journal article·2013-05

Development of heat-resistant anticorrosion urethane siloxane paints

Moussa Tamboura, Anna M. Mikhailova, Meng Qiu Jia

Publisher page

Abstract

Three two-layer heat-resistant and anticorrosion paints have been formulated from urethane siloxane binder and traditional anticorrosion pigments such as micaceous iron oxide (MIO), zinc phosphate (ZP), and aluminum oxide. These pigments were used as the dominant components of different undercoats or topcoats. Heat-resistant pigments such as silicon nitride and glass-spheres were used in the composition of the topcoats. Thermogravimetric analysis of paints shows that the paint with ZP as dominant component of the undercoat have the highest heat-resistance and stability in inert gas and oxygen. The paint with a combination of MIO and ZP has the best hardness as well as the best protective and anticorrosion properties based on the electrochemical impedance spectroscopy. A maximum synergic effect of the properties of pigments seems to appear in this paint. Surface morphology of paints was studied by means of scanning electron microscopy. Heated at different temperatures and for several hours, paint containing MIO as the dominant component in the undercoat exhibits the best mechanical and adhesion properties.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer composites and self-healing · Corrosion Behavior and Inhibition · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (66)

Show source-provided references
1. Wicks, ZW, Jr, Pappas, SP, Wicks, DA, Organic Coatings—Science and Technology, 3rd ed. Wiley, Hoboken (2007)
2. Lambourne, R, Srtivens, TA, Paint and Surface Coatings, 2nd ed. Cambridge University Press, Cambridge (1999)10.1533/9781855737006 ↗
3. Sorensen, PA, Kiil, S, Dam-Johansen, K, Weinel, CE, “Anticorrosive Coatings: A Review.” J. Coat. Technol. Res., 6 (2) 135–176 (2009)10.1007/s11998-008-9144-2 ↗
4. Clarson, SJ, “Silicones and Silicone-Modified Materials: A Concise Overview.” In: Clarson, SJ, Fitzgerald, JJ, Owen, MJ, Smith, SD (eds.) Synthesis and Properties of Silicones and Silicone-Modified Materials, pp. 1–10. American Chemical Society, Washington, DC (2003)10.1021/bk-2003-0838 ↗
5. Finzel, WA, “Properties of High Temperature Silicone Coatings.” J. Prot. Coat. Linings, 8 38–43 (1987)
6. Molotova, VA, Industrial Applications of Silicone Coatings. Khimiya, Moscow (1978)
7. Smith, TL, “Strength of Elastomers. A Perspective.” Rubber Chem. Technol., 51 225–252 (1978)10.5254/1.3545831 ↗
8. Yilgor, I, McGrath, JE, “Polysiloxane Containing Copolymers: A Survey of Recent Developments.” Adv. Polym. Sci., 86 1–86 (1988)10.1007/BFb0025274 ↗
9. Goldberg, EP, “Resinous Mixtures of Polysiloxanes and Polymers from Carbonates of Dihydric Phenols.” US patent 2,999,835, 1961
10. Bostick, EE, “Compatible Polycarbonate-Siloxane Composition.” US patent 3,751,519, 1973
11. Chojnowski, J, Cypryk, M, “Synthesis of Linear Polysiloxanes.” In: Jones, R, Ando, W, Chojnowski, J (eds.) Silicon-Containing Polymers. The Science and Technology of Their Synthesis and Applications, pp. 3–41. Kluwer, Boston (2000)10.1007/978-94-011-3939-7_1 ↗
12. Wen, J, Wilkes, GL, “Organic/inorganic hybrid network materials by the sol–gel approach.” Chem. Mater., 8 1667–1681 (1996)10.1021/cm9601143 ↗
