Protective coating for paper: new development and analytical characterization
Source abstract
Abstract
Abstract A novel modified “sol–gel” method based on the carboxylate-alumoxanes has been developed for the fabrication of coatings for the protection of degradation of paper. Two types of paper chosen for study: the filter paper (Whatman) and particulate matter from the several pages of ancient manuscript at Lithuanian National M. Mazvydas Library. All paper samples used in this study were coated by hexanato-alumoxane. The obtained hexanato-alumoxane was dissolved in CHCl 3 , and paper specimens were treated in hexanato-alumoxane solution. The filter paper samples were artificially aged at different conditions. All the filter paper samples (untreated, impregnated with hexanato-alumoxane and treated-uncoated) were examined by SEM. The hexanato-alumoxane treated and treated-uncoated paper samples were visually indistinguishable from their untreated equivalents. Analytical characterization of hexanato-alumoxane coated and treated-uncoated of particulate matter from the ancient manuscript showed no degradation of its cellulosic substrate.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Cultural Heritage Materials Analysis · Building materials and conservation · Corrosion Behavior and Inhibition
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (40)
Show source-provided references
1. Sticky problems for conservators of works of art on paper10.1016/0143-7496(95)98747-A ↗
2. Structural evolution of a formamide modified sol–spectroscopic study10.1023/A:1026425304873 ↗
3. Sol–gel coatings on metals10.1023/A:1018373404815 ↗
4. A new approach to characterization of barrier properties of ORMOCER protective coatings10.1023/A:1018399605241 ↗
5. Protective coatings for outdoor bronze sculptures. Available materials and new developments
6. Physical properties of sol–gel coatings, J. Sol–gel Sci
7. Long-term protection of the last judgment mosaic in Prague10.1023/A:1008784221259 ↗
8. Sol–gel nanocoating: an approach to the preparation of structured materials10.1021/cm001257z ↗
9. Organic–inorganic sol–gel coating for corrosion protection of stainless steel10.1023/A:1014733413682 ↗
10. Spectroscopic evaluation of the efficacy of two mass deacidification processes for paper10.1039/jm9920201049 ↗
11. UK paper conservation courses: an overview10.1080/003798199103721 ↗
12. Topochemical investigation of ancient manuscripts10.1007/s002160100750 ↗
13. Derivative infrared spectroscopy and electron spectroscopy for chemical analysis of ancient paper documents
14. An X-ray photoelectron spectroscopic study of ancient paper and its deterioration10.1007/s001140050478 ↗
15. Hydrolytic and oxidative degradation of paper
16. From minerals to materials: synthesis of alumoxanes from the reaction of boehmite with carboxylic acids10.1039/JM9950500331 ↗
17. Gomez-Romero · 2004
18. Carboxylate substituted alumoxanes as processable precursors to transition metal–aluminum and lanthanide–aluminum mixed metal oxides: atomic scale mixing via a new transmetalation reaction10.1021/cm960153e ↗
19. Yttrium doped alumoxanes: a chimie douce route to Y3Al5O12 (YAG) and Y4Al2O9 (YAM)10.1002/adma.19970090116 ↗
20. Surface repair of porous and damaged alumina bodies using carboxylate-alumoxane nanoparticles10.1023/A:1016048409812 ↗
21. From precursors to thin films – thermoanalytical techniques in the thin film technology10.1023/A:1010154818649 ↗
22. Thermogravimetric analysis—a powerful tool for the refinement of the synthesis process of Hg-based superconductors10.1016/S0039-9140(00)00317-9 ↗
23. Schrader · 1995
24. Nakanishi · 1977
25. Infrared study of SiO2 sol to gel evolution and gel aging10.1016/0022-3093(94)00484-6 ↗
26. Spectrochemical characterization by micro-FTIR spectroscopy of blue pigments in different polychrome works of art10.1016/S0924-2031(98)00096-4 ↗
27. Infrared spectroscopy in the mineralogical characterization of ancient pottery10.1016/S1296-2074(02)01178-0 ↗
28. Characterization of binders employed in the manufacture of Venetian historical mortars10.1016/S1296-2074(02)01156-1 ↗
29. Facile synthesis of aluminum-containing mixed-metal oxides using doped carboxylate alumoxane nanoparticles10.1111/j.1151-2916.2000.tb01464.x ↗
30. Effects of aqueous light bleaching on the subsequent aging of paper10.1179/019713692806066583 ↗
31. Aqueous light bleaching of paper: comparison of calcium hydroxide and magnesium bicarbonate bathing solutions10.1179/019713696806113702 ↗
32. Mitchell · 1924
33. On iron gallic ink10.1002/zaac.19915980134 ↗
34. Phytate—a potential conservation agent for the treatment of ink corrosion caused by irongall inks
35. Thompson · 1996
36. FTIR-deconvolution spectra of paper documents
37. The degrading action of iron and copper on paper. A FTIR-deconvolution analysis
38. A semiquantitative assay, based on the TAPPI method, for monitoring changes in gelatin content of paper due to treatmnets10.1179/019713695806124693 ↗
39. Investigation of complexation and solid–liquid extraction of iron from paper by UV/VIS and atomic absorption spectrometry10.1007/s006040170068 ↗
40. Stabilisation of corrosive iron gall inks