Recent progress in pyrochlore-based nanocrystalline materials for energy, sensing, and electronic applications
Bibliographic record
Abstract
No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.
Source: Not provided · Quality: missing
Research context
OpenAlex topics: Nuclear materials and radiation effects · Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. A. Ashok, J.P. Singh, A. Kumar, N. Bhagat, Bridging current and future innovations to unlock the potential of multifunctional materials for sustainable energy applications. Mater. Adv. 6, 3386–3415 (2025). https://doi.org/10.1039/D5MA00102A10.1039/D5MA00102A ↗
2. M. Sang, J. Shin, K. Kim, K.J. Yu, Electronic and thermal properties of graphene and recent advances in graphene based electronics applications. Nanomaterials 9, 374 (2019). https://doi.org/10.3390/nano903037410.3390/nano9030374 ↗
3. I.O. Oladele, V.O. Oki, T.F. Omotosho, M.B. Adebanjo, O.T. Ayanleye, S.A. Adekola, Sustainable polymer and polymer-based composite materials for extreme conditions and demanding applications – a review on pushing boundaries in materials science. Next Materials 8, 100775 (2025). https://doi.org/10.1016/j.nxmate.2025.10077510.1016/j.nxmate.2025.100775 ↗
4. M.S. Chavali, M.P. Nikolova, Metal oxide nanoparticles and their applications in nanotechnology. SN Appl. Sci. 1, 607 (2019). https://doi.org/10.1007/s42452-019-0592-310.1007/s42452-019-0592-3 ↗
5. A.-G. Schiopu, D.M. Iordache, M. Oproescu, L.M. Cursaru, A.-M. Ioța, Tailoring the synthesis method of metal oxide nanoparticles for desired properties. Crystals 14, 899 (2024). https://doi.org/10.3390/cryst1410089910.3390/cryst14100899 ↗
6. E.A.R. Assirey, Perovskite synthesis, properties and their related biochemical and industrial application. Saudi Pharm. J. 27, 817–829 (2019). https://doi.org/10.1016/j.jsps.2019.05.00310.1016/j.jsps.2019.05.003 ↗
7. Z. Teng, L. Zhu, Y. Tan, S. Zeng, Y. Xia, Y. Wang, H. Zhang, Synthesis and structures of high-entropy pyrochlore oxides. J. Eur. Ceram. Soc. 40, 1639–1643 (2020). https://doi.org/10.1016/j.jeurceramsoc.2019.12.00810.1016/j.jeurceramsoc.2019.12.008 ↗
8. W. Tang, T. Liu, M. Zhang, F. Yuan, K. Zhou, R. Lai, Y. Lian, S. Xing, W. Xiong, M. Zhang, F. Gao, B. Zhao, D. Di, The roles of metal oxidation states in perovskite semiconductors. Matter 6, 3782–3802 (2023). https://doi.org/10.1016/j.matt.2023.07.01910.1016/j.matt.2023.07.019 ↗
9. J. Wei, J. Mu, Y. Tang, D. Qin, J. Duan, A. Wu, Next-generation nanomaterials: advancing ocular anti-inflammatory drug therapy. J. Nanobiotechnol. 21, 282 (2023). https://doi.org/10.1186/s12951-023-01974-410.1186/s12951-023-01974-4 ↗
10. A.S. Belousov, E.V. Suleimanova, D.G. Fukina, Pyrochlore oxides as visible light-responsive photocatalysts. New J. Chem. 45, 22531–22558 (2021). https://doi.org/10.1039/D1NJ04439G10.1039/D1NJ04439G ↗
11. J.M. Farmer, L.A. Boatner, B.C. Chakoumakos, M.-H. Du, M.J. Lance, C.J. Rawn, J.C. Bryan, Structural and crystal chemical properties of rare-earth titanate pyrochlores. J. Alloys Compd. 605, 63–70 (2014). https://doi.org/10.1016/j.jallcom.2014.03.15310.1016/j.jallcom.2014.03.153 ↗
12. A.F. Fuentes, E.C. O’Quinn, S.M. Montemayor, H. Zhou, M. Lang, R.C. Ewing, Pyrochlore-type lanthanide titanates and zirconates: synthesis, structural peculiarities, and properties. Appl. Phys. Rev. 11, 021337 (2024). https://doi.org/10.1063/5.019241510.1063/5.0192415 ↗
