Chemical, mechanical, and thermal properties of UV-curable cellulose acetate butyrate-based oligomers and their electrospun fibrous mats
Source abstract
Abstract
In this research, toluene diisocyanate-2-hydroxyethyl methacrylate (TDI-HEMA) adduct was used to modify the hydroxyl groups on cellulose acetate butyrate (CAB) structure. The obtained oligomer was characterized by Fourier transform infrared and proton nuclear magnetic resonance (1H NMR) spectroscopies, and gel permeation chromatography, respectively. Then, the UV-cured free films of the modified CAB oligomers were investigated in terms of thermal degradation, physicochemical, wettability, and mechanical properties. The chemical modification process was performed in various percentages; then, the contribution of the unreacted hydroxyl groups of CAB on the wettability, thermal degradation, and air/water vapor permeability properties were all investigated. The mechanical properties, thermal stability, and surface wettability character of pure CAB were improved with TDI-HEMA adduct modification. Electrospinning was used to obtain a fibrous layer in order to search the air/water vapor permeability properties. Modification of CAB caused decline in air/water vapor barrier character and thus enhanced the permeability properties.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Advanced Cellulose Research Studies · Polymer composites and self-healing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (35)
Show source-provided references
1. Cao, Y, Li, H, Zhang, J, “Homogeneous Synthesis and Characterization of Cellulose Acetate Butyrate (CAB) in 1-Allyl-3-Methylimidazolium Chloride (AmimCl) Ionic Liquid.” Ind. Eng. Chem. Res., 50 (13) 7808–7814 (2011)10.1021/ie2004362 ↗
2. El-Sakhawy, M, Kamel, S, Salama, A, Sarhan, H-A, “Carboxymethyl Cellulose Acetate Butyrate: A Review of the Preparations, Properties, and Applications.” J. Drug Deliv., 2014 575969 (2014)10.1155/2014/575969 ↗
3. Hou, A, Zhou, M, Wang, X, “Preparation and Characterization of Durable Antibacterial Cellulose Biomaterials Modified with Triazine Derivatives.” Carbohydr. Polym., 75 (2) 328–332 (2009)10.1016/j.carbpol.2008.07.032 ↗
4. Wang, X, Huang, S, Wang, Y, Wei, P, Chen, Y, Xia, Y, Wang, Y, “Eco-Friendly Cellulose Acetate Butyrate/Poly (Butylene Succinate) Blends: Crystallization, Miscibility, Thermostability, Rheological and Mechanical Properties.” J. Polym. Res., 24 (2) 16 (2017)10.1007/s10965-016-1165-4 ↗
5. Biniaś, W, Biniaś, D, “Formation of Microfibres from Cellulose Acetate Butyrate by Electrospinning with a Surface Modified in Low-Temperature Plasma.” Fibres Text. East. Eur., 22 (4) 37–42 (2014)
6. Çakmakçı, E, Güngör, A, Kayaman-Apohan, N, Kuruca, SE, Çetin, MB, Dar, KA, “Cell Growth on In Situ Photo-Cross-Linked Electrospun Acrylated Cellulose Acetate Butyrate.” J. Biomater. Sci. Polym. Ed., 23 (7) 887–899 (2012)10.1163/092050611X566135 ↗
7. Mitchell, GR, Electrospinning: Principles, Practice and Possibilities, Chap. 1, pp. 1–18. Royal Society of Chemistry (2015)10.1039/9781849735575 ↗
