
24. Shang KL, Shi WJ, Yang YL, Huang YY, Shur V, Laletin V, Zhang LY, Jing RY, Li J (2024) Innovative design of BNKT-xSLZT ceramics: maximizing the polarization difference for enhanced energy storage. ACS Appl Mater Interfaces 16:20485–20496. https://doi.org/10.1021/acsami.4c0134810.1021/acsami.4c01348 ↗
25. Kuang SJ, Tang XG, Li LY, Jiang YP, Liu QX (2009) Influence of Zr dopant on the dielectric properties and Curie temperatures of Ba(ZrxTi1-x)O3 (0 ≤ x ≤ 0.12). ceramics. Scripta Mater 61:68–71. https://doi.org/10.1016/j.scriptamat.2009.03.01610.1016/j.scriptamat.2009.03.016 ↗
26. Makovec D, Drofenik M (2000) Microstructural changes during the reduction/reoxidation process in donor-doped BaTiO3 ceramics. J Am Ceram Soc 83:2593–2599. https://doi.org/10.1111/j.1151-2916.2000.tb01594.x10.1111/j.1151-2916.2000.tb01594.x ↗
27. Buscaglia MT, Buscaglia V, Viviani M, Nanni P, Hanuskova M (2000) Influence of foreign ions on the crystal structure of BaTiO3. J Eur Ceram Soc 20:1997–2007. https://doi.org/10.1016/S0955-2219(00)00076-510.1016/S0955-2219(00)00076-5 ↗
28. Sun C, Wang X, Ma C, Li L (2009) Low-temperature sintering barium titanate-based X8R ceramics with Nd2O3 dopant and ZnO-B2O3 flux agent. J Am Ceram Soc 92:1613–1616. https://doi.org/10.1111/j.1551-2916.2009.03066.x10.1111/j.1551-2916.2009.03066.x ↗
29. Guo J, Sun Y, Li X, Xi S, Ibrahim M, Qiu H, Mersal G, El-Bahy Z, Murugadoss V, Abdul W, Zhou F, Ren J, Guo Z, Zhu J (2024) Hollow core-shell structure Fe3O4@Polypyrrole composites for enhanced electromagnetic wave absorption. Compos Sci Technol 258:110917. https://doi.org/10.1016/j.compscitech.2024.11091710.1016/j.compscitech.2024.110917 ↗
30. Badapanda T, Senthil V, Rout SK, Cavalcante LS, Simões AZ, Sinha TP, Panigrahi S, De Jesus MM, Longo E, Varela JA (2011) Rietveld refinement, microstructure, conductivity and impedance properties of Ba(Zr0.25Ti0.75)O3 ceramic. Curr Appl Phys 11:1282–1293. https://doi.org/10.1016/j.cap.2011.03.05610.1016/j.cap.2011.03.056 ↗
31. Liu W, Zhang S, Almalki F, El-Bahy RJ, Zhao X, Seok I, Guo Z (2024) In situ synthesis of honeycomb nanorods Ni3S2@NiCo-layered-double hydroxide/nickel foam electrocatalysts with high performance electrocatalytic hydrogen production. ACS Appl Energy Mater. https://doi.org/10.1021/acsaem.4c0150110.1021/acsaem.4c01501 ↗
32. Suk-Joong LK (2005) Sintering: densification, grain growth and microstructure. Elsevier Butterworth-Heinemann. https://doi.org/10.1002/9783527631957.ch610.1002/9783527631957.ch6 ↗
33. Badapanda T, Rout SK, Cavalcante LS, Sczancoski JC, Panigrahi S, Longo E, Li MS (2009) Optical and dielectric relaxor behaviour of Ba(Zr0.25Ti0.75)O3 ceramic explained by means of distorted clusters. J Phys D Appl Phys 42: 175414. https://doi.org/10.1088/0022-3727/42/17/17541410.1088/0022-3727/42/17/175414 ↗
34. Hornebecq V, Elissalde C, Weill F, Villesuzanne A, Menetrier M, Ravez J (2000) Study of disorder in a tetragonal tungsten bronze ferroelectric relaxor: a structural approach. J Appl Crystallogr 33:1037–1045. https://doi.org/10.1107/S002188980000512410.1107/S0021889800005124 ↗
