journal article·2025-05

Impact of selected driers on the curing kinetics, thermodynamics, and molecular features of commercial artists' oil paints

Silvia Pizzimenti, Giulia Caroti, Luca Bernazzani, Jacopo La Nasa, Elena Pulidori, Amedeo Franco Bonatti, Carmelo De Maria, Guy Van Assche, Francesca Martini, Marco Geppi, Ulysses Jackson, Celia Duce, Ilaria Bonaduce

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Abstract

The study investigates the impact of various metal-based driers on the curing process of commercial artists’ oil paints, focusing on drying time, curing kinetics, molecular structure, and mechanical properties of the final paint film. Six custom-made formulations with different metal-based driers (calcium, zirconium, cobalt, cobalt with calcium, and cobalt with manganese) were tested. Results showed that cobalt-containing driers significantly reduced drying time, while calcium and zirconium had a moderate effect. Cobalt combined with calcium further decreased the drying time, whereas manganese slightly increased it. Depending on the drier and/or driers’ combination the curing kinetic and thermodynamic are influenced. Cobalt-based driers increase surface polarity and promote inhomogeneous cross-linking density. All driers had an influence on the mechanical properties of the paint films: after three years of natural ageing paint layers containing driers are stiffer.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Conservation Techniques and Studies · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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