journal article·2026-03Open access

Solvent effect on PMMA coating adhesion to soda lime silicate glass

Shaylee M. Becerra, Hande Özbayraktar, Erhan Kilinc, John C. Mauro

Abstract

Abstract Adhesion behavior is a primary consideration when applying a coating to any substrate material. Polymer coatings have been applied to glass for enhanced surface properties and protection. Several research studies have been performed on how the solvent used affects the coating properties such as glass transition temperature, relaxation behavior, and surface morphology. While multiple experiments have been conducted to investigate the solvent effect on polymer adhesion to various substrate materials, research has not yet been substantially conducted using glass as the substrate material. Here, the effect of various solvents on poly (methyl methacrylate) (PMMA) adhesion to soda lime silicate glass is investigated. PMMA is dissolved in four different solvents, acetone, butyl acetate, ethyl acetate, and toluene and coated onto 20 × 20 mm 2 glass substrates via spin coating. Four different methods for measuring coating thickness are explored including ellipsometry, profilometry, atomic force microscopy (AFM), and scanning electron microscopy (SEM). Adhesion is assessed qualitatively via the tape test, ASTM D3359-23. Thickness data showed conclusive proof that the spin coatings were nonuniform. Ultimately, results from the tape test show a solvent effect on PMMA adhesion to glass, establishing toluene to be the strongest out of the four for adhesion. Recommendations for experimental testing and characterization methods are presented.
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Research context

OpenAlex topics: Silicone and Siloxane Chemistry · Building materials and conservation · Polymer Nanocomposites and Properties

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References (73)

Show source-provided references
1. Kramer, PA, Banker, GS, Nadkarni, PD, Kildsig, DO, “Effect of Surface Roughness and Coating Solvent on Film Adhesion to Tablets.” J. Pharmaceut. Sci., 64 1554–1557 (1975)10.1002/jps.2600640931 ↗
2. Taga, Y, “Recent Progress in Coating Technology for Surface Modification of Automotive Glass.” J. Non-Cryst. Solids, 218 335–341 (1997)10.1016/S0022-3093(97)00281-0 ↗
3. Svinterikos, E, Zuburtikudis, I, Khalifeh, HA, Ali, SF, “Multifunctional Polymer-Based Coatings for Outdoor Glass Surfaces: A State of the Art.” Adv. Ind. Eng. Polym. Res., 6 (3) 310–332 (2023)
4. Shahzadi, P, Gilani, SR, Rana, BB, Ghaffar, A, Munir, A, “Transparent, Self-cleaning, Scratch Resistance and Environment Friendly Coatings for Glass Substrate and their Potential Applications in Outdoor and Automobile Industry.” Sci. Rep., 11 20743 (2021)10.1038/s41598-021-00230-9 ↗
5. Dean, DA, “Some Recent Advances in the Packaging of Pharmaceuticals (I).” Drug Dev. Commun.. https://doi.org/10.3109/03639047609051898 (1976)10.3109/03639047609051898 ↗
6. Ewing, AM, “Turning Accidents into Profit Through Careful Observation.” J. Chem. Educ., 13 530 (1936)10.1021/ed013p530 ↗
