Synthesis of Co-substituted Mn-Zn ferrite nanoparticles by mechanochemistry approach
Source abstract
Abstract
In this paper, a series of Co-substituted Mn-Zn ferrites with the formula CoxMn0.8-xZn0.2Fe2O4 (x = 0, 0.2, 0.4, 0.6 and 0.8) have been successfully obtained by ultrasonic-assisted ball milling approach. The characterization of the samples has been done by using room temperature X-ray diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM). The XRD results reveal that the formation of single-phrase ferrite fully is completed after 60 h. The TEM analysis confirms that the average size of nanoparticles is about 25–30 nm. A maximum saturation magnetization of 78.7 emu/g is obtained when x = 0.6, which decreases with further Co doping. The changes in fluorescence intensity and conductivity reflect the reaction speed and confirm the coupling effect of ultrasonic and ball milling.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Iron oxide chemistry and applications · Characterization and Applications of Magnetic Nanoparticles
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
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1. R. Arulmurugan, G. Vaidyanathan, S. Sendhilnathan et al., Mn–Zn ferrite nanoparticles for ferrofluid preparation: study on thermal–magnetic properties. J. Magn. Magn. Mater. 298(2), 83–94 (2006)10.1016/j.jmmm.2005.03.002 ↗
2. S. Mukherjee, S. Pradip, A.K. Mishra et al., Zn substituted NiFe2O4 with very high saturation magnetization and negligible dielectric loss synthesized via a soft chemical route. Appl. Phys. A 116(1), 389–393 (2014)10.1007/s00339-013-8140-2 ↗
3. I. Sharifi, H. Shokrollahi, M.M. Doroodmand et al., Magnetic and structural studies on CoFe2O4 nanoparticles synthesized by co-precipitation, normal micelles and reverse micelles methods[J]. J. Magn. Magn. Mater. 324, 1854–1861 (2012)10.1016/j.jmmm.2012.01.015 ↗
4. J. Joseph, R.B. Tangsali, V.P.M. Pillai et al., Structure and magnetic properties of highly textured nanocrystalline Mn–Zn ferrite thin film. Phys. B Condens. Matter 456, 293–297 (2015)10.1016/j.physb.2014.09.015 ↗
5. S.N. Dolia, Role of particle size on structural and magnetic behavior of nanocrystalline cu-ni ferrite. Solid State Phenom. 171, 79–91 (2011)10.4028/www.scientific.net/SSP.171.79 ↗
6. A. Meffre, B. Mehdaoui, V. Kelsen et al., A simple chemical route toward monodisperse iron carbide nanoparticles displaying tunable magnetic and unprecedented hyperthermia properties. Nano Lett. 12(9), 4722–4728 (2012)10.1021/nl302160d ↗
7. F. Peinado, E. Medel, R. Silvestre et al., Open-grade wearing course of asphalt mixture containing ferrite for use as ferromagnetic pavement. Compos. Part B 57, 262–268 (2014)10.1016/j.compositesb.2013.10.008 ↗
8. M. Frivaldsky, P. Spanik, P. Drgona et al., Influence of transformer core geometry on the qualitative indexes of front-end converters. ELEKTRO, 2014. IEEE 2014, 170–175 (2014)
9. Y. Liu, S. Wei, H. Tian et al., Characterization of soft magnetic spinel ferrite coating prepared by plasma spray. Surf. Coat. Technol. 258, 189–199 (2014)10.1016/j.surfcoat.2014.09.029 ↗
10. S. Rana, A. Gallo, R.S. Srivastava, R.D.K. Misra, On the suitability of nanocrystalline ferrites as a magnetic carrier for drug delivery: functionalization, conjugation, and drug release kinetics. Acta Biomater. 3, 233–242 (2007)10.1016/j.actbio.2006.10.006 ↗
11. J. Zhang, S. Rana, R.S. Srivastava, R.D.K. Misra, On the chemical synthesis and drug delivery response of folate receptor activated polyethylene glycol-functionalized magnetite nanoparticles. Acta Biomater. 4, 40–48 (2008)10.1016/j.actbio.2007.06.006 ↗
12. Z. Jia, R.D.K. Misra, Magnetic sensors for data storage: perspective and future outlook. Mater. Technol. 26, 191–199 (2011)10.1179/175355511X13109965351077 ↗
13. A. Kumar, P.S. Rana, M.S. Yadav et al., Effect of Gd3+ ion distribution on structural and magnetic properties in nano-sized Mn–Zn ferrite particles. Ceram. Int. 41(1), 1297–1302 (2015)10.1016/j.ceramint.2014.09.060 ↗
14. S.F. Wang, Y.F. Hsu, C.H. Chen, Effects of Nb2O5, TiO2, SiO2, and CaO additions on the loss characteristics of Mn-Zn Ferrite. J. Electroceram. 33(3–4), 172–179 (2014)10.1007/s10832-014-9943-z ↗
15. W.D. Yang, Y.G. Wang, Effects of TiO2 and Co2O3 combination additions on the elemental distribution and electromagnetic properties of Mn–Zn power ferrites. J. Magn. Magn. Mater. 384, 13–17 (2015)10.1016/j.jmmm.2015.02.020 ↗
16. R. Arulmurugan, B. Jeyadevan, G. Vaidyanathan et al., Effect of zinc substitution on Co–Zn and Mn–Zn ferrite nanoparticles prepared by co-precipitation. J. Magn. Magn. Mater. 288, 470–477 (2005)10.1016/j.jmmm.2004.09.138 ↗
