Structure and piezoelectric properties of K0.5Na0.5NbO3 based lead-free piezoceramics with slight deviation from A-site K or Na stoichiometry
Source abstract
Abstract
The dependence of structure and piezoelectric response d33 on individual excess A-site K or Na in K0.5Na0.5NbO3 based lead-free piezoceramics is reported. The coexistence of orthorhombic, tetragonal, and monoclinic phases at room temperature is observed in the investigated 0.94K0.5+xNa0.5NbO3–0.06LiNbO3 and 0.94K0.5Na0.5+yNbO3–0.06LiNbO3 ceramics (x, y = 0–0.025). The weight ratio of three phases, orthorhombic-tetragonal phase transition temperature, and d33 value are highly sensitive to A-site K or Na nonstoichiometry. A-site Na nonstiochiometry plays a dominant role in enhancing the electrical properties of KNN by significantly reducing the weight ratio percentage of monoclinic phase and shifting the orthorhombic-tetragonal phase transition temperature to lower temperatures.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Multiferroics and related materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. A. J. Moulson, J. M. Herbert, Electroceramics: materials, properties, applications, Second edn. (John Wiley & Sons, West Sussex, 2003)10.1002/0470867965 ↗
2. R. Guo, L. E. Cross, S. E. Park, B. Noheda, D. E. Cox, G. Shirane, Phys. Rev. Lett. 84, 5423 (2000)10.1103/PhysRevLett.84.5423 ↗
3. J. A. Perez, M. R. Soares, P. Q. Mantas, A. M. R. Senos, J. Eur. Ceram. Soc. 25, 2207 (2005)10.1016/j.jeurceramsoc.2005.03.031 ↗
4. Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Nature (London) 432, 84 (2004)10.1038/nature03028 ↗
5. M. R. Bafandeh, R. Gharahkhani, M. H. Abbasi, A. Saidi, J. S. Lee, H. S. Han, J. Electroceram. 33, 128 (2014)10.1007/s10832-014-9951-z ↗
6. S. Swain, P. Kumar, J. Electroceram. 32, 102 (2014)10.1007/s10832-013-9884-y ↗
7. G. Lévêque, P. Marchet, F. Levassort, L. P. Tran-Huu-Hue, J. R. Duclere, J. Eur. Ceram. Soc. 31, 577 (2011)10.1016/j.jeurceramsoc.2010.10.031 ↗
8. R. López, F. González, M. E. Villafuerte-Castrejón, J. Eur. Ceram. Soc. 30, 1549 (2010)10.1016/j.jeurceramsoc.2009.10.023 ↗
9. F. Rubio-Marcos, P. Ochoa, J. F. Fernandez, J. Eur. Ceram. Soc. 27, 4125 (2007)10.1016/j.jeurceramsoc.2007.02.110 ↗
10. E. Hollenstein, M. Davis, D. Damjanovic, N. Setter, Appl. Phys. Lett. 87, 182905 (2005)10.1063/1.2123387 ↗
11. F. Rubio-Marcos, M. G. Navarro-Rojero, J. J. Romero, P. Marchet, J. F. Fernández, IEEE Trans. Ultrason. Ferroelectr. Freq. Control 56, 1835 (2009)10.1109/TUFFC.2009.1258 ↗
12. Y. J. Dai, X. W. Zhang, K. P. Chen, Appl. Phys. Lett. 94, 042905 (2009)10.1063/1.3076105 ↗
13. Y. Guo, K. I. Kakimoto, H. Ohsato, Appl. Phys. Lett. 85, 4121 (2004)10.1063/1.1813636 ↗
14. Y. H. Lee, J. H. Cho, B. I. Kim, D. K. Choi, J. Appl. Phys. 47, 4620 (2008)10.1143/JJAP.47.4620 ↗
15. L. Zheng, J. Wang, J. Electroceram. 32, 192 (2014)10.1007/s10832-013-9870-4 ↗
16. C. Miclea, C. Tanasoiu, C. F. Miclea, L. Amarande, A. Gheorghiu, I. Spanulescu, C. Plavitu, C. T. Miclea, M. C. Cioangher, L. Trupina, A. Iuga, J. Eur. Ceram. Soc. 27, 4055 (2007)10.1016/j.jeurceramsoc.2007.02.094 ↗
17. M. S. Kim, D. S. Lee, E. C. Park, S. J. Jeong, J. S. Song, J. Eur. Ceram. Soc. 27, 4121 (2007)10.1016/j.jeurceramsoc.2007.02.194 ↗
18. J. G. Wu, D. Q. Xiao, Y. Y. Wang, J. G. Zhu, L. Wu, Y. H. Jiang, Appl. Phys. Lett. 91, 252907–252909 (2007)10.1063/1.2827573 ↗
19. P. Zhao, B. P. Zhang, J. F. Li, Scripta Mater. 58, 429 (2008)10.1016/j.scriptamat.2007.10.028 ↗
20. D. M. Lin, K. W. Kwok, H. L. Chan, J. Am. Ceram. Soc. 92, 2765 (2009)10.1111/j.1551-2916.2009.03239.x ↗
21. N. Zhang, A. M. Glazer, D. Baker, P. A. Thomas, Acta Crystallogr. Sect. B: Struct. Sci. 65, 291 (2009)10.1107/S0108768109011057 ↗
22. S. J. Liu, B. B. Wan, P. F. Wang, S. H. Song, Scripta Mater. 63, 124 (2010)10.1016/j.scriptamat.2010.03.033 ↗
23. F. Rubio-Marcos, P. Marchet, T. Merle-Méjean, J. F. Fernández, Mater. Chem. Phys. 123, 91 (2010)10.1016/j.matchemphys.2010.03.065 ↗
24. N. Klein, E. Hollenstein, D. Damjanovic, H. J. Trodahl, N. Setter, M. Kuball, J. Appl. Phys. 102, 014112 (2007)10.1063/1.2752799 ↗
25. T. A. Skidmore, T. P. Comyn, S. J. Milne, Appl. Phys. Lett. 94, 222902 (2009)10.1063/1.3153157 ↗
26. D. W. Baker, P. A. Thomas, N. Zhang, A. M. Glazer, Appl. Phys. Lett. 95, 091903 (2009)10.1063/1.3212861 ↗
27. D. W. Baker, P. A. Thomas, N. Zhang, A. M. Glazer, Acta Crystallogr. Sect. B: Struct. Sci. 65, 22 (2009)10.1107/S0108768108037361 ↗
28. F. Rubio-Marcos, M. A. Bañares, J. J. Romero, J. F. Fernández, J. Raman Spectrosc. 42, 639 (2011)10.1002/jrs.2753 ↗
29. H. J. Trodahl, N. Klein, D. Damjanovic, N. Setter, B. Ludbrook, D. Rytz, M. Kuball, Appl. Phys. Lett. 93, 262901 (2008)10.1063/1.3056658 ↗
30. R. J. C. Lima, W. Paraguassu, P. T. C. Freire, J. M. Sasaki, F. E. A. Melo, J. Mendes Filho, S. Lanfredi, J. Raman Spectrosc. 42, 639 (2011)10.1002/jrs.2753 ↗
31. H. R. Xia, H. C. Chen, H. Yu, K. X. Wang, B. Y. Zhao, Phys. Stat. Sol. (b) 210, 47 (1998)10.1002/(SICI)1521-3951(199811)210:1<47::AID-PSSB47>3.0.CO;2-W ↗
32. K. H. Cho, H. Y. Park, C. W. Ahn, S. Nahm, J. Am. Ceram. Soc. 90, 1946 (2007)10.1111/j.1551-2916.2007.01715.x ↗
33. Y. H. Zhen, J. F. Li, J. Am. Ceram. Soc. 90, 3496 (2007)10.1111/j.1551-2916.2007.01977.x ↗
34. L. J. Cheng, L. Liu, Q. Ma, S. J. Liu, Scripta Mater. 111, 102 (2016)10.1016/j.scriptamat.2015.08.025 ↗
35. K. H. Härdtl, D. Hennings, J. Am. Ceram. Soc. 55, 230 (1972)10.1111/j.1151-2916.1972.tb11267.x ↗
36. S. J. Liu, V. Zenou, I. Sus, T. Kotani, M. Schilfgaarde, N. Newman, Acta Mater. 55, 2647 (2007)10.1016/j.actamat.2006.12.006 ↗
37. P. Zhao, B. P. Zhang, J. F. Li, J. Am. Ceram. Soc. 91, 1690 (2008)10.1111/j.1551-2916.2008.02322.x ↗
38. P. Zhao, B. P. Zhang, J. F. Li, Appl. Phys. Lett. 90, 242909 (2007)10.1063/1.2748088 ↗
39. J. G. Wu, D. Q. Xiao, Y. Y. Wang, L. Wu, Y. H. Jiang, J. G. Zhu, J. Am. Ceram. Soc. 91, 2385 (2008)10.1111/j.1551-2916.2008.02415.x ↗
40. Y. S. Sung, H. M. Lee, W. Du, H. G. Yeo, S. C. Lee, J. H. Cho, T. K. Song, M. H. Kim, Appl. Phys. Lett. 94, 062901 (2009)10.1063/1.3081018 ↗
41. K. Datta, K. Roleder, P. A. Thomas, Phys. Rev. B 82, 224105 (2010)10.1103/PhysRevB.82.224105 ↗