journal article·2011-03

Insights into Masolino's wall paintings in Castiglione Olona: Advanced reflectance and fluorescence imaging analysis

Daniela Comelli, Austin Nevin, Gianluca Valentini, Iacopo Osticioli, Emilio Mario Castellucci, Lucia Toniolo, Davide Gulotta, Rinaldo Cubeddu

Journal of Cultural Heritage· Volume 12· Issue 1
Publisher page

Abstract

Investigations of wall paintings by Masolino da Panicale in the Baptistery of Castiglione Olona were conducted using a multi-analytical approach, based on in situ fluorescence imaging, multispectral reflectance imaging and non-destructive analysis of a historical cross-section. Fluorescence imaging of wall paintings, mainly focused on the discrimination and identification of organic compounds, has been conducted with a novel approach, which incorporates the use of spectrally-resolved and lifetime-resolved imaging devices, applied together for the first time for the analysis of paintings. Analysis of the UV-induced emissions from the surface of the paintings allowed the documentation of the selective use of a carmine-based red lake, identified using micro-Raman spectroscopy and Scanning Electron Microscopy. Visible reflectance measurements highlighted the distribution and use of different inorganic pigments. Finally, the in situ study, with the support of early 20th century photographs, provided additional information on Masolino's style and revealed details and decorative elements of the painting, which are indiscernible under standard illumination. (C) 2010 Elsevier Masson SAS. All rights reserved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Conservation Techniques and Studies · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. Lasers in the analysis of cultural heritage materials
2. Fiber optics application to works of art10.1016/0925-4005(95)01682-1 ↗
3. Analysis of art objects using a portable x-ray fluorescence spectrometer10.1002/(SICI)1097-4539(200001/02)29:1<48::AID-XRS404>3.0.CO;2-H ↗
4. A new instrument adapted to in situ Raman analysis of objects of art10.1007/s00216-004-2551-z ↗
5. Non-invasive identification of surface materials on marble artifacts with fiber optic mid-FTIR reflectance spectroscopy10.1016/j.talanta.2005.12.054 ↗
6. In situ non-invasive investigation on the painting techniques of early Meissen Stoneware10.1016/j.saa.2009.02.003 ↗
7. Near infrared spectroscopic reflectance imaging: a new tool in art conservation10.1016/S0924-2031(01)00145-X ↗
8. The fluorescence lidar technique for the remote sensing of photoautotrophic biodeteriogens in the outdoor cultural heritage: a decade of in situ experiments10.1016/j.ibiod.2009.03.006 ↗
9. TeraHertz imaging of hidden paint layers on canvas10.1364/OE.17.003407 ↗
10. C.B. Strehlke, C. Frosinini, The panel paintings of Masolino and Masaccio. The role of technique, 5 Continents Editions, Milano, 2002.
11. C. Bertelli, Masolino: gli affreschi del Battistero e della Collegiata a Castiglione Olona, Skyra, Milano, 1998.
12. A. Gallone, Analisi di campioni di colore prelevati dagli affreschi di Masolino da Panicale a Castiglione Olona, in: P.C. Marani (Ed.), Conservazione e valorizzazione degli affreschi nella provincia di Varese: atti del convegno del 21 aprile 1995, Crespi Editore, Cassano M., 1997, pp. 43–8.
13. R.J. Gettens, G.L. Stout, Painting materials, a short encyclopaedia, Dover Publications, New York, 1966.
14. C. Cennini, Il libro dell’arte, in: F. Brunello (Ed.), Vicenza, 1993.
15. J. Kirby, The preparation of Early Lake Pigments: a survey, in: H.E. Garland (Ed.), Summary of talks of Dyes in History and Archaeology, Sixth Annual Meeting, 25th September 1987, Edinburgh, Leeds, 1998, pp. 12–8.
16. J. Kirby, R. White, The identification of red lake pigment dyestuffs and a discussion of their use, in The National Gallery Technical Bulletin, vol. 17, London, 1996, pp. 56–80.
17. H. Schweppe, H.R. Roosen-Runge, Carmine: cochineal carmine and kermes carmine, in Artist's pigments: a handbook of their history and characteristics, ed. RobertFeller, Washington, 1986, pp. 255–83.
18. Multispectral Imaging of Paintings10.1109/MSP.2008.923095 ↗
19. Identification of pigments in paint cross sections by reflection visible light imaging microscpectroscopy10.1021/ac020282g ↗
20. D. Comelli, G. Valentini, A. Nevin, A. Farina, L. Toniolo, R. Cubeddu, A portable UV-fluorescence multispectral imaging system for the analysis of painted surfaces, Rev. Sci. Instrum. 79 (2008) article number: 086112.10.1063/1.2969257 ↗
21. G. Wyszecki, W.S. Stiles, Color science: concepts and methods, quantitative data and formulae, Wiley-Interscience, 2000.
22. P. Geladi, H. Grahn, Multivariate image analysis, Wiley, Chichester, 1997.
23. Fluorescence lifetime imaging and spectroscopy as tools for nondestructive analysis of works of art10.1364/AO.43.002175 ↗
24. Fluorescence lifetime imaging and fourier transform infrared spectroscopy of Michelangelo's David10.1366/0003702055012663 ↗
25. Vibrational and electronic properties of painting lakes10.1007/s00339-008-4474-6 ↗
26. Library of FT-Raman spectra of pigments, minerals, pigment media and varnishes, and supplement to existing library of Raman spectra of pigments with visible excitation10.1016/S1386-1425(00)00495-9 ↗
27. 1064nm dispersive Raman micro-spectroscopy for the in-situ identification of organic red colorants
28. P. Papaevangeliou, A. Zoppi, C. Lofrumento, E. Castellucci, G. Lanterna, M. Galeotti, C. Lalli, La Spettroscopia Raman per la differenziazione e lo studio di lacche rosse, in Atti del IV Congresso Nazionale di Archeometria, Pisa, 2006.
29. An innovative surface-enhanced Raman spectroscopy (SERS) method for the identification of six historical red lakes and dyestuffs10.1002/jrs.1576 ↗
30. Application of surface-enhanced Raman scattering techniques to the ultrasensitive identification of natural dyes in works of art10.1002/jrs.1582 ↗
31. Quantitative characterisation of pigment mixtures used in art by fibre-optics diffuse-reflectance spectroscopy10.1007/s00339-006-3522-3 ↗
32. Non-destructive analysis and identification of pigments on colored relies by fiber optic reflectance spectroscopy
33. A study of the blue colors used by Telemaco Signorini (1835–1901)10.1016/j.culher.2008.05.006 ↗
34. http://fors.ifac.cnr.it/-, Fiber optics reflectance spectra (FORS) of Pictorial Materials in the 270–1700nm range.