Investigation of NLO Properties of Eriochrome Black T Colloidal Solution: Role of Surfactant and Reverse Micelles
Source abstract
Abstract
The photophysical and nonlinear optical properties of Eriochrome Black T (EBT) in micelles, with two charge types of surfactant and reverse micelles (RMs) in a wide range of sizes, were investigated via ultraviolet–visible absorption, fluorescence spectroscopy, and a Z-scan technique. Accordingly, a significant redshift in absorbance and fluorescence quenching of the EBT was observed with an increase in cetyltrimethylammonium bromide (CTAB) concentration. Comparably, the nonlinear absorption coefficient (β) of the EBT decreased following an increase in cationic CTAB concentration, due to an increasing trend in the CTAB:EBT complex in the solution, and it decreased following an increase in anionic aerosol OT concentration. The same behavior was further detected for the nonlinear index of refraction (n2). The β value of the EBT also decreased with an increase in the size and concentration of the RMs, while the n2 was enhanced.
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Research context
OpenAlex topics: Nonlinear Optical Materials Studies · Photochemistry and Electron Transfer Studies · Protein Interaction Studies and Fluorescence Analysis
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