journal article·2007-06

A new pigment for smart anticorrosive coatings

C. Deyá, R. Romagnoli, B. del Amo

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Abstract

The purpose of this paper was to evaluate the performance of a modified zeolite as an anticorrosive pigment for paints. A procedure to prepare the pigment was outlined and its anticorrosive properties assessed following the electrochemical behavior of a steel electrode in pigment suspension. In a second stage, alkyd paints were formulated employing different anticorrosive pigments: (1) 30% by volume (v/v) of the modified zeolitic rock, (2) 10% (v/v) of zinc phosphate, and (3) a mixture of 10% (v/v) zinc phosphate plus 20% (v/v) of the modified zeolitic rock. In every case, percentages were referred to the total pigment content. Titanium dioxide, zinc oxide, and barium sulfate were incorporated to complete the pigment formula. The pigment volume concentration/critical pigment volume concentration (PVC/CPVC) ratio was 0.8. The performance of the resulting anticorrosive paints was assessed by accelerated (salt spray and humidity chambers) tests and electrochemical (corrosion potential, ionic resistance, and polarization resistance) essays. It was demonstrated that the modified zeolite is effective in protecting steel from corrosion when it is used in combination with zinc phosphate. There exists a synergism between the modified zeolite and zinc phosphate that allows the zinc phosphate content in anticorrosive paints to be reduced.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Pigment Synthesis and Properties · Concrete Corrosion and Durability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (58)

Show source-provided references
1. Romagnoli R, Vetere VF (1995) Heterogeneous Reaction between Steel and Zinc Phosphate, Corrosion (NACE) 51(2):11610.5006/1.3293583 ↗
2. Szklarska-Smialowska Z, Mankowsky J, “Cathodic Inhibition of the Corrosion of Mild Steel in Phosphate, Tungstate, Arsenate and Silicate Solutions Containing Ca2+ ions.” J. Brit. Corros., 4(9) 271 (1969)
3. Meyer, G, “Uber Zinkphosphat und Bariumchromat als moderne Korrosionsinhibitoren.” Farbe+Lack, 69 (7) 528 (1963)
4. Barraclouugh, J, Harrison, JB, “New Leadless Anti-corrosive Primers.” J. Oil Colour Chem. Assoc., 48 (4) 341 (1965)
5. de Fragata FL, Dopico JE (1991) Anticorrosive Behaviour of Zinc Phosphate in Alkyd and Epoxy Binders. J. Oil Colour Chem. Assoc. 74(3):92
6. Romagnoli R, Vetere VF (1995) Non Pollutant Corrosion Inhibitive Pigments: Zinc Phosphate, A Review, Corros. Rev. 13(81):45
7. Svoboda M, Mleziva J (1984) Properties of Coatings Determined by Anticorrosive Pigments, Prog. Org. Coat. 12:25110.1016/0033-0655(84)80011-4 ↗
8. Chromy L, Kaminska E (1990) Non-toxic Anticorrosive Pigments, Prog. Org. Coat. 18:31910.1016/0033-0655(90)85014-O ↗
9. Gerhard A, Bittner A (1986) Second Generation Phosphate Anti-corrosive Pigments. Formulating Rules for Full Replacement of New Anti-corrosive Pigments, J. Coat. Technol., 58 (740):59
10. Bittner A (1989) Advanced Phosphate Anticorrosive Pigments for Compliant Primers, J. Coat. Technol. 61(777):14
11. Romagnoli R, del Amo B, Vetere VF, Vèleva L (2000) High Performance Anticorrosive Epoxy Paints Pigmented with Zinc Molybdenum Phosphate, Surface Coat. Int. 83(1):2710.1007/BF02692684 ↗
12. del Amo B, Romagnoli R, Vetere VF (1996) Study of the Anticorrosive Properties of Zinc Phospahte and Zinc Molybdophosphate in Alkyd Paints, Corros. Rev. 14(1–2):12110.1515/CORRREV.1996.14.1-2.121 ↗
13. Vetere VF, Romagnoli R (1994) Role of Calcium Acid Phosphate as Corrosion Inhibitive Pigment, Brit. Corros. J., 29(2):11510.1179/000705994798267863 ↗
14. Del Amo B, Romagnoli R, Vetere VF (1999) Steel Corrosion Protection by Means of Alkyd Paints Pigmented with Calcium Acid Phosphate, Ind. Eng. Chem. Res., 38:231010.1021/ie9805638 ↗
15. Taketani Y, Kondo H, Kropman M (1993) Proprietary Aluminium Triphosphate Pigments for Water-borne Coatings, Polym. Paint Colour J. 183(4329):270
16. Jackson KG, Kropman M (1988) Novel Water-borne High Performance Steel Primers, Polym. Paint Colour J. 178(4129):559
17. Takahashi M, (1984) Characteristics and Applications of Aluminium Triphosphate as Special Chemical, Polym. Paint Colour J. 174(4133):281
18. Kamiya K, Okuda M, Okajima M (1988) Combination Effect of K-White and Chromate Pigments in Coil Coatings Systems, Polym. Paint Colour J. 178(4228):974
19. Nakano J, Murakami M, Okuda M (1987) Aluminium Triphosphate – Salt Spray Studies, Polym. Paint Colour J. 177(4199):642
20. Nishihara M, Nakano G, Kobayashi M, Nagita M, Murakami M (1984) Studies on Anticorrosive Properties of Aluminium Triphosphate Pigments. Corrosion Inhibition Properties in Alkyd Resin Coatings System, Polym. Paint Colour J. 174(4125):590
21. Noguchi T, Nahono J, Kabayashi M, Nagita M, Kinugasa M, Murakami M (1984) Studies on Anticorrosive Properties of Aluminium Triphosphate Pigments. Corrosion Inhibition Properties in Epoxy Resin Coatings System, Polym. Paint Colour J. 174(4133):888
22. Deyá M, Vetere V, Romagnoli R, del Amo B (2001) Aluminium Tripolyphosphate Pigments for Anticorrosive Paints, Pigment Resin Technol., 30(1):1310.1108/03699420110364129 ↗
23. Vetere V, Deyá M, Romagnoli R, del Amo B (2001) Calcium Tripolyphosphate: an Anticorrosive Pigment for Paints, J. Coat. Technol. 73(917):5710.1007/BF02698398 ↗
24. Deyá M, Blustein G, Romagnoli R, del Amo B (2002) The Influence of the Anion Type on the Anticorrosive Behaviour of Inorganic Phosphates, Surface Coat. Technol. 150:13310.1016/S0257-8972(01)01522-5 ↗
25. Deyá M, Vetere VF, Romagnoli R, Del Amo B (2003) Zinc Tripolyphosphate: An Anticorrosive Pigment for Paints, Surface Coat. Int., 86 B1:7910.1007/BF02699598 ↗
26. Hare, C, “Synergistic Effects of Wollastonite/Inhibitor Combinations in Epoxy Metal Primers.” JPCL, September 53 (1989)
27. Hare, C, “Anatomy of Paint. Extender Pigments.” JPCL, June 43 (1990)
28. Nicholson, JW, “Water-Borne Coatings: A Review of Basic Principles.” J. Oil Colour Chem. Assoc., 70 (1) 1 (1987)
29. Swaraj, P (ed.), “Water-Borne Coatings.” In: Surface Coatings. Science and Technology, 2nd edn. J. Wiley & Sons, Great Britain (1997)
30. Masciale MJ (1995) Water-bornes and High Solids: Innovative Applications, Eur. Coat. J. 1–2:16
31. CEM van der Kolk, Kruijt R, EA de Rouville (1993) Water-based Acrylic Dispersion Paints for the Protection of Structural Steel; A Technology in Full Development, J. Oil Colour Chem. Assoc. 76(7):280
32. Padget JC (1994) Polymers for Water-based Coatings – A Systematic Overview. J. Coat. Technol. 66(839):89
33. Reinhard G (1990) Formulation of Water-borne Dispersions for Corrosion-Protective Primers, Prog. Org. Coat. 18:12310.1016/0033-0655(90)85008-L ↗
34. Spengler E, Fragata FL, Margarit ICP, Mattos OR (1997) Corrosion Protection of Low Toxicity Paints. Prog. Org. Coat. 30:5110.1016/S0300-9440(96)00668-6 ↗
35. Reinhardt G, Rammelt U, Moll A (1996) Zur Pigmente von Wasserlacken fur den Korrosionsschutz, Farbe Lack, 102(5):58
36. Jackson K (1999) Recent Advances in Water-borne Protective Coatings, Surface Coat. Int. 82:34010.1007/BF02720130 ↗
37. Gee S (1997) Water Borne Coatings, Surface Coat. J. 80(7):31610.1007/BF02692678 ↗
38. Liu, L-M, Levon, K, Article on Line of the Othmer Department of Chemical & Biological Sciences & Engineering
39. Romagnoli, R, Deyá, M, del Amo, B, “The Mechanism of the Anticorrosive Action of Calcium-exchanged Silica.” Surface Coat. Int. B, 86 (B2) 135 (2003)10.1007/BF02699625 ↗
40. Kumar, A, Stephenson, LD, “Accelerated Testing of Self-healing Coatings.” Coat. World, June, 24 (2004)
41. Del Amo B, Deyá C, Zalba P (2005) Zeolitic Rock as a New Pigment for Ceiling Paints. Influence of the Pigment Volume Concentration, Micropor. Mesopor. Mater. 84:35310.1016/j.micromeso.2005.06.002 ↗
42. Columbié Pineda, R, Rodríguez Fuentes, G, Victorero Rodríguez, A, Prieto Valdés, JJ, “Utilización de zeolitas modificadas en la obtención de recubrimientos de zeosil.” “Zeolitas’91”, Memorias de la 3° Conferencia Internacional sobre Ocurrencia, Propiedades y Usos de las Zeolitas naturales, p. 21, La Habana, 9–12 de abril de (1991)
43. Cowan, MM, Abshire, KZ, Houk, SL, Evans, SM, “Antimicrobial Efficacy of a Silver–Zeolite Matrix Coatings on Stainless Steel.” J. Ind. Microbiol. Biotechnol., 30 102 (2003)10.1007/s10295-002-0022-0 ↗
44. Torii, K, Sand, LB, Mumpton, FA (eds.), “Utilisation of Natural Zeolites in Japan.” In: Natural Zeolites: Occurrence, Properties and Uses, p. 441. Pergamon Press (1978)
45. Flanigen, E, Mumpton, FA (eds.), “Commercial Properties of Natural Zeolites, chapter 8.” In: Mineralogy and Geology of Natural Zeolites, p. 165. Book Crafters Inc., Michigan (1981)10.1515/9781501508585-012 ↗
46. Ming, DW, Dixon, JB, “Quantitative Determination of Clinoptilolite in soils by a Cation – Exchange Capacity Method.” Clays Clay Minerals, 35 (6) 463 (1987)10.1346/CCMN.1987.0350607 ↗
47. Societé Nouvelle des Couleurs Zinciques: “L’anticorrosion”. Products data sheets and Materials safety data sheets
48. Blustein G, del Amo B, Romagnoli R (2000) The Influence of the Solubility of Zinc Phosphate Pigments on their Anticorrosive Behaviour, Pigment Resin Technol. 29(2):10010.1108/03699420010319148 ↗
49. del Amo, B, Romagnoli, R, Vetere, VF, Hernández, LS, “Study of the Anticorrosive Properties of Zinc Phosphate in Vinyl Paints.” Prog. Org. Coat., 33 28 (1998)10.1016/S0300-9440(97)00124-0 ↗
50. Killeffer, DH, Linz, A, (eds.) “Oxides of Molybdenum.” In: Molybdenum Compounds, p. 46. Interscience Publishers, USA (1952)
51. Li Z, Anghel I, Bowman RS (1998) Sorption of oxyanions by surfactant: modified zeolite, J. Dispers. Sci. Technol. 19(6&7):84310.1080/01932699808913218 ↗
52. Montemor, MF, Simoes, AP, Da Cunha Belo M, Ferreira, MGS, “The Role of Mo in the Behaviour of the Passive Films Formed on Stainless Steel.” In: ISE. The 1997 Joint International Meeting, Abstract 369, 453 (1997)
53. Qvarfort R (1998) Some Observations Regarding the Influence of Molybdenum on the Pitting Corrosion Resistance of Stainless Steel, Corros. Sci. 40(2/3):21510.1016/S0010-938X(97)00118-2 ↗
54. ZSzklarska-Smialowslka, Mankowsky J (1969) Cathodic Inhibition of the Corrosion of Mild Steel in Phosphate, Tungstate, Arsenate and Silicate Solutions Containing Ca2+ ions, Br. Corros. J. 4(9):27110.1179/000705969798325217 ↗
55. Morris RV, H V.Lauer, Lawson CA, Gibson EK Jr, Nace GA, Stewart CJ 1985) Spectral and Othmer Physicochemical Properties of Submicron Powders of Hematite (α-Fe2O3), Maghemite (γ-Fe2O3), Magnetite (Fe3O4), Goethite (α-FeOOH), and Lepidocrocite (γ-FeOOH), Geophys. Res. 90:312610.1029/JB090iB04p03126 ↗
56. Tandon SP, JP Gupta (1970) Diffuse Reflectance Spectrum of Ferric Oxide, Spectros. Lett. 3:29710.1080/00387017008078624 ↗
57. Strens RG, Wood BJ (1979) Diffuse Reflectance Spectra and Optical Properties of Some Iron and Titanium Oxides and Hydroxides, Mineral. Mag. 43:34710.1180/minmag.1979.043.327.06 ↗
58. Castells RC, Meda J, Caprari JJ, Damia M (1983) Particle Packing Analysis of Coatings above the Critical Pigment Volume Concentration, J. Coat. Technol. 55(707):53