13. M. Jafar, S.B. Phapale, S. Nigam, S.N. Achary, R. Mishra, C. Majumder, A.K. Tyagi, Implication of aliovalent cation substitution on structural and thermodynamic stability of Gd2Ti2O7: experimental and theoretical investigations. J. Alloys Compd. 859, 157781 (2021). https://doi.org/10.1016/j.jallcom.2020.15778110.1016/j.jallcom.2020.157781 ↗
14. P. Tang, Y. Cao, H. Li, M. Lu, W. Qiu, The preparation of high-performance aqueous supercapacitor with high-entropy pyrochlore-type electrode and super-concentrated electrolyte. Ceram. Int. 48, 2660–2669 (2022). https://doi.org/10.1016/j.ceramint.2021.10.05010.1016/j.ceramint.2021.10.050 ↗
15. M.Y. Tashlanov, S.N. Marshenya, A.A. Golubnichiy, D.A. Aksyonov, E.V. Antipov, S.S. Fedotov, Low-strain, long-life and high-power K-ion anode material enabled by a pyrochlore-type framework with facile 3D isotropic diffusion. J. Power Sources 629, 236042 (2025). https://doi.org/10.1016/j.jpowsour.2024.23604210.1016/j.jpowsour.2024.236042 ↗
16. A. Aimi, H. Onodera, Y. Shimonishi, K. Fujimoto, S. Yoshida, High Li-ion conductivity in pyrochlore-type solid electrolyte Li2–xLa(1+x)/3M2O6F (M = Nb, Ta). Chem. Mater. 36, 3717–3725 (2024). https://doi.org/10.1021/acs.chemmater.3c0328810.1021/acs.chemmater.3c03288 ↗
17. A.P. Anantharaman, H.P. Dasari, Potential of pyrochlore structure materials in solid oxide fuel cell applications. Ceram. Int. 47, 4367–4388 (2021). https://doi.org/10.1016/j.ceramint.2020.10.01210.1016/j.ceramint.2020.10.012 ↗
18. B. Choudhary, L. Besra, S. Anwar, S. Anwar, La2Ce2O7 based materials for next generation proton conducting solid oxide cells: progress, opportunity and future prospects. Int. J. Hydrogen Energy 48, 28460–28501 (2023). https://doi.org/10.1016/j.ijhydene.2023.03.39310.1016/j.ijhydene.2023.03.393 ↗
19. F. Zhong, J. Zhao, L. Shi, Y. Xiao, G. Cai, Y. Zheng, J. Long, Alkaline-earth metals-doped pyrochlore Gd2Zr2O7 as oxygen conductors for improved NO2 sensing performance. Sci. Rep. 7, 4684 (2017). https://doi.org/10.1038/s41598-017-04920-110.1038/s41598-017-04920-1 ↗
20. M. Ganesan, V. Jayaraman, P. Selvaraj, K.M. Mani, D.-H. Kim, Pyrochlore cerium stannate (Ce2Sn2O7) for highly sensitive NO2 gas sensing at room temperature. Appl. Surf. Sci. 624, 157135 (2023). https://doi.org/10.1016/j.apsusc.2023.15713510.1016/j.apsusc.2023.157135 ↗
21. M. Zhang, Z. Tang, H. Zhang, G. Smith, Q. Jiang, T. Saunders, B. Yang, H. Yan, Characterization of microwave and terahertz dielectric properties of single crystal La2Ti2O7 along one single direction. J. Eur. Ceram. Soc. 41, 7375–7379 (2021). https://doi.org/10.1016/j.jeurceramsoc.2021.07.05910.1016/j.jeurceramsoc.2021.07.059 ↗
22. I. Bala, S.K. Barbar, M. Roy, Synthesis, structural and electrical properties of Ti modified Bi2Sn2O7 pyrochlore. Phys. B Condens. Matter 407, 3939–3944 (2012). https://doi.org/10.1016/j.physb.2012.05.06610.1016/j.physb.2012.05.066 ↗
23. E.V. Dudnik, S.N. Lakiza, N.I. Hrechanyuk, A.K. Ruban, V.P. Red’ko, M.S. Hlabay, A.B. Myloserdov, The Gd2Zr2O7-based materials for thermal barrier coatings. Powder Metall. Met. Ceram. 57, 301–315 (2018). https://doi.org/10.1007/s11106-018-9983-z10.1007/s11106-018-9983-z ↗
24. E.K. Michael, S. Trolier-McKinstry, Bismuth pyrochlore thin films for dielectric energy storage. J. Appl. Phys. 118, 054101 (2015). https://doi.org/10.1063/1.492773810.1063/1.4927738 ↗
25. Z. Lu, J. Wang, Y. Tang, Y. Li, Synthesis and photoluminescence of Eu3+-doped Y2Sn2O7 nanocrystals. J. Solid State Chem. 177, 3075–3079 (2004). https://doi.org/10.1016/j.jssc.2004.04.05310.1016/j.jssc.2004.04.053 ↗