17. M.G. Naseri, M.K. Halimah, A. Dehzangi et al., A comprehensive overview on the structure and comparison of magnetic properties of nanocrystalline synthesized by a thermal treatment method. J. Phys. Chem. Solids 75(3), 315–327 (2014)10.1016/j.jpcs.2013.11.004 ↗
18. S.A.S. Ebrahimi, S.M. Masoudpanah, H. Amiri et al., Magnetic properties of MnZn ferrite nanoparticles obtained by SHS and sol–gel autocombustion techniques. Ceram. Int. 40(5), 6713–6718 (2014)10.1016/j.ceramint.2013.11.133 ↗
19. A. Thakur, M. Singh, Preparation and characterization of nanosize Mn0.4 Zn0.6Fe2O4 ferrite by citrate precursor method. Ceram. Int. 29(5), 505–511 (2003)10.1016/S0272-8842(02)00194-3 ↗
20. A. Kale, S. Gubbala, R.D.K. Misra, Magnetic behavior of nanocrystalline nickel ferrite synthesized by the reverse micelle technique. J. Magn. Magn. Mater. 277, 350–358 (2004)10.1016/j.jmmm.2003.11.015 ↗
21. K.M. Reddy, L. Satyanarayana, S.V. Manorama, R.D.K. Misra, A comparative study of the gas behavior of nanostructured nickel ferrite synthesized by hydrothermal and reverse micelle techniques. Mater. Res. Bull. 39, 1491–1498 (2004)10.1016/j.materresbull.2004.04.022 ↗
22. H. Nathani, S. Gubbala, R.D.K. Misra, Magnetic behavior of nickel ferrite-polyethylene nanocomposite synthesized by mechanical milling process. Mater. Sci. Eng. B 111, 95–100 (2004)10.1016/j.mseb.2004.03.002 ↗
23. R.D.K. Misra, A. Kale, B.J. Kooi, J.T.M. De Hosson, Some aspects of nanocrystalline nickel and zinc ferrites processed using microemulsion technique. Mater. Sci. Technol. 19(11), 1617–1621 (2003)10.1179/026708303225008040 ↗
24. R.D.K. Misra, A. Kale, R.S. Srivastava, O.N. Senkov, Synthesis of nanocrystalline nickel and zinc ferrites by micro-emulsion technique. Mater. Sci. Technol. 19(6), 826–830 (2003)10.1179/026708303225003018 ↗
25. D. Chen, D. Li, Z. Kang, Preparation of magnesium ferrite nanoparticles by ultrasonic wave-assisted aqueous solution ball milling. Ultrason. Sonochem. 20(6), 1337–1340 (2013)10.1016/j.ultsonch.2013.04.001 ↗
26. D. Chen, H.Y. Liu, L. Li, One-step synthesis of manganese ferrite nanoparticles by ultrasonic wave-assisted ball milling technology. Mater. Chem. Phys. 134(2), 921–924 (2012)10.1016/j.matchemphys.2012.03.091 ↗
27. Z. Yuan, Z. Chen, D. Chen et al., Analyses of factors affecting nickel ferrite nanoparticles synthesis in ultrasound-assisted aqueous solution ball milling. Ultrason. Sonochem. 22, 188–197 (2015)10.1016/j.ultsonch.2014.07.009 ↗
28. R. Xiao, D. Diaz-Rivera, Z. He et al., Using pulsed wave ultrasound to evaluate the suitability of hydroxyl radical scavengers in sonochemical systems. Ultrason. Sonochem. 20(3), 990–996 (2013)10.1016/j.ultsonch.2012.11.012 ↗
29. R.G. Zepp, B.C. Faust, J. Hoigne, Hydroxyl radical formation in aqueous reactions (pH 3–8) of iron (II) with hydrogen peroxide: the photo-Fenton reaction. Environ. Sci. Technol. 26(2), 313–319 (1992)10.1021/es00026a011 ↗
30. Q.Y. Zhang, P. Zheng, L. Zheng et al., Effect of Co-substitution on the structure and magnetic properties of MnZn power ferrite. J. Electroceram. 32(2–3), 230–233 (2014)10.1007/s10832-013-9878-9 ↗
31. A. Fujita, S. Gotoh, Temperature dependence of core loss in Co-substituted MnZn ferrites. J. Appl. Phys. 93(10), 7477–7479 (2003)10.1063/1.1557952 ↗
32. H. Anwar, A. Maqsood, Comparison of structural and electrical properties of Co2+ doped Mn-Zn soft nano ferrites prepared via coprecipitation and hydrothermal methods. Mater. Res. Bull. 49, 426–433 (2014)10.1016/j.materresbull.2013.09.009 ↗
33. H. Anwar, A. Maqsood, I.H. Gul, Effect of synthesis on structural and magnetic properties of cobalt doped Mn–Zn nano ferrites. J. Alloys Compd. 626, 410–414 (2015)10.1016/j.jallcom.2014.11.177 ↗
34. C.F. Zhang, X.C. Zhong, H.Y. Yu et al., Effects of cobalt doping on the microstructure and magnetic properties of Mn–Zn ferrites prepared by the co-precipitation method. Phys. B Condens. Matter 404(16), 2327–2331 (2009)10.1016/j.physb.2008.12.044 ↗
35. Y.X. Zhang, J.N. Fan, Q. Li et al., A low-temperature method to synthesize Co-Substituted Mn-Zn ferrite nanoparticles with distinct magnetic properties. Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 40(8), 556–562 (2010)10.1080/15533174.2010.503221 ↗
36. J. Xiang, X.Q. Shen, X.F. Meng, Preparation of Co-substituted MnZn ferrite fibers and their magnetic properties. Mater. Chem. Phys. 114(1), 362–366 (2009)10.1016/j.matchemphys.2008.09.037 ↗
37. Q.A. Pankhurst, R.J. Pollard, Origin of the spin-canting anomaly in small ferrimagnetic particles. Phys. Rev. Lett. 67(2), 248 (1991)10.1103/PhysRevLett.67.248 ↗