journal article·2025-07

A One-Pot Approach for Synthesizing a Rod-Shaped Photocathode Composed of W(VI) Oxide/Polypyrrole for Sacrificial Agent-Free Green Hydrogen Production

Mohamed Rabia, Maha Abdallah Alnuwaiser

Journal of Electronic Materials· Volume 54· Issue 7
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OpenAlex topics: Advanced Photocatalysis Techniques · Electrocatalysts for Energy Conversion · Ammonia Synthesis and Nitrogen Reduction

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References (41)

Show source-provided references
1. M.A. Giovanniello, A.N. Cybulsky, T. Schittekatte, and D.S. Mallapragada, The influence of additionality and time-matching requirements on the emissions from grid-connected hydrogen production. Nat. Energy 2024, 1 (2024). https://doi.org/10.1038/s41560-023-01435-0.10.1038/s41560-023-01435-0 ↗
2. M. Jovičević-Klug, I.R. Souza Filho, H. Springer, C. Adam, and D. Raabe, Green steel from red mud through climate-neutral hydrogen plasma reduction. Nature 625, 703 (2024). https://doi.org/10.1038/s41586-023-06901-z.10.1038/s41586-023-06901-z ↗
3. P. Constantinou, T.J.Z. Stock, L.-T. Tseng, D. Kazazis, M. Muntwiler, C.A.F. Vaz, Y. Ekinci, G. Aeppli, N.J. Curson, and S.R. Schofield, EUV-induced hydrogen desorption as a step towards large-scale silicon quantum device patterning. Nat. Commun. 15, 1 (2024). https://doi.org/10.1038/s41467-024-44790-6.10.1038/s41467-024-44790-6 ↗
4. C.G. Morales-Guio, S.D. Tilley, H. Vrubel, M. Graẗzel, and X. Hu, Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Nat. Commun. 5, 1 (2014). https://doi.org/10.1038/ncomms4059.10.1038/ncomms4059 ↗
5. C.W. Tsao, S. Narra, J.C. Kao, Y.C. Lin, C.Y. Chen, Y.C. Chin, Z.J. Huang, W.H. Huang, C.C. Huang, C.W. Luo et al., Dual-plasmonic Au@Cu7S4 Yolk@shell nanocrystals for photocatalytic hydrogen production across visible to near infrared spectral region. Nat. Commun. 15, 1 (2024). https://doi.org/10.1038/s41467-023-44664-3.10.1038/s41467-023-44664-3 ↗
6. H. Xie, Z. Zhao, T. Liu, Y. Wu, C. Lan, W. Jiang, L. Zhu, Y. Wang, D. Yang, and Z. Shao, A membrane-based seawater electrolyser for hydrogen generation. Nature 612, 673 (2022). https://doi.org/10.1038/s41586-022-05379-5.10.1038/s41586-022-05379-5 ↗
7. G. Lopez, L. Santamaria, A. Lemonidou, S. Zhang, C. Wu, A.T. Sipra, and N. Gao, Hydrogen generation from biomass by pyrolysis. Nat. Rev. Methods Primers 2, 1 (2022). https://doi.org/10.1038/s43586-022-00113-x.10.1038/s43586-022-00113-x ↗
8. M.M. Ibrahim, G.A.M. Mersal, A.M. Fallatah, K. Althubeiti, H.S. El-Sheshtawy, M.F.A. Taleb, M.R. Das, R. Boukherroub, M.S. Attia, and M.A. Amin, Electrocatalytic hydrogen generation using tripod containing pyrazolylborate-based copper(Ii), nickel(Ii), and iron(Iii) complexes loaded on a glassy carbon electrode. RSC Adv. 12, 8030 (2022). https://doi.org/10.1039/D1RA08530A.10.1039/D1RA08530A ↗
9. D.M. Nerkar, S.E. Jaware, and G.G. Padhye, Fabrication of a novel flexible room temperature hydrogen sulfide (H2S) gas sensor based on polypyrrole films. Int. J. Sci. Res. 5, 2319 (2013).