26. M.V. Talanov, V.M. Talanov, Structural diversity of ordered pyrochlores. Chem. Mater. 33, 2706–2725 (2021). https://doi.org/10.1021/acs.chemmater.0c0486410.1021/acs.chemmater.0c04864 ↗
27. J. Xu, R. Xi, X. Xu, Y. Zhang, X. Feng, X. Fang, X. Wang, A2B2O7 pyrochlore compounds: a category of potential materials for clean energy and environment protection catalysis. J. Rare Earths 38, 840–849 (2020). https://doi.org/10.1016/j.jre.2020.01.00210.1016/j.jre.2020.01.002 ↗
28. B. Matovic, J. Maletaskic, J. Zagorac, V. Pavkov, R.S.S. Maki, K. Yoshida, T. Yano, Synthesis and characterization of pyrochlore lanthanide (Pr, Sm) zirconate ceramics. J. Eur. Ceram. Soc. 40, 2652–2657 (2020). https://doi.org/10.1016/j.jeurceramsoc.2019.11.01210.1016/j.jeurceramsoc.2019.11.012 ↗
29. G.R. Lumpkin, R.D. Aughterson, Perspectives on pyrochlores, defect fluorites, and related compounds: building blocks for chemical diversity and functionality. Front. Chem. 9, 778140 (2021). https://doi.org/10.3389/fchem.2021.77814010.3389/fchem.2021.778140 ↗
30. D. Drey, E. O’Quinn, S. Finkeldei, J. Neuefeind, M. Lang, Local ordering in disordered NdxZr1-xO2-0.5x pyrochlore as observed using neutron total scattering. Acta Mater. 225, 117590 (2022). https://doi.org/10.1016/j.actamat.2021.11759010.1016/j.actamat.2021.117590 ↗
31. M.A. Boles, M. Engel, D.V. Talapin, Self-assembly of colloidal nanocrystals: from intricate structures to functional materials. Chem. Rev. 116, 11220–11289 (2016). https://doi.org/10.1021/acs.chemrev.6b0019610.1021/acs.chemrev.6b00196 ↗
32. Y. Wang, C. Jing, Z.Y. Ding, Y.Z. Zhang, T. Wei, J.H. Ouyang, Z.G. Liu, Y.J. Wang, Y.M. Wang, The structure, property, and ion irradiation effects of pyrochlores: a comprehensive review. Crystals 13, 143 (2023). https://doi.org/10.3390/cryst1301014310.3390/cryst13010143 ↗
33. K.J. Baumler, R.E. Schaak, Tutorial on describing, classifying, and visualizing common crystal structures in nanoscale materials systems. ACS Nanosci. Au 4, 290–316 (2024). https://doi.org/10.1021/acsnanoscienceau.4c0001010.1021/acsnanoscienceau.4c00010 ↗
34. K. Mondal, L. Nuñez III., C.M. Downey, I.J. van Rooyen, Thermal barrier coatings overview: design, manufacturing, and applications in high-temperature industries. Ind. Eng. Chem. Res. 60, 6061–6077 (2021). https://doi.org/10.1021/acs.iecr.1c0078810.1021/acs.iecr.1c00788 ↗
35. A. Tkach, J.S. Amaral, S. Zlotnik, V.S. Amaral, P.M. Vilarinho, Enhancement of the dielectric permittivity and magnetic properties of Dy substituted strontium titanate ceramics. J. Eur. Ceram. Soc. 38, 605–611 (2018). https://doi.org/10.1016/j.jeurceramsoc.2017.09.00710.1016/j.jeurceramsoc.2017.09.007 ↗
36. D.R. Clarke, C.G. Levi, Materials design for the next generation thermal barrier coatings. Annu. Rev. Mater. Res. 33, 383–417 (2003). https://doi.org/10.1146/annurev.matsci.33.011403.11371810.1146/annurev.matsci.33.011403.113718 ↗
37. C. Zhang, F. Wang, B. Xiong, H. Yang, Regulating the electronic structures of mixed B-site pyrochlore to enhance the turnover frequency in water oxidation. Nano Convergence. 9, 22 (2022). https://doi.org/10.1186/s40580-022-00311-z10.1186/s40580-022-00311-z ↗
38. J. Wu, A.E. O’Neill, C. Li, J.R. Jinschek, G. Cavataio, Superior TWC activity of Rh supported on pyrochlore-phase ceria zirconia. Appl. Catal. B Environ. 280, 119450 (2021). https://doi.org/10.1016/j.apcatb.2020.11945010.1016/j.apcatb.2020.119450 ↗
39. Y. Zhang, H. Li, S. Moricca, Pyrochlore-structured titanate ceramics for immobilisation of actinides: hot isostatic pressing (HIPing) and stainless steel/waste form interactions. J. Nucl. Mater. 377, 470–475 (2008). https://doi.org/10.1016/j.jnucmat.2008.03.02210.1016/j.jnucmat.2008.03.022 ↗
40. R.C. Ewing, W.J. Weber, J. Lian, Nuclear waste disposal—pyrochlore (A2B2O7) nuclear waste form for the immobilization of plutonium and minor actinides. J. Appl. Phys. 95, 5949–5971 (2004). https://doi.org/10.1063/1.170721310.1063/1.1707213 ↗
41. Y. Wang, C. Jing, Z.-Y. Ding, Y.-Z. Zhang, T. Wei, J.-H. Ouyang, Z.-G. Liu, Y.-J. Wang, Y.-M. Wang, The structure, property, and ion irradiation effects of pyrochlores: a comprehensive review. Crystals 13, 143 (2023). https://doi.org/10.3390/cryst1301014310.3390/cryst13010143 ↗
42. T. Connor, O. Cheong, T. Bornhake, A.C. Shad, R. Tesch, M. Sun, Z. He, A. Bukayemsky, V.L. Vinograd, S.C. Finkeldei, P.M. Kowalski, Pyrochlore compounds from atomistic simulations. Front. Chem. 9, 733321 (2021). https://doi.org/10.3389/fchem.2021.73332110.3389/fchem.2021.733321 ↗
43. C.R. Kreller, J.A. Valdez, T.G. Holesinger, R. Mukundan, E.L. Brosha, T. Williamson, Y.Q. Wang, B.P. Uberuaga, Synthesis and characterization of dense Gd2Ti2O7 pyrochlore thin films deposited using RF Magnetron sputtering. Solid State Ionics. 314, 36–40 (2018). https://doi.org/10.1016/j.ssi.2017.10.00910.1016/j.ssi.2017.10.009 ↗
44. A. Mori, M. Kawamura, S. Takase, Y. Shimizu, Pyrochlore-type Bi2Sn2O7 oxide as an electrocatalyst for carbon dioxide reduction. J. Ceram. Soc. Jpn. 126, 843–846 (2018). https://doi.org/10.2109/jcersj2.1807910.2109/jcersj2.18079 ↗
45. M.S. Koroleva, A.G. Krasnov, I.V. Piir, Enhancement of bi-based niobate pyrochlores conductivity with Ru-doping. Structural, optical, and electrical properties. Int. J. Hydrogen Energy 48, 22712–22717 (2023). https://doi.org/10.1016/j.ijhydene.2023.03.42310.1016/j.ijhydene.2023.03.423 ↗
46. F.X. Zhang, M. Lang, J.M. Zhang, R.C. Ewing, M. Nyman, Structural changes of (K,Gd)2Ta2O7 pyrochlore at high pressure. J. Solid State Chem. 184, 2329–2332 (2011). https://doi.org/10.1016/j.jssc.2011.06.04010.1016/j.jssc.2011.06.040 ↗
47. V.A. Chernyshev, V.P. Petrov, A.E. Nikiforov, P.A. Agzamova, N.M. Avram, Elastic properties of rare earth pyrochlores R2Ti2O7 (R = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu): ab initio calculations. Opt. Mater. 72, 565–570 (2011). https://doi.org/10.1016/j.optmat.2017.06.06210.1016/j.optmat.2017.06.062 ↗
48. F. Matteucci, G. Cruciani, M. Dondi, G. Baldi, A. Barzanti, Crystal structural and optical properties of Cr-doped Y2Ti2O7 and Y2Sn2O7 pyrochlores. Acta Mater. 55(7), 2229–2238 (2007). https://doi.org/10.1016/j.actamat.2006.11.00810.1016/j.actamat.2006.11.008 ↗
49. V. Chishkala, S. Lytovchenko, B. Mazilin, E. Gevorkyan, V. Shkuropatenko, V. Voyevodin, M. Rucki, Z. Siemiątkowski, J. Matijošius, A. Dudziak, J. Caban, A. Kilikevičius, Novel microwave-assisted method of Y2Ti2O7 powder synthesis. Materials 13(24), 5621 (2020). https://doi.org/10.3390/ma1324562110.3390/ma13245621 ↗
50. B.P. Singh, A.K. Parchur, R.S. Ningthoujam, P.V. Ramakrishna, S. Singh, P. Singh, S.B. Rai, R. Maalej, Enhanced up-conversion and temperature-sensing behaviour of Er3+ and Yb3+ co-doped Y2Ti2O7 by incorporation of Li+ ions. Phys. Chem. Chem. Phys. 16(41), 22665–22676 (2014). https://doi.org/10.1039/C4CP02949F10.1039/C4CP02949F ↗
51. Z. Tian, H. Yu, Z. Han, Z. Guan, S. Xu, J. Sun, Y. Cao, Y. Wang, L. Cheng, B. Chen, Luminescence properties, and anti-counterfeiting application of one-dimensional electrospun Y2Ti2O7:Ho/Yb nanostructures. Ceram. Int. 48(19), 27836–27848 (2022). https://doi.org/10.1016/j.ceramint.2022.06.08610.1016/j.ceramint.2022.06.086 ↗
52. N. Gumber, M. Shafeeq, S.K. Gupta, R. Phatak, U.K. Goutam, R. Kumar, R.V. Pai, Synthesis and feasibility studies of doping U at Ti site of Y2Ti2O7 as a radioactive waste immobilization matrix. Dalton Trans. 52(39), 14170–14181 (2023). https://doi.org/10.1039/D3DT02727A10.1039/D3DT02727A ↗
53. H.E. Hung, C.K. Hao, C.S. Lee, The stability and ionic conductivity in Cr doped Y2Ti2O7 in the search for potential SOFC electrolyte materials. ECS Trans. 58, 175 (2013). https://doi.org/10.1149/05803.0175ecst10.1149/05803.0175ecst ↗
54. C.R. Kreller, J.A. Valdez, T.G. Holesinger, R. Mukundan, E.L. Brosha, T. Williamson, Y.Q. Wang, B.P. Uberuaga, Synthesis and characterization of dense Gd2Ti2O7 pyrochlore thin films deposited using RF magnetron sputtering. Solid State Ionics 314, 36–40 (2018). https://doi.org/10.1016/j.ssi.2017.10.00910.1016/j.ssi.2017.10.009 ↗
55. E.R. Aluri, A.P. Grosvenor, A study of the electronic structure and structural stability of Gd2Ti2O7 based glass-ceramic composites. RSC Adv. 5, 80939–80949 (2015). https://doi.org/10.1039/C5RA10720B10.1039/C5RA10720B ↗
56. S. Balamurugan, K. Dheebikha, T.S. Gokul Raja, Nanocrystalline Gd2Ti2O7 pyrochlore material for nir reflective pigment application: micro-structural and optical studies. J. Nanosci. Nanotechnol. 16(1), 677–688 (2016). https://doi.org/10.1166/jnn.2016.1060410.1166/jnn.2016.10604 ↗
57. L. Lin, Z.Y. Zhao, D. Liu, Y.L. Xie, S. Dong, Z.B. Yan, J.-M. Liu, Chemically modulated multiferroicity in Dy-doped Gd2Ti2O7. J. Appl. Phys. 113, 17D903 (2013). https://doi.org/10.1063/1.479412910.1063/1.4794129 ↗
58. A. Masud, B.K. Singh, J. Lahiri, N.K. Das, A.K. Himanshu, Investigation of structural and optical studies of Gd2Ti2O7.AIP Conf. Proc.2995, 020059(2024).https://doi.org/10.1063/5.017834410.1063/5.0178344 ↗
59. Y. Singh, V. Kumar, S.K. Sharma, T. Vazhappilly, J. Lian, P.K. Kulriya, Investigations of thermal conductivity in nano-crystalline Gd2Ti2O7 pyrochlore. J. Alloys Compd. 990, 174249 (2024). https://doi.org/10.1016/j.jallcom.2024.17424910.1016/j.jallcom.2024.174249 ↗
60. K. Nakamura, M. Mori, T. Itoh, T. Ohnuma, Theoretical and experimental investigation of defect formation / migration in Gd2Ti2O7: general rule of oxide-ion migration in A2B2O7pyrochlore. AIP Adv. 6, 115003 (2016). https://doi.org/10.1063/1.496721110.1063/1.4967211 ↗
61. P. Sivagnanapalani, P.K. Panda, Samarium titanate (Sm2Ti2O7) materials for high-temperature sensor applications. Sens. Int. 3, 100200 (2022). https://doi.org/10.1016/j.sintl.2022.10020010.1016/j.sintl.2022.100200 ↗
62. R. Sain, C. Upadhyay, Unveiling the structural and optical properties of samarium titanates pyrochlore, Sm2Ti2O7.IOP Conf. Ser. : Mater. Sci. Eng. 1300, 012042 (2023). https://doi.org/10.1088/1757-899X/1300/1/01204210.1088/1757-899X/1300/1/012042 ↗
63. T. Jeyasingh, P.S. Vindhya, S.K. Saji, P.R.S. Wariar, V.T. Kavitha, Structural and magnetic properties of combustion synthesized A2Ti2O7 (A = Gd, dy and Y) pyrochlore oxides. Bull. Mater. Sci. 42, 195 (2019). https://doi.org/10.1007/s12034-019-1878-110.1007/s12034-019-1878-1 ↗
64. W. Zhang, H. Li, L. Du, A novel porous Sm2Ti2O7 material synthesized in sol-gel process using polyethylene glycol 4000 as template. IOP Conf. Ser. : Mater. Sci. Eng. 1300, 012042 (2023)
65. J. Yao, Y. Chen, L. Du, W. Zhang, Sol-gel loading of Sm2Ti2O7 on HZSM-5 zeolite for enhanced photocatalytic activity.Optoelectron. Adv. Mater. -Rapid Commun. 13(1–2), 136–140 (2019)
66. Z. Shao, S. Saitzek, A. Ferri, M. Rguiti, L. Dupont, P. Roussel, R. Desfeux, Evidence of ferroelectricity in metastable Sm2Ti2O7 thin film.J. Mater. Chem. 22(19), 9806 (2012). https://doi.org/10.1039/c2jm16261j10.1039/c2jm16261j ↗
67. H. Huang, J. Du, Q. Feng, S. Hu, T. Fujita, J. Qin, C. Yuan, T. Wang, X. Wang, X. Chen, N. Luo, Enhanced energy storage performance in Sn4+ doped Sm2Ti2O7 pyrochlore ceramics. J. Power Sources. 633, 236466 (2025). https://doi.org/10.1016/j.jpowsour.2025.23646610.1016/j.jpowsour.2025.236466 ↗
68. Y.M. Jana, A. Sengupta, D. Ghosh, Estimation of single ion anisotropy in pyrochlore Dy2Ti2O7, a geometrically frustrated system, using crystal field theory. J. Magn. Magn. Mater. 248, 7–18 (2002). https://doi.org/10.1016/S0304-8853(01)00983-010.1016/S0304-8853(01)00983-0 ↗
69. A.K. Pandit, T.H. Ansari, R.A. Singh, B.M. Wanklyn, Electrical conduction in Dy2Ti2O7 single crystal. Mater. Lett. 11(1–2), 52–58 (1991). https://doi.org/10.1016/0167-577X(91)90189-D10.1016/0167-577X(91)90189-D ↗
70. M. Mito, S. Kuwabara, K. Matsuhira, H. Deguchi, S. Takagi, Z. Hiroi, Uniaxial pressure effects on spin-ice compound Dy2Ti2O7. J. Magn. Magn. Mater. 310(2, Part 2), e432–e434 (2007). https://doi.org/10.1016/j.jmmm.2006.10.44110.1016/j.jmmm.2006.10.441 ↗
71. E.R. Kassner, A.B. Eyvazova, B. Pichler, T.J.S. Munsie, H.A. Dabkowska, G.M. Luke, J.C.S. Davis, Supercooled spin liquid state in the frustrated pyrochlore Dy2Ti2O7. Proc. Natl. Acad. Sci. U.S.A. (PNAS) 112(28), 8549–8554 (2015). https://doi.org/10.1073/pnas.151100611210.1073/pnas.1511006112 ↗
72. R. Upadhyay, M. Shukla, R.K. Pandey, C. Upadhyay, Effect of Mn doping on the electronic and optical properties of Dy2Ti2O7: a combined spectroscopic and theoretical study. J. Phys.: Condens. Matter 35, 335502 (2023). https://doi.org/10.1088/1361-648X/acd4a110.1088/1361-648X/acd4a1 ↗
73. Y. Yang, Y. Shi, J. Duan, K. Lu, G. Cheng, Y. Zhao, Z. Huang, P. Li, N. Wei, X. Zhu, J. Qi, T. Lu, Photoluminescence enhancement of Gd₂Zr₂O₇:Eu³⁺ red phosphor sensitized by co-doped Al³⁺ ions. Ceram. Int. 47, 13071–13077 (2021). https://doi.org/10.1016/j.ceramint.2021.01.17110.1016/j.ceramint.2021.01.171 ↗
74. V.V. Kharton, E.V. Tsipis, A.A. Yaremchenko, N.P. Vyshatko, A.L. Shaula, E.N. Naumovich, J.R. Frade, Oxygen ionic and electronic transport in Gd₂₋ₓCaₓTi₂O₇-δ pyrochlores. J. Solid State Electrochem. 7, 468–476 (2003). https://doi.org/10.1007/s10008-002-0348-610.1007/s10008-002-0348-6 ↗
75. V.K. Anand, D.A. Tennant, B. Lake, Investigations of the effect of nonmagnetic Ca substitution for magnetic Dy on spin-freezing in Dy2Ti2O7. J. Phys.: Condens. Matter 27, 436001 (2015). https://doi.org/10.1088/0953-8984/27/43/43600110.1088/0953-8984/27/43/436001 ↗
76. D. Staško, K. Vlášková, D. Vojtasová, F. Hájek, P. Král, R.H. Colman, M. Klicpera, The synthesis of the rare earth A2Zr2O7 single crystals by simplified laser-heated floating hot zone and pedestal methods. Mater. Today Chem. 39, 102153 (2024). https://doi.org/10.1016/j.mtchem.2024.10215310.1016/j.mtchem.2024.102153 ↗
77. W. Ma, Y. Luo, Z. Ma, C. Li, Y. Qian, W. Li, T. Xiong, Z. Wang, X. Li, Q. Jiang, G. Wang, J. Yang, La2Zr2O7 based high-entropy ceramic with a low thermal conductivity and enhanced CMAS corrosion resistance. Ceram. Int. 49, 29729–29735 (2023). https://doi.org/10.1016/j.ceramint.2023.06.21510.1016/j.ceramint.2023.06.215 ↗
78. Y. Lu, T. Zhao, L. Ye, X. Sui, S. Zhang, J. Hao, Polymer-derived Er3+-doped La2Zr2O7 nanocrystals: synthesis, microstructure and photoluminescence. Mater. Sci. Technol. 36(18), 1930–1935 (2020). https://doi.org/10.1080/02670836.2020.184999910.1080/02670836.2020.1849999 ↗
79. V. Nečina, T. Uhlířová, L. Kotrbová, J. Mrázek, W. Pabst, Thermal conductivity of Eu-doped La2Zr2O7 transparent ceramics. J. Eur. Ceram. Soc. 45, 116821 (2025). https://doi.org/10.1016/j.jeurceramsoc.2024.11682110.1016/j.jeurceramsoc.2024.116821 ↗
80. E. Antonova, E. Tropin, A. Khodimchuk, Alkaline earth-doped La2Zr2O7 oxides with a pyrochlore structure: phase equilibria and electrical properties. Ionics 28, 5181–5188 (2022). https://doi.org/10.1007/s11581-022-04750-w10.1007/s11581-022-04750-w ↗
81. B.V.N. Kumar, Y.N. Rajeev, S.E.B. Basha, K.V. Rao, K.R. Rao, S. Cole, Enhanced luminescence and energy transfer of Bi3+/Dy3+ co-doped La2Zr2O7 nanophosphors for pc-LED applications. Phys. Chem. Res. 11(1), 23–31 (2023). https://doi.org/10.22036/pcr.2022.333784.205010.22036/pcr.2022.333784.2050 ↗
82. S. Ahmad, S. Gouadria, K. Jabbour, A. Naz, S. Manzoor, M. Abdullah, M.Z. Ansari, H.H. Hegazy, S. Aman, M.N. Ashiq, Iron doped Gd2Zr2O7 hierarchical nanoflake arrays as robust electrode materials for energy storage application. J. Energy Storage 60, 106687 (2023). https://doi.org/10.1016/j.est.2023.10668710.1016/j.est.2023.106687 ↗
83. Z.-G. Liu, J.-H. Ouyang, Y. Zhou, X.-L. Xia, Electrical conductivity of Nd and Ce co-doped Gd2Zr2O7 ceramics. Philos. Mag. Lett. 90, 753–761 (2010). https://doi.org/10.1080/09500839.2010.50717410.1080/09500839.2010.507174 ↗
84. A.V. Shlyakhtina, N.V. Gorshkov, I.V. Kolbanev, K.I. Shefer, A.V. Kas’yanova, D.A. Medvedev, Electrical properties of beryllium-doped Gd2Zr2O7. Inorg. Mater. 57, 1184–1193 (2021). https://doi.org/10.1134/S002016852111011X10.1134/S002016852111011X ↗
85. V.K. Singh, S. Tripathi, M.K. Mishra, R. Tiwari, V. Dubey, N. Tiwari, Optical studies of erbium and ytterbium doped Gd2Zr2O7 phosphor for display and optical communication applications. J. Disp. Technol. 12, 1224–1228 (2016). https://doi.org/10.1109/JDT.2016.260199810.1109/JDT.2016.2601998 ↗
86. Y. Ye, Z. Tang, Z. Ji, H. Xiao, Y. Liu, Y. Qin, L. Liang, J. Qi, T. Lu, Fabrication and luminescent properties of holmium doped Y2Zr2O7 transparent ceramics as new type laser material. Opt. Mater. 121, 111643 (2021). https://doi.org/10.1016/j.optmat.2021.11164310.1016/j.optmat.2021.111643 ↗
87. R.T. Parayil, S.K. Gupta, G.D. Patra, M. Mohapatra, Nano triumphs bulk in red light emission from Eu³⁺ doped Y2Zr2O7: Gel combustion versus solid state synthesis. Mater. Lett. 366, 136503 (2024). https://doi.org/10.1016/j.matlet.2024.13650310.1016/j.matlet.2024.136503 ↗
88. Y. Wang, P. Darapaneni, O. Kizilkaya, J.A. Dorman, Role of Ce in manipulating the photoluminescence of Tb doped Y2Zr2O7. Inorg. Chem. 59, 2358–2366 (2020). https://doi.org/10.1021/acs.inorgchem.9b0322610.1021/acs.inorgchem.9b03226 ↗
89. M. Kumar, I. Arul Raj, R. Pattabiraman, Y2Zr2O7 (YZ)-pyrochlore based oxide as an electrolyte material for intermediate temperature solid oxide fuel cells (ITSOFCs)-Influence of Mn addition on YZ. Mater. Chem. Phys. 108, 102–108 (2008). https://doi.org/10.1016/j.matchemphys.2007.09.01010.1016/j.matchemphys.2007.09.010 ↗
90. A.R. Bansod, A.R. Kadam, P.S. Bokare, S.J. Dhoble, Luminescence study of Sm3+, Eu3+-doped Y2Zr2O7 host: optical investigation of greenish yellow to red colour tunable pyrochlore phosphor. Luminescence 37, 1352–1360 (2022). https://doi.org/10.1002/bio.430510.1002/bio.4305 ↗
91. E. Öztürk, E. Karacaoğlu, V. Kalem, Photoluminescence and piezoelectric behaviour of Y2Zr2O7 pyrochlore-based multifunctional materials and the influence of Eu³⁺ and Sm³⁺. Luminescence 35, 1–6 (2020). https://doi.org/10.1002/bio.374110.1002/bio.3741 ↗
92. A. Zhang, P. Yang, Y. Cao, Y. Zhu, Eu, Dy codopedY2Zr2O7 powders with white light luminescence. Adv. Mater. Lett. 2, 322–326 (2011). https://doi.org/10.5185/amlett.2011.3042am201110.5185/amlett.2011.3042am2011 ↗
93. Y. Zheng, P. Duan, Z. Li, G. Cai, F. Zhong, Y. Xiao, Heterovalent ions incorporated pyrochlore Sm₂Zr₂O₇ ceramic for enhanced NO₂ sensing. J. Eur. Ceram. Soc. 40, 3453–3461 (2020). https://doi.org/10.1016/j.jeurceramsoc.2020.03.04210.1016/j.jeurceramsoc.2020.03.042 ↗
94. S.. Ya.. Istomin, O.G. D’yachenko, E.V. Antipov, G. Svensson, Synthesis and characterization of reduced niobates CaLnNb2O7, Ln = Y, Nd with a pyrochlore structure. Mater. Res. Bull. 32, 421–430 (1997). https://doi.org/10.1016/S0025-5408(96)00003-710.1016/S0025-5408(96)00003-7 ↗
95. M.S. Koroleva, A.G. Krasnov, A. Senyshyn, A. Schökel, I.R. Shein, M.I. Vlasov, I.V. Piir, Structure, thermal stability, optoelectronic and electrophysical properties of Mg- and Na-codoped bismuth niobate pyrochlores: experimental and theoretical study. J. Alloys Compd. 858, 157742 (2021). https://doi.org/10.1016/j.jallcom.2020.15774210.1016/j.jallcom.2020.157742 ↗
96. F.A. Jusoh, K.B. Tan, Z. Zainal, S.K. Chen, C.C. Khaw, O.J. Lee, Investigation of structural and dielectric properties of subsolidus bismuth iron niobate pyrochlores. J. Asian Ceram. Soc. 8, 957–969 (2020). https://doi.org/10.1080/21870764.2020.179991410.1080/21870764.2020.1799914 ↗
97. I.V. Piir, M.S. Koroleva, V.S. Maksimov, Effect of codoping on the electrical properties of magnesium- and copper-containing bismuth niobate with pyrochlore-type structure. Russ. J. Gen. Chem. 93, 358–362 (2023). https://doi.org/10.1134/S107036322302017210.1134/S1070363223020172 ↗
98. N.A. Zhuk, N.A. Sekushin, M.G. Krzhizhanovskaya, A.A. Selutin, A.V. Koroleva, K.A. Badanina, S.V. Nekipelov, O.V. Petrova, V.N. Sivkov, Photoelectron spectroscopy study of the optical and electrical properties of Cr/Cu/Mn tri-doped bismuth niobate pyrochlore. Sci 7, 1 (2025). https://doi.org/10.3390/sci701000110.3390/sci7010001 ↗
99. G.M. Bertoldo, A.C. Oliveira, G.D. Saraiva, R. Jucá, J.G. da Silva Filho, E. Rodríguez-Aguado, J. Jiménez-Jiménez, E. Rodríguez-Castellón, Metal-doped niobate pyrochlores and double-perovskites for glycerol valorization: structural and electronic properties and DFT calculations. Dalton Trans. 53, 9139–9150 (2024). https://doi.org/10.1039/d4dt00898g10.1039/d4dt00898g ↗
100. P. Baxter, N.J. Hellicar, Electrical properties of lead-barium niobates and associated materials. J. Am. Ceram. Soc. 43, 578–583 (1960). https://doi.org/10.1111/j.1151-2916.1960.tb13619.x10.1111/j.1151-2916.1960.tb13619.x ↗