35. Chu F, Sun HT, Zhang LY, Yao X (1992) Temperature dependence of ultra-low-frequency dielectric relaxation of barium titanate ceramic. J Am Ceram Soc 75:2939–2944. https://doi.org/10.1111/j.1151-2916.1992.tb04368.x10.1111/j.1151-2916.1992.tb04368.x ↗
36. Liu L, Liu Y, Hao J, Chen J, Li P, Chen S, Fu P, Li W, Zhai J (2023) Multi-scale collaborative optimization of SrTiO3-based energy storage ceramics with high performance and excellent stability. Nano Energy 109:108275. https://doi.org/10.1016/j.nanoen.2023.10827510.1016/j.nanoen.2023.108275 ↗
37. Cole MW, Nothwang WD, Hubbard C, Ngo E, Ervin M (2003) Low dielectric loss and enhanced tunability of Ba0.6Sr0.4TiO3 based thin films via material compositional design and optimized film processing methods. J Appl Phys 93:9218–9225. https://doi.org/10.1063/1.156939210.1063/1.1569392 ↗
38. Li BY, Yan ZN, Zhou XF, Qi H, Koval V, Luo XG, Luo H, Yan HX, Zhang D (2023) Achieving ultrahigh energy storage density of La and Ta Codoped AgNbO3 ceramics by optimizing the field-induced phase transitions. ACS Appl Mater Interfaces 15:4246–4256. https://doi.org/10.1021/acsami.2c2050810.1021/acsami.2c20508 ↗
39. Narang SB, Kaur D, Bahel S (2006) Dielectric properties of lanthanum substituted barium titanate microwave ceramics. Mater Lett 60:3179–3182. https://doi.org/10.1016/j.matlet.2006.02.07910.1016/j.matlet.2006.02.079 ↗
40. Kim J, Kim D, Noh T, Ahn B, Lee H (2011) Microstructure and thermal properties of dysprosium and thulium co-doped barium titanate ceramics for high performance multilayer ceramic capacitors. Mater Sci Eng, B 176:1227–1231. https://doi.org/10.1016/j.mseb.2011.07.00110.1016/j.mseb.2011.07.001 ↗
41. Kumar S, Varma KBR (2009) Influence of lanthanum doping on the dielectric, ferroelectric and relaxor behaviour of barium bismuth titanate ceramics. J Phys D Appl Phys 42:075405. https://doi.org/10.1088/0022-3727/42/7/07540510.1088/0022-3727/42/7/075405 ↗
42. Ganguly M, Parida S, Sinha E, Rout SK, Simanshu AK, Hussain A, Kim IW (2011) Structural, dielectric and electrical properties of BaFe0.5Nb0.5O3 ceramic prepared by solid-state reaction technique. Mater Chem Phys 131:535–539. https://doi.org/10.1016/j.matchemphys.2011.10.01710.1016/j.matchemphys.2011.10.017 ↗
43. Viehland D, Chen YH (2000) Random-field model for ferroelectric domain dynamics and polarization reversal. J Appl Phys 88:6696–6707. https://doi.org/10.1063/1.132500110.1063/1.1325001 ↗
44. Wang T, Jin L, Li CC, Hu QY, Wei XY (2015) Relaxor ferroelectric BaTiO3-Bi(Mg2/3Nb1/3)O3 ceramics for energy storage application. J Am Ceram Soc 98:559–566. https://doi.org/10.1111/jace.1332510.1111/jace.13325 ↗
45. Han F, Bai Y, Qiao LJ, Guo D (2016) A systematic modification of the large electrocaloric effect within a broad temperature range in rare-earth doped BaTiO3 ceramics. J Mater Chem C 4:1842–1849. https://doi.org/10.1039/C5TC04209G10.1039/C5TC04209G ↗
46. Yan F, Bai HR, Ge GL, Lin JF, Shi C, Zhu K, Shen B, Zhai JW, Zhang SJ (2022) Composition and structure optimized BiFeO3-SrTiO3 lead-free ceramics with ultrahigh energy storage performance. Small 18:2106515. https://doi.org/10.1002/smll.20210651510.1002/smll.202106515 ↗