13. Roy, R, “Aids in Hydrothermal Experimentation: II. Methods of Making Mixtures for both ‘Dry’ and ‘Wet’ Phase Equilibrium Studies.” J. Am. Ceram. Soc., 39 (4) 145–146 (1956)10.1111/j.1151-2916.1956.tb14180.x ↗
14. Roy, R, “Ceramics by the Solution Sol–Gel Route.” Science, 238 1664–1669 (1987)10.1126/science.238.4834.1664 ↗
15. Schmidt, H, Scholze, H, Kaiser, H, “Principles of Hydrolysis and Condensation Reaction of Alkoxysilanes.” J. Non-Cryst. Solids, 63 1–11 (1983)10.1016/0022-3093(84)90381-8 ↗
16. Wilkes, GL, Orler, B, Huang, H, “‘Ceramers’: Hybrid Materials Incorporating Polymeric/Oligomeric Species into Inorganic Glasses Utilizing a Sol–Gel Approach.” Polym. Prep., 26 (2) 300–301 (1985)
17. Holohan, AT, George, MH, Barrie, JA, Parker, DG, “Polyhydroxyether-Polydimethylsiloxane Graft Copolymers: 2. Properties and Morphology.” Polymer, 35 977–982 (1994)10.1016/0032-3861(94)90941-5 ↗
18. Wagner, M, Wolf, BA, “Effect of Block Copolymer on the Interfacial Tension Between Two ‘Immiscible’ Homopolymers.” Polymer, 34 (7) 1460–1464 (1993)10.1016/0032-3861(93)90862-5 ↗
19. Knaub, P, Camberlin, Y, Gérard, JF, “New reactive Polymer Blends Based on Poly(urethanes-ureas) (PUR) and Polydisperse Polydimethylsiloxane (PDMS): Control of Morphology Using a PUR-b-PDMS Block Copolymer.” Polymer, 29 (8) 1365–1377 (1988)10.1016/0032-3861(88)90298-4 ↗
20. Khandpur, AK, Guegan, P, Macosko, CW, “Compatibilizers for A/B Blends: A–C–B Triblock Versus A–B Diblock Copolymers.” SPE Regional Technical Conference on Polymer Alloys and Blends, Polyblends’ 95, Quebec, October 1995, pp. 88–96
21. Macosko, CW, Guégan, P, Khandpur, AK, “Compatibilizers for Melt Blending: Premade Block Copolymers.” Macromolecules, 29 (17) 5590–5598 (1996)10.1021/ma9602482 ↗
22. Hamurcu, EE, Baysal, BM, “Interpenetrating Polymer Networks of Poly(dimethylsiloxane): 1. Preparation and Characterization.” Polymer, 34 (24) 5163–5167 (1993)10.1016/0032-3861(93)90264-B ↗
23. Turner, J, Cheng, YL, “Process for Preparing Interpenetrating Polymer Networks of Controlled Morphology.” US patent 6,331,578, 2001
24. Bischoff, R, Gray, SE, “Polysiloxanes in Macromolecular Architecture.” Prog. Polym. Sci., 24 (2) 185–219 (1999)10.1016/S0079-6700(99)00006-4 ↗
25. Yilgor, I, Eynur, T, Bilgin, S, Yilgor, E, Wilkes, GL, “Influence of Soft Segment Molecular Weight on the Mechanical Hystheresis and Set Behavior of Silicone–Urea Copolymers with Low Hard Segment Content.” Polymer, 52 (2) 266–274 (2011)10.1016/j.polymer.2010.11.040 ↗
26. Stoye, D, Freitag, W, Paints, Coatings and Solvents. Wiley, New York (1998)10.1002/9783527611867 ↗
27. Majumbdar, P, Webster, DC, “Preparation of Siloxane−Urethane Coatings Having Spontaneously Formed Stable Biphasic Microtopograpical Surfaces.” Macromolecules, 38 (14) 5857–5859 (2005)10.1021/ma050967t ↗
28. Mathivanan, L, Radhakrishna, S, “Heat-Resistant Anticorrosive Paint from Epoxy-Silicone Vehicles.” Anti-Corros. Methods Mater., 44 (6) 400–406 (1997)10.1108/00035599710185476 ↗
29. Ni, H, Simonsick, WJ, Jr, Skaja, AD, Williams, JP, Soucek, MD, “Polyurea/Polysiloxane Ceramer Coatings.” Prog. Org. Coat., 88 (2) 97–110 (2000)10.1016/S0300-9440(00)00079-5 ↗
30. Oichi, M, Takamiy, K, Kiyoraha, O, Nakanishi, T, “Effect of the Addition of Aramid–Silicone Block Copolymer on Phase Structure and Toughness of Cured Epoxy Resins Modified with Silicone.” Polymer, 39 725–731 (1998)10.1016/S0032-3861(97)00319-4 ↗