7. Gy, R, “Tempered and Laminated Glazing for Cars.” In: Encyclopedia of Glass Science, Technology, History, and Culture, John Wiley & Sons, Ltd, 1091–1102 (2021). https://doi.org/10.1002/9781118801017.ch9.2.10.1002/9781118801017.ch9.2 ↗
8. Benedictus, E, “Improvements in and Relating to Glass.” (1910)
9. Dalle Vacche, S, Mariggiò, G, Vitale, A, Bongiovanni, R, Corrado, M, “Compositionally Graded Hydrophobic UV-Cured Coatings for the Prevention of Glass Stress Corrosion.” Coatings, 9 424 (2019)10.3390/coatings9070424 ↗
10. Bos, F, Louter, C, Veer, F, Challenging Glass: Conference on Architectural and Structural Applications of Glass, Faculty of Architecture, Delft University of Technology, IOS Press. (2008)
11. Zeiss, B, Dounce, SM, “Lubricious Coatings To Reduce Silicone Oil & Particle Levels.” Frederick Fumess Publishing Ltd (2016)
12. Schuman, T, Thames, SF, “Coating solvent Effects Producing Adhesion to Molded Plastic Parts.” J. Adhesion Sci. Technol., 19 1207–1235 (2005)10.1163/156856105774429109 ↗
13. Berg, JC, “The Importance of Acid–Base Interactions in Wetting, Coating, Adhesion and Related Phenomena.” Nordic Pulp Paper Res. J., 8 75–85 (1993)10.3183/npprj-1993-08-01-p075-085 ↗
14. Bascom, WD, “Structure of Silane Adhesion Promoter Films on Glass and Metal Surfaces.” Macromolecules, 5 792–798 (1972)10.1021/ma60030a024 ↗
15. Alvarado-Beltrán, CG, Almaral-Sánchez, JL, Ramírez-Bon, R, “Synthesis and Properties of PMMA-ZrO2 Organic–Inorganic Hybrid Films.” J. Appl. Polym. Sci., 132(44) (2015)10.1002/app.42738 ↗
16. Provost, M, Raulin, K, Maindron, T, Gaud, V, “Influence of Silane Coupling Agent on the Properties of UV Curable SiO2-PMMA Hybrid Nanocomposite.” J. Sol-Gel. Sci. Technol., 89 796–806 (2019)10.1007/s10971-018-4861-1 ↗
17. Pacaphol, K, Aht-Ong, D, “The Influences of Silanes on Interfacial Adhesion and Surface Properties of Nanocellulose Film Coating on Glass and Aluminum Substrates.” Surf. Coat. Technol., 320 70–81 (2017)10.1016/j.surfcoat.2017.01.111 ↗
18. Semaltianos, NG, “Spin-Coated PMMA Films.” Microelectron. J., 38 754–761 (2007)10.1016/j.mejo.2007.04.019 ↗
19. Rahman, F, et al. “A Review of Polymethyl Methacrylate (PMMA) as a Versatile Lithographic Resist–With Emphasis on UV Exposure.” Microelectron. Eng., 224 111238 (2020)10.1016/j.mee.2020.111238 ↗
20. Caruso, F, et al. “Frequency-Downconversion Stability of PMMA Coatings in Hybrid White Light-Emitting Diodes.” J. Electron. Mater., 45 682–687 (2016)10.1007/s11664-015-4173-y ↗
21. Di Martino, D, et al. “Straightforward Fabrication of Stable White LEDs by Embedding of Inorganic UV-LEDs into Bulk Polymerized Polymethyl-Methacrylate Doped with Organic Dyes.” Sci. Rep., 4 4400 (2014)10.1038/srep04400 ↗
22. Ali, U, Karim, KJ, Buang, NA, “A Review of the Properties and Applications of Poly (methyl methacrylate) (PMMA).” Polym. Rev., 55 (4) 678–705 (2015)10.1080/15583724.2015.1031377 ↗
23. Kumar, AM, Latthe, SS, Sudhagar, P, Obot, IB, Gasem, ZM, “In-situ Synthesis of Hydrophobic SiO2-PMMA Composite for Surface Protective Coatings: Experimental and Quantum Chemical Analysis.” Polymer, 77 79–86 (2015)10.1016/j.polymer.2015.09.030 ↗