10. M.M.A. Hamid, M. Alruqi, A.M. Elsayed, M.M. Atta, H.A. Hanafi, and M. Rabia, Testing the photo-electrocatalytic hydrogen production of polypyrrole quantum dot by combining with graphene oxide sheets on glass slide. J. Mater. Sci. Mater. Electron. 34, 1 (2023). https://doi.org/10.1007/S10854-023-10229-9/METRICS.10.1007/S10854-023-10229-9/METRICS ↗
11. S.V.P. Vattikuti, P. Anil, K. Reddy, J. Shim, and C. Byon, Visible-light-driven photocatalytic activity of SnO2-ZnO quantum dots anchored on g-C3N4 nanosheets for photocatalytic pollutant degradation and H2 production. ACS Omega (2018). https://doi.org/10.1021/acsomega.8b00471.10.1021/acsomega.8b00471 ↗
12. X. Huang, M. Zhang, R. Sun, G. Long, Y. Liu, and W. Zhao, Enhanced hydrogen evolution from CuOx-C/TiO2 with multiple electron transport pathways. PLoS ONE 14, e0215339 (2019). https://doi.org/10.1371/JOURNAL.PONE.0215339.10.1371/JOURNAL.PONE.0215339 ↗
13. G. Liu, S.K. Karuturi, H. Chen, D. Wang, J.W. Ager, A.N. Simonov, and A. Tricoli, Enhancement of the photoelectrochemical water splitting by perovskite BiFeO3 via interfacial engineering. Sol. Energy 202, 198 (2020). https://doi.org/10.1016/j.solener.2020.03.117.10.1016/j.solener.2020.03.117 ↗
14. S.I. Al-saeedi, Photoelectrochemical green hydrogen production utilizing ZnO nanostructured photoelectrodes. Micromachines. 14(5), 1047 (2023).10.3390/mi14051047 ↗
15. A. Atta, H. Negm, E. Abdeltwab, M. Rabia, and M.M. Abdelhamied, Facile fabrication of polypyrrole/NiOx core-shell nanocomposites for hydrogen production from wastewater. Polym. Adv. Technol. (2023). https://doi.org/10.1002/PAT.5997.10.1002/PAT.5997 ↗
16. M. Rabia, A.M. Elsayed, and M.A. Alnuwaiser, Cr2S3-Cr2O3/Poly-2-aminobenzene-1-thiol as a highly photocatalytic material for green hydrogen generation from sewage water. Micromachines 14, 1567 (2023). https://doi.org/10.3390/MI14081567.10.3390/MI14081567 ↗
17. M. Rabia, E. Aldosari, and A.H.A. Geneidy, Highly flexible poly-O-aminothiophenol/intercalated iodide composite with highly morphological properties for green hydrogen generation from red sea water. Phys. Scr. 99, 045001 (2024). https://doi.org/10.1088/1402-4896/AD2BC5.10.1088/1402-4896/AD2BC5 ↗
18. A. Helmy, M. Rabia, M. Shaban, A.M. Ashraf, S. Ahmed, and A.M. Ahmed, Graphite/rolled graphene oxide/carbon nanotube photoelectrode for water splitting of exhaust car solution. Int. J. Energy Res. 44, 7687 (2020). https://doi.org/10.1002/er.5501.10.1002/er.5501 ↗
19. Ü. Ecer, A. Zengin, and T. Şahan, Hydrogen generation from NaBH4 hydrolysis catalyzed by cobalt (0)-deposited cross-linked polymer brushes: optimization with an experimental design approach. Int. J. Hydrogen Energy 48, 12814 (2023). https://doi.org/10.1016/J.IJHYDENE.2022.12.224.10.1016/J.IJHYDENE.2022.12.224 ↗
20. F.O. Baydaroglu, E. Özdemir, and A.G. Gürek, Polypyrrole supported co–W–B nanoparticles as an efficient catalyst for improved hydrogen generation from hydrolysis of sodium borohydride. Int. J. Hydrogen Energy 47, 9643 (2022). https://doi.org/10.1016/J.IJHYDENE.2022.01.052.10.1016/J.IJHYDENE.2022.01.052 ↗