31. Qian, M, Soutar, AM, Tan, XH, Zeng, XT, Wijesinghe, SL, “Two-Part Epoxy-Siloxane Hybrid Corrosion Protection Coatings for Carbon Steel.” Thin Solid Films, 517 (17) 5237–5242 (2009)10.1016/j.tsf.2009.03.114 ↗
32. Smith, SD, DeSimone, JM, Huang, H, York, G, Wright, DW, Wilkes, GL, McGrath, JE, “Synthesis and Characterization of Poly(methyl methacrylate)-g-Poly(dimethylsiloxane) Copolymers. I. Bulk and Surface Characterization.” Macromolecules, 25 (10) 2575–2581 (1992)10.1021/ma00036a002 ↗
33. Liu, P, Song, J, He, L, Liang, X, Ding, H, Li, Q, “Alkoxysilane Functionalized Polycaprolactone/Polysilane Modified Epoxy Resin Through Sol–Gel Process.” Eur. Polym. J., 44 940–951 (2008)10.1016/j.eurpolymj.2007.12.014 ↗
34. Wang, D, Bierwagen, GP, “Sol–Gel Coatings on Metals for Corrosion Protection.” Prog. Org. Coat., 64 327–338 (2009)10.1016/j.porgcoat.2008.08.010 ↗
35. Witucki, GL, “The Evolution of Silicon-Based Technology in Coating.” Dow Corning Corp., 26 1202–1208 (2003)
36. Jiang, H, Zheng, Z, Song, W, Wang, X, “Moisture-Cured Polyurethane/Polysiloxane Copolymers: Effect of the Structure of Polyester Diol and NCO/OH Ratio.” J. Appl. Polym. Sci., 108 (6) 3644–3651 (2008)10.1002/app.27343 ↗
37. Leir, CM, Galkiewicz, RK, Kantner, SS, Mazurek, M, “Telechelic Siloxanes with Hydrogen-Bonded Polymerizable End Groups. I. Liquid Rubbers and Elastomers.” J. Appl. Polym. Sci., 117 (2) 656–756 (2010)
38. Barikani, M, Barmar, M, “Thermoplastic Polyurethane Elastomers: Synthesis, and Study of Effective Structural Parameters.” Iran Polym. J., 5 231–235 (1996)
39. Chattopadhyay, DK, Raju, KVSN, “Structural Engineering of Polyurethane Coating for High Performance Applications.” Prog. Polym. Sci., 32 (3) 352–418 (2007)10.1016/j.progpolymsci.2006.05.003 ↗
40. Brinker, CJ, Hurd, AJ, Shunrk, PR, Frye, GC, Ashley, CS, “Review of Sol–Gel Thin Film Formation.” J. Non-Cryst. Solids, 147 424–436 (1992)10.1016/S0022-3093(05)80653-2 ↗
41. Pierre, AC, Introduction to Sol–Gel Processing. Kluwer, Boston (1998)10.1007/978-1-4615-5659-6 ↗
42. Jia, M, Wu, C, Li, W, Gao, D, “Synthesis and Characterization of Silicon Resin with Silphenylene Units in Si–O–Si Backbones.” J. Appl. Polym. Sci., 114 (2) 971–977 (2009)10.1002/app.30635 ↗
43. Mikhailova, AM, Tamboura, M, Jia, MQ, “Synthesis, Characterization and Analyses of Mechanical, Adhesion and Thermal Properties of Polysiloxane Resin Modified with Segmented Polyurethane.” J. Coat. Technol. Res., doi: 10.1007/s11998-012-9424-8 (2012)10.1007/s11998-012-9424-8 ↗
44. Kalendova, A, “Comparison of the Efficiency of Anticorrosive Pigments Based on Phosphates.” Pigment Resin Technol., 31 (6) 381–388 (2002)10.1108/03699420210449070 ↗
45. Kalendova, A, “Effect of Particle Sizes and Shapes of Zinc Metal on the Properties of Anticorrosive Coatings.” Prog. Org. Coat., 46 (4) 324–332 (2003)10.1016/S0300-9440(03)00022-5 ↗
46. Bertoti, I, “Characterization of Nitride Coatings by XPS.” Surf. Coat. Technol., 151–152 194–203 (2002)10.1016/S0257-8972(01)01619-X ↗
47. Heinrich, JG, Kruner, H, Tailoring of Mechanical Properties of Si 3 N 4 Ceramics: Proceeding of the NATO Advanced Research Workshop. Schlos Ringberg/Munich, vol. 276, 1993
48. Yamada, M, Inamoto, T, Fukumoto, M, Yasui, T, “Fabrication of Silicon Nitride Thick Coatings by Reactive RF Plasma Spraying.” Mater. Trans., 45 (12) 3304–3308 (2004)10.2320/matertrans.45.3304 ↗
49. Dombrovsky, LA, Randrianalisoa, JH, Baillis, D, “Infrared Radiative Properties of Polymer Coatings Containing Hollow Microspheres.” Int. J. Heat Mass Transf., 50 1516–1527 (2007)10.1016/j.ijheatmasstransfer.2006.08.034 ↗
50. German, ML, Grinchuk, PS, “Mathematical Model for Calculating the Heat-Protection Properties of the Composite Coating ‘Ceramic Microspheres–Binder’.” J. Eng. Phys. Thermophys., 75 (6) 1301–1313 (2002)10.1023/A:1022150523156 ↗
51. Mansfeld, F, Kendig, MW, “Electrochemical Impedance Test of Protective Coatings.” In: Haynes, C, Baboian, R (eds.) ASTM Publication STP 866, p. 122. ASTM, Philadelphia (1985)
52. Amirudin, A, Thierry, D, Application of Electrochemical Impedance Spectroscopy to Study the Degradation of Polymer-Coated Metals. Swedish Corrosion Institute, Stockholm (1995)
53. O’Donoghe, M, Garrett, R, Datta, V, Roberts, P, Abens, T, Electrochemical Impedance Spectroscopy: Testing Coating for Rapid Immersion Service. Coatings & Linings, Houston (2003)
54. Loveday, D, Peterson, P, Rodgers, B, “Evaluation of Organic Coatings with Electrochemical Impedance Spectroscopy. Part 2: Application of EIS to Coatings.” J. Coat. Technol., 1 (10) 88–93 (2004)
55. Forsgren, A, Corrosion Control Through Organic Coatings. Taylor & Francis Group, New York (2006)10.1201/9781420007022 ↗
56. Drinberg, AS, Ytsko, EF, Kalinskaya, TV, Anti-corrosion Primers, Niproins Lkm, Saint-Petersburg (2006)
57. Tracton, A, Coating Technology Handbook, 3rd ed. Academic Press, New York (2006)10.1201/9781420044089 ↗
58. Chuang, F-S, Tsia, H-Y, Chow, J-D, Tsen, W-C, Shu, Y-C, Jang, S-C, “Thermal Degradation of Poly(siloxane-urethane) Copolymers.” Polym. Degrad. Stab., 93 1753–17761 (2008)10.1016/j.polymdegradstab.2008.07.029 ↗
59. Joki-Korpela, F, Pakkaren, TT, “Incorporation of Polydimethylsiloxane into Polyurethanes and Characterization of Copolymers.” Eur. Polym. J., 47 1694–1708 (2011)10.1016/j.eurpolymj.2011.06.006 ↗
60. Stanciu, A, Bulacovschi, V, Oprea, S, Vlad, S, “Thermal and Mechanical Behaviour of Some New Crosslinked Poly(ester-siloxane) Urethanes.” Polym. Degrad. Stab., 72 (3) 551–558 (2001)10.1016/S0141-3910(01)00063-5 ↗
61. Jenekhe, SA, Chen, XL, “Self-Assembly of Ordered Microporous Materials from Rod-Coil Block Copolymers.” Science, 283 372–375 (1999)10.1126/science.283.5400.372 ↗
62. Olsen, BD, Segalman, RA, “Self-Assembly of Rod-Coil Block Copolymers.” Mater. Sci. Eng. R, 62 (2) 37–66 (2008)10.1016/j.mser.2008.04.001 ↗
63. Mayne, JEO, “The Mechanism of the Inhibition of the Corrosion of Iron and Steel by Means of Paint.” Off. Dig., 24 127–136 (1952)
64. Oliveira, CG, Ferreira, MGS, “Ranking High-Quality Paint Systems Using EIS. Part I: Intact Coatings.” Corros. Sci., 45 123–138 (2003)10.1016/S0010-938X(02)00088-4 ↗
65. Sonke, J, Bos, WM, “Scientific Methods for Qualification and Selection of Protective Coatings.” J. Prot. Coat. Linings (2008)
66. Bos, WM, Ferrari, GM, De Wit, JHW, “Determination of Degradation Mechanisms of Organic Coatings” In: s.n. (ed.) Corrosion and Protection in High Technology Era, pp. 1–16. International Corrosion Council, Beijing (2005)