24. Chang, KC, Chuang, TL, Ji, WF, Chang, CH, Peng, YY, Shih, H, Hsu, CL, Yeh, JM, Tang, WC, Su, YC, “UV-Curable Nanocasting Technique to Prepare Bioinspired Superhydrophobic Organic-Inorganic Composite Anticorrosion Coatings.” Exp. Polym. Lett., 9 (2) 143–153 (2015)10.3144/expresspolymlett.2015.15 ↗
25. Wang, J, et al. “Preparation of Superhydrophobic Poly(methyl methacrylate)-Silicon Dioxide Nanocomposite Films.” Appl. Surf. Sci., 257 1473–1477 (2010)10.1016/j.apsusc.2010.08.075 ↗
26. Meena, MK, Sinhamahapatra, A, Kumar, A, “Superhydrophobic Polymer Composite Coating on Glass via Spin Coating Technique.” Colloid Polym. Sci., 297 1499–1505 (2019)10.1007/s00396-019-04560-z ↗
27. Harb, SV, Cerrutti, BM, Pulcinelli, SH, Santilli, CV, Hammer, P, “Siloxane–PMMA Hybrid Anti-corrosion Coatings Reinforced by Lignin.” Surf. Coat. Technol., 275 9–16 (2015)10.1016/j.surfcoat.2015.05.002 ↗
28. Wang, H, Sun, F, Wang, C, Zhu, Y, Wang, H, “A Simple Drop-Casting Approach to Fabricate the Super-Hydrophobic PMMA-PSF-CNFs Composite Coating with Heat-, Wear- and Corrosion-Resistant Properties.” Colloid Polym. Sci., 294 303–309 (2016)10.1007/s00396-015-3772-8 ↗
29. Min, K, et al. “Interfacial Adhesion Behavior of Polyimides on Silica Glass: A Molecular Dynamics Study.” Polymer, 98 1–10 (2016)10.1016/j.polymer.2016.06.017 ↗
30. Krokhina, LS, Kuleznev, VN, Lyusova, LR, Glagolev, VA, “Effect of Solvent on Polymer Interaction in Solution and Properties of Films Obtained.” Polym. Sci. USSR., 18 (3) 756–762 (1976)10.1016/0032-3950(76)90278-1 ↗
31. Bistac, S, Schultz, J, “Solvent Retention in Solution-Cast Films of PMMA: Study by Dielectric Spectroscopy.” Prog. Org. Coat., 31 347–350 (1997)10.1016/S0300-9440(97)00093-3 ↗
32. Ito, A, Ayerdurai, V, Miyagawa, A, Matsumoto, A, Okada, H, Courtoux, A, Yamaguchi, M, “Effects of Residual Solvent on Glass Transition Temperature of Poly (methyl methacrylate).” Nihon Reoroji Gakkaishi., 46 (3) 117–121 (2018)10.1678/rheology.46.117 ↗
33. Spangler, LL, Torkelson, JM, Royal, JS, “Influence of Solvent and Molecular Weight on Thickness and Surface Topography of Spin-Coated Polymer Films.” Polym. Eng. Sci., 30 644–653 (1990)10.1002/pen.760301104 ↗
34. Tippo, T, et al. “The Effects of Solvents on the Properties of Ultra-thin Poly (methyl methacrylate) Films Prepared by Spin Coating.” Thin Solid Films, 546 180–184 (2013)10.1016/j.tsf.2013.05.022 ↗
35. Kaczmarek, H, Chaberska, H, “The Influence of Solvent Residue, Support Type and UV-Irradiation on Surface Morphology of Poly(methyl methacrylate) Films Studied by Atomic Force Microscopy.” Polym. Test., 27 736–742 (2008)10.1016/j.polymertesting.2008.05.005 ↗
36. Briscoe, BJ, Akram, A, Adams, MJ, Johnson, SA, Gorman, DM, “The Influence of Solvent Quality on the Mechanical Properties of Thin Cast Isotactic Poly(methyl methacrylate) Coatings.” J. Mater. Sci., 37 4929–4936 (2002)10.1023/A:1020895104449 ↗
37. Park, H, Lee, SH, “Review on Interfacial Bonding Mechanism of Functional Polymer Coating on Glass in Atomistic Modeling Perspective.” Polymers, 13 2244 (2021)10.3390/polym13142244 ↗
38. Min, K, et al. “Computational Approaches for Investigating Interfacial Adhesion Phenomena of Polyimide on Silica Glass.” Sci. Rep., 7 10475 (2017)10.1038/s41598-017-10994-8 ↗
39. Goyal, S, et al. “Characterizing the Fundamental Adhesion of Polyimide Monomers on Crystalline and Glassy Silica Surfaces: A Molecular Dynamics Study.” J. Phys. Chem. C, 120 23631–23639 (2016)10.1021/acs.jpcc.6b08081 ↗
40. ASTM Standard D3359, 2023,Standard Test Methods for Rating Adhesion by Tape Test, ASTM International, West Conshohocken, PA. (2023) https://doi.org/10.1520/D3359-23, www.astm.org.10.1520/D3359-23 ↗
41. Faghih, MM, Sharp, MK, “Solvent-Based Bonding of PMMA–PMMA for Microfluidic Applications.” Microsyst. Technol., 25 3547–3558 (2019)10.1007/s00542-018-4266-7 ↗
42. Van Dyk, JW, Frisch, HL, Wu, DT, “Solubility, Solvency, and Solubility Parameters.” Ind. Eng. Chem. Prod. Res. Dev., 24 473–478 (1985)10.1021/i300019a028 ↗
43. Belmares, M, et al. “Hildebrand and Hansen Solubility Parameters from Molecular Dynamics with Applications to Electronic Nose Polymer Sensors.” J. Comput. Chem., 25 1814–1826 (2004)10.1002/jcc.20098 ↗
44. Alshehri, S, Haq, N, Shakeel, F, “Solubility, Molecular Interactions and Mixing Thermodynamic Properties of Piperine in Various Pure Solvents at Different Temperatures.” J. Mol. Liquids, 250 63–70 (2018)10.1016/j.molliq.2017.11.167 ↗
45. Evchuk, IY, Musii, RI, Makitra, RG, Pristanskii, RE, “Solubility of Polymethyl Methacrylate in Organic Solvents.” Rus. J. Appl. Chem., 78 1576–1580 (2005)10.1007/s11167-005-0564-9 ↗
46. Patra, N, Barone, AC, Salerno, M, “Solvent Effects on the Thermal and Mechanical Properties of Poly(methyl methacrylate) Casted from Concentrated Solutions.” Adv. Polym. Technol, 30 12–20 (2011)10.1002/adv.20203 ↗
47. Sha, J, et al. “Solubility Determination, Model Evaluation, Hansen Solubility Parameter and Thermodynamic Properties of Benflumetol in Pure Alcohol and Ester Solvents.” J. Chem. Thermodyn., 154 106323 (2021)10.1016/j.jct.2020.106323 ↗
48. He, H, et al. “Solubility Determination, Model Evaluation, Hansen Solubility Parameter and Thermodynamic Properties of N-Hydroxyphthalimide in Eleven Neat Solvents.” J. Mol. Liquids, 325 114677 (2021)10.1016/j.molliq.2020.114677 ↗
49. Fernández-Piérola, I, Horta, A, “Cosolvents of PMMA.” Die Makromolekulare Chemie, 182 1705–1714 (1981)10.1002/macp.1981.021820611 ↗
50. Tyona, MD, “A Theoritical Study on Spin Coating Technique.” Adv. Mater. Res., 2 195–208 (2013)10.12989/amr.2013.2.4.195 ↗
51. Mohajerani, E, Farajollahi, F, Mahzoon, R, Baghery, S, “Morphological and Thickness Analysis for PMMA Spin Coated Films.” J. Optoelectron. Adv. Mater., 9 3901–3906 (2007)
52. Atthi, N, et al. “Study of Optimization Condition for Spin Coating of the Photoresist Film on Rectangular Substrate by Taguchi Design of an Experiment.” Songklanakarin J. Sci. Technol., 31 331–335 (2009)
53. Gordji, ME, Abbaszadeh, S, “A Fixed Point Method for Proving the Stability of Ring (α, β, γ)-Derivations in 22-Banach Algebras.” J. Linear Topol. Algebra.. https://doi.org/10.1016/B978-0-12-803920-5.00002-X (2017)10.1016/B978-0-12-803920-5.00002-X ↗
54. Soman, VV, Kelkar, DS, “FTIR Studies of Doped PMMA–PVC Blend System.” Macromol. Symposia, 277 152–161 (2009)10.1002/masy.200950319 ↗
55. Ramesh, S, Leen, KH, Kumutha, K, Arof, AK, “FTIR Studies of PVC/PMMA Blend Based Polymer Electrolytes.” Spectrochim. Acta A: Mol. Biomol. Spectrosc., 66 1237–1242 (2007)10.1016/j.saa.2006.06.012 ↗
56. El-Batal, FH, et al. “FTIR Spectral Analysis of Corrosion Mechanisms in Soda Lime Silica Glasses Doped with Transition Metal Oxides.” Silicon, 2 41–47 (2010)10.1007/s12633-010-9037-8 ↗
57. Husung, RD, Doremus, RH, “The Infrared Transmission Spectra of Four Silicate Glasses Before and After Exposure to Water.” J. Mater. Res., 5 2209–2217 (1990)10.1557/JMR.1990.2209 ↗
58. Eischens, RP, “Infrared Spectra of Chemisorbed Molecules.” Acc. Chem. Res., 5 74–80 (1972)10.1021/ar50050a005 ↗
59. Efimov, AM, Pogareva, VG, Shashkin, AV, “Water-Related Bands in the IR Absorption Spectra of Silicate Glasses.” J. Non-Cryst. Solids, 332 93–114 (2003)10.1016/j.jnoncrysol.2003.09.020 ↗
60. Yan, Y, Li, J, Liu, Q, Zhou, P, “Evaporation Effect on Thickness Distribution for Spin-Coated Films on Rectangular and Circular Substrates.” Coatings, 11 1322 (2021)10.3390/coatings11111322 ↗
61. Liu, Q, Yan, Y, Meng, L, Zhang, Z, Zhou, P, “Influence of Airflow Disturbance on the Uniformity of Spin Coating Film Thickness on Large Area Rectangular Substrates.” Coatings, 12 1253 (2022)10.3390/coatings12091253 ↗
62. Kumari, B, Kumar, N, “Principle of Bernoulli’s Equation and Its Applications.” NeuroQuantology, 20 5078–5084 (2022)
63. Lévesque, L, “Refractive Index Determination of Materials on Thin Transparent Substrates Using Ellipsometry.” Phys. Educ., 35 359 (2000)10.1088/0031-9120/35/5/309 ↗
64. Van Zele, M, et al. “Thickness Characterization Toolbox for Transparent Protective Coatings on Polymer Substrates.” Materials, 11 1101 (2018)10.3390/ma11071101 ↗
65. Tompkins, HG, Smith, S, Convey, D, “Optimizing the Ellipsometric Analysis of a Transparent Layer on Glass.” Surf. Interf. Anal., 29 845–850 (2000)10.1002/1096-9918(200012)29:12<845::AID-SIA938>3.0.CO;2-Q ↗
66. Rasband, WS. ImageJ. U.S. National Institutes of Health (1997).
67. Jarusuwannapoom, T, et al. “Effect of Solvents on Electro-spinnability of Polystyrene Solutions and Morphological Appearance of Resulting Electrospun Polystyrene Fibers.” Euro. Polym. J., 41 409–421 (2005)10.1016/j.eurpolymj.2004.10.010 ↗
68. Dong, T, Knoshaug, EP, Pienkos, PT, Laurens, LML, “Lipid Recovery from Wet Oleaginous Microbial Biomass for Biofuel Production: A Critical Review.” Appl. Energy, 177 879–895 (2016)10.1016/j.apenergy.2016.06.002 ↗
69. CRC, Handbook of Chemistry and Physics. CRC Press, Boca Raton, FL, (2016). https://doi.org/10.1201/9781315380476.10.1201/9781315380476 ↗
70. Fowkes, FM, “Role of Acid–base Interfacial Bonding in Adhesion.” J. Adhesion Sci. Technol.. https://doi.org/10.1163/156856187X00049 (1987)10.1163/156856187X00049 ↗
71. Chehimi, MM, Abel, M-L, Sahraoui, Z, “An Inverse Gas Chromatographic Study of the PMMA/Conducting Polypyrrole Interface.” J. Adhesion Sci. Technol.,. https://doi.org/10.1163/156856196X00715 (1996)10.1163/156856196X00715 ↗
72. Awaja, F, Gilbert, M, Kelly, G, Fox, B, Pigram, PJ, “Adhesion of Polymers.” Prog. Polym. Sci., 34 948–968 (2009)10.1016/j.progpolymsci.2009.04.007 ↗
73. Newman, DJ, Nunn, CJ, “Solvent Retention in Organic Coatings.” Prog. Org. Coat., 3 221–243 (1975)10.1016/0300-9440(75)80008-7 ↗