8. Kayaman-Apohan, N, Amanoel, A, Arsu, N, Güngör, A, “Synthesis and Characterization of UV-Curable Vinyl Ether Functionalized Urethane Oligomers.” Prog. Org. Coat., 49 (1) 23–32 (2004)10.1016/S0300-9440(03)00148-6 ↗
9. Xie, J, Zhang, N, Guers, M, Varadan, VK, “Ultraviolet-Curable Polymers with Chemically Bonded Carbon Nanotubes for Microelectromechanical System Applications.” Smart Mater. Struct., 11 (4) 575 (2002)10.1088/0964-1726/11/4/313 ↗
10. Barszczewska-Rybarek, IM, “Characterization of Urethane-Dimethacrylate Derivatives as Alternative Monomers for the Restorative Composite Matrix.” Dent. Mater., 30 (12) 1336–1344 (2014)10.1016/j.dental.2014.09.008 ↗
11. Lei, G, Angeli, S, Kristol, D, Snyder, W, “Preparation of New Blocked Diisocyanate for Dental Application.” J. Polym. Sci. Part A Polym. Chem., 25 (2) 607–615 (1987)10.1002/pola.1987.080250214 ↗
12. Liu, X-D, Sheng, D-K, Gao, X-M, Li, T-B, Yang, Y-M, “UV-Assisted Surface Modification of PET Fiber for Adhesion Improvement.” Appl. Surf. Sci., 264 61–69 (2013)10.1016/j.apsusc.2012.09.107 ↗
13. Wang, F, Hu, J, Tu, W, “Study on Microstructure of UV-Curable Polyurethane Acrylate Films.” Prog. Org. Coat., 62 (3) 245–250 (2008)10.1016/j.porgcoat.2007.12.005 ↗
14. Wang, SJ, Wang, YL, Yang, PF, Li, TD, “Preparation of Polyurethane-Poly(Butyl Acrylate) Hybrid Latexes via Miniemulsion Polymerization.” In: Applied Mechanics and Materials, pp. 3938–3941. Trans Tech Publication (2012)10.4028/www.scientific.net/AMM.204-208.3938 ↗
15. ISO 12947-2: Textiles—Determination of Abrasion Resistance of Fabrics by the Martindale Method—Part 2: Determination of Specimen Breakdown (2017)
16. Bhusari, GS, Umare, SS, Chandure, AS, “Effects of NCO: OH Ratio and HEMA on the Physicochemical Properties of Photocurable Poly(ester-urethane) Methacrylates.” J. Coat. Technol. Res., 12 (3) 571–585 (2015)10.1007/s11998-014-9635-2 ↗
17. ASTM D638-14, Standard Test Method for Tensile Properties of Plastics. ASTM International, West Conshohocken, PA, 2014. www.astm.org (2014)
18. Duran, K, Bozacı, E, Karahan, H, “Protein Esaslı Mamüllerin Enzimatik ÖnTerbiyesi.” Tekstil ve Konfeksiyon, 3 187–192 (2007)
19. EN ISO 9237:1996, TEXTILES. Determination of Permeability of Fabrics to Air (1996)
20. ISO 11092:2014 Textiles, Physiological Effects, Measurement of Thermal and Water-Vapour Resistance Under Steady-State Conditions (Sweating Guarded-Hotplate Test) (2014)
21. Engin, A, Nuray, ÖC, Abdurrahim, Y, Adnan, M, “Investigating the Thermal Comfort Properties of Men’s Jacket as Single and Multiple Layered Material.” Industria Textile, 68 (6) 458–463 (2017)10.35530/IT.068.06.1501 ↗
22. Naeem, J, Akcagun, E, Mazari, A, Havelka, A, Kus, Z, “Analysis of Thermal Properties, Water Vapor Resistance and Radiant Heat Transmission Through Different Combinations of Firefighter Protective Clothing.” Industria Textila, 69 (6) 458–465 (2018)
23. Grepinet, B, Pla, F, Hobbes, P, Swaels, P, Monge, T, “Modeling and Simulation of Urethane Acrylates Synthesis. I. Kinetics of Uncatalyzed Reaction of Toluene Diisocyanate with a Monoalcohol.” J. Appl. Polym. Sci., 75 (5) 705–712 (2000)10.1002/(SICI)1097-4628(20000131)75:5<705::AID-APP13>3.0.CO;2-H ↗
24. Liao, F, Zeng, X-R, Li, H-Q, Lai, X-J, Zhao, F-C, “Synