journal article·2021-05

Study on the blackening mechanism of buried cinnabar within ancient Chinese jades

Yunyi Mai, Rong Wang, Hua Cui

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Abstract

Abstract Buried jades can turn to different colors because of underground weathering. As for the secondary blackness on excavated jades, previous studies have confirmed they resulted from carbon, manganese, iron and copper, but latest archaeological discoveries seem to be concerned with another chemical element, mercury. In order to clarify the specific composition of mercury, as well as its possible source and transition, this research analyzes typical jades from the tomb of Yuehe (not later than 538 BC) by Raman, FTIR, XRF, SEM-EDX, XPS, μ-XRD and mercury isotopes. Relevant evidences and simulated experiment indicate the coloring factor is metacinnabar (β-HgS), which might be converted from cinnabar (α-HgS) in the influence of bromine and alkali.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Building materials and conservation · Mineralogy and Gemology Studies

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References (52)

Show source-provided references
1. Wang · 2020
2. The record of jades, in Lingnan Jade Club
3. Travials about golds and jades
4. The chronology and typology of jades
5. Opinions on jades
6. Knowledge on the identification of jades
7. Opinions on jades
8. Liu · 1940
9. Sima · 2010
10. Ouyang · 1965
11. Li · 1980
12. Tuo · 1977
13. The correction of the record of jade
14. The scientific methods of identifying ancient jades in traditional collections
15. The analysis and discussion on eight scientific names of jades and stones
16. The scientific analysis and research on some jades from the tomb of Fuhao in Yinxu Site -- With discussion on the Liao sacrifice to jades
17. Study on the grossular rabbit with high hardness excavated from Yin Ruins, Anyang, China10.1007/s12520-018-0696-5 ↗
18. The analysis on the phenomena of ‘Shui Yin Qin’ in the jades from the tomb of Yuehe, Tongbai in Spring and Autumn period
19. The reunderstanding of black ‘mercury seeps’ in the jades from Chu’s noble tombs of warring states — A case study on the black impregnation phenomena on the jades in Warring States period collected by Hunan Provincial Museum
20. Brief report on the excavation of No. 1 Tomb in Yuehe twon, Tongbai county in Spring and Autumn period
21. Application of Raman spectroscopy in the nondestructive analyses of ancient Chinese jades10.1002/jrs.2846 ↗
22. Study on nephrite (tremolite jade) from three localities in China
23. The characteristics for identification on albite and similar jades by infrared spectroscopy
24. The features of infrared spectrum and identification of turquoise
25. The vapour pressure, dissociation, and transition point of mercury sulphide10.1002/recl.19280470105 ↗
26. Thermal behaviour of cinnabar, α-HgS, and the kinetics of the β-HgS (metacinnabar) → α-HgS conversion at room temperature10.1127/0935-1221/2013/0025-2341 ↗
27. Tie · 2016
28. The stability relations of cinnabar and metacinnabar
29. Yin · 2012
30. Studies on the darkening of vermilion by light
31. Vermilion and cinnabar10.1179/sic.1972.006 ↗
32. The light-induced blackening of red mercury(II) sulphide10.1039/dt9810000833 ↗
33. The blackening of vermillion by light
34. Mechanistic and computational study of cinnabar phase transformation: application and implications to the preservation of this pigment in historical painting
35. Discoloration of pigments induced by laser irradiation
36. Blackening of Pompeian cinnabar paintings: X-ray microspectroscopy analysis10.1021/ac0612224 ↗
37. Applications of synchrotron-based micro-imaging techniques to the chemical analysis of ancient paintings10.1039/b801358f ↗
38. The use of microscopic X-ray diffraction for the study of HgS and its degradation products corderoite (α-Hg3S2Cl2), kenhsuite (γ-Hg3S2Cl2) and calomel (Hg2Cl2) in historical paintings10.1039/c0ja00260g ↗
39. M. Radepont, Understanding of chemical reactions involved in pigment discoloration, in particular in mercury sulfide (HgS) blackening. Unpublished PhD dissertation, University of Antwerp, 2013.
40. Thermodynamic and experimental study of the degradation of the red pigment mercury sulfide10.1039/C4JA00372A ↗
41. Darkening of cinnabar in sunlight
42. Photochemical behavior of mercury ore in water10.1016/0160-4120(83)90060-0 ↗
43. Photoinduced chemical reactions on natural single crystals and synthesized crystallites of mercury(II) sulfide in aqueous solution containing naturally occurring amino acids10.1021/ic025916g ↗
44. Analytical imaging studies clarifying the process of the darkening of vermilion in paintings10.1021/ac048158f ↗
45. A study of cinnabar blackening: new approach and treatment perspective
46. Raman spectroscopy as a tool to diagnose the impact and conservation state of Pompeian second and fourth style wall paintings exposed to diverse environments (House of Marcus Lucretius)10.1002/jrs.2671 ↗
47. Casting light on the darkening of colors in historical paintings10.1103/PhysRevLett.111.208302 ↗
48. Formation of metallic mercury during photodegradation/photodarkening of α-HgS: electrochemical evidence10.1002/anie.201303977 ↗
49. Cinnabar alteration in archaeological wall paintings: an experimental and theoretical approach10.1007/s00339-015-9456-x ↗
50. Weathering behavior of cinnabar-based tempera paints upon natural and accelerated aging10.1016/j.saa.2019.03.027 ↗
51. Veränderung den zinnobers durch das licht10.1002/cber.187400701240 ↗
52. The Editorial Committee of Chinese Towns and Cities: Henan Province · 1992