21. B. Sun, X. Li, and J. Zheng, Hydrogen generation from nabh4 for portable proton exchange membrane fuel cell. Mater. Rep.: Energy 4, 100248 (2024). https://doi.org/10.1016/J.MATRE.2023.100248.10.1016/J.MATRE.2023.100248 ↗
22. S.K. Sen, S. Dutta, M.R. Khan, M.S. Manir, S. Dutta, A. Al Mortuza, S. Razia, and M.A. Hakim, Characterization and antibacterial activity study of hydrothermally synthesized H-MoO3 nanorods and α-MoO3 nanoplates. BioNanoScience 9, 873 (2019). https://doi.org/10.1007/S12668-019-00671-7/TABLES/3.10.1007/S12668-019-00671-7/TABLES/3 ↗
23. E. Aldosari, M. Rabia, H.A. Ewais, and K. Song, One-pot synthesis of a network of Mn2O3-MnO2-poly(m-Methylaniline) composite nanorods on a polypyrrole film presents a promising and efficient optoelectronic and solar cell device. Open Chem. (2024). https://doi.org/10.1515/chem-2024-0039.10.1515/chem-2024-0039 ↗
24. X. An, J.C. Kays, I.V. Lightcap, T. Ouyang, A.M. Dennis, and B.M. Reinhard, Wavelength-dependent bifunctional plasmonic photocatalysis in Au/chalcopyrite hybrid nanostructures. ACS Nano 16, 6813 (2022). https://doi.org/10.1021/ACSNANO.2C01706/SUPPL_FILE/NN2C01706_SI_001.PDF.10.1021/ACSNANO.2C01706/SUPPL_FILE/NN2C01706_SI_001.PDF ↗
25. M. Valenti, A. Venugopal, D. Tordera, M.P. Jonsson, G. Biskos, A. Schmidt-Ott, and W.A. Smith, hot carrier generation and extraction of plasmonic alloy nanoparticles. ACS Photonics 4, 1146 (2017). https://doi.org/10.1021/acsphotonics.6b01048.10.1021/acsphotonics.6b01048 ↗
26. U. Sharma, S. Karazhanov, R. Jose, and S. Das, Plasmonic hot-electron assisted phase transformation in 2D-MoS2 for the hydrogen evolution reaction: current status and future prospects. J. Mater. Chem. A (2022). https://doi.org/10.1039/D1TA10918A.10.1039/D1TA10918A ↗
27. D.D. Tuan, C.W. Huang, X. Duan, C.H. Lin, and K.Y.A. Lin, Cobalt-based coordination polymer-derived hexagonal porous cobalt oxide nanoplate as an enhanced catalyst for hydrogen generation from hydrolysis of borohydride. Int. J. Hydrogen Energy 45, 31952 (2020). https://doi.org/10.1016/J.IJHYDENE.2020.08.243.10.1016/J.IJHYDENE.2020.08.243 ↗
28. A.A. Bakulin, S. Neutzner, H.J. Bakker, L. Ottaviani, D. Barakel, and Z. Chen, Charge trapping dynamics in PbS colloidal quantum dot photovoltaic devices. ACS Nano 7, 8771 (2013). https://doi.org/10.1021/NN403190S.10.1021/NN403190S ↗
29. M. Rabia, A.M. Elsayed, and M.A. Alnuwaiser, Mn (IV) oxide/Mn (IV) Sulfide/Poly-2-amino-1-mercaptobenzene for green hydrogen generation. Surf. Innov. (2023). https://doi.org/10.1680/JSUIN.23.00031.10.1680/JSUIN.23.00031 ↗
30. M. Shaban, M. Rabia, A.M.A. El-Sayed, A. Ahmed, and S. Sayed, Photocatalytic properties of PbS/graphene oxide/polyaniline electrode for hydrogen generation. Sci. Rep. 7, 1 (2017). https://doi.org/10.1038/s41598-017-14582-8.10.1038/s41598-017-14582-8 ↗
31. S.M. Sayyah, M. Shaban, and M. Rabia, A high-sensitivity potentiometric mercuric ion sensor based on m-toluidine films. IEEE Sens. J. 16, 1541 (2016). https://doi.org/10.1109/JSEN.2015.2505313.10.1109/JSEN.2015.2505313 ↗
32. Y.Q. Qin, Y.Q. Peng, W.F. Yang, Y. Wang, J.W. Cui, and Y. Zhang, Ultrathin exfoliated WS2 nanosheets in low-boiling-point solvents for high-efficiency hydrogen evolution reaction. IOP Conf. Ser.: Mater. Sci. Eng. 770, 012079 (2020). https://doi.org/10.1088/1757-899X/770/1/012079.10.1088/1757-899X/770/1/012079 ↗
33. P.A. Chate, D.J. Sathe, and P.P. Hankare, Electrical, optical and morphological properties of chemically deposited nanostructured tungsten disulfide thin films. Appl. Nanosci. (Switzerland) 3, 19 (2013). https://doi.org/10.1007/S13204-012-0073-0/FIGURES/6.10.1007/S13204-012-0073-0/FIGURES/6 ↗
34. R. Senthilkumar, G. Ravi, C. Sekar, M. Arivanandhan, M. Navaneethan, and Y. Hayakawa, Determination of gas sensing properties of thermally evaporated WO3 nanostructures. J. Mater. Sci. Mater. Electron. 26, 1389 (2015). https://doi.org/10.1007/S10854-014-2552-4/FIGURES/7.10.1007/S10854-014-2552-4/FIGURES/7 ↗
35. A.W. Burton, K. Ong, T. Rea, and I.Y. Chan, On the estimation of average crystallite size of zeolites from the scherrer equation: a critical evaluation of its application to zeolites with one-dimensional pore systems. Microporous Mesoporous Mater. 117, 75 (2009). https://doi.org/10.1016/J.MICROMESO.2008.06.010.10.1016/J.MICROMESO.2008.06.010 ↗
36. A. Morato, V. Rives, Comments on the application of the scherrer equation in “copper aluminum mixed oxide (CuAl MO) catalyst: a green approach for the one-pot synthesis of imines under solvent-free conditions”, by Suib et Al. [Appl. Catal. B: Environ, 188 (2016) 227–234, https://doi.org/10.1016/j.Apcatb.2016.02.007]. Appl. Catal. B: Environ. 202, 418–419 (2017). https://doi.org/10.1016/J.APCATB.2016.09.05010.1016/j.Apcatb.2016.02.007 ↗
37. D.J. Lim, N.A. Marks, and M.R. Rowles, Universal scherrer equation for graphene fragments. Carbon 162, 475 (2020). https://doi.org/10.1016/J.CARBON.2020.02.064.10.1016/J.CARBON.2020.02.064 ↗
38. A.B.G. Trabelsi, A.M. Elsayed, F.H. Alkallas, and M. Rabia, Flower-like Cr2O3-Cr(OH)3/Poly-2-chloroaniline nanocomposite photoelectrode grown on polypyrrole film for hydrogen generation from sewage water. Opt. Quant. Electron. 56, 1 (2024). https://doi.org/10.1007/S11082-023-05306-6/METRICS.10.1007/S11082-023-05306-6/METRICS ↗
39. S. Sharma, D. Kumar, and N. Khare, Plasmonic ag nanoparticles decorated Bi2S3 nanorods and nanoflowers: their comparative assessment for photoelectrochemical water splitting. Int. J. Hydrogen Energy 44, 3538 (2019). https://doi.org/10.1016/j.ijhydene.2018.11.238.10.1016/j.ijhydene.2018.11.238 ↗
40. S.B. Aziz, M.M. Nofal, H.O. Ghareeb, E.M.A. Dannoun, S.A. Hussen, J.M. Hadi, K.K. Ahmed, and A.M. Hussein, Characteristics of Poly(Vinyl Alcohol) (PVA) based composites integrated with green synthesized Al3+-metal complex: structural, optical, and localized density of state analysis. Polymers 13, 1316 (2021). https://doi.org/10.3390/POLYM13081316.10.3390/POLYM13081316 ↗
41. I. Ahmad, S. Shukrullah, M.Y. Naz, H.N. Bhatti, N.R. Khalid, and S. Ullah, Rational design of ZnO–CuO–Au S-scheme heterojunctions for photocatalytic hydrogen production under visible light. Int. J. Hydrogen Energy 48, 12683 (2023). https://doi.org/10.1016/J.IJHYDENE.2022.11.289.10.1016/J.IJHYDENE.2022.11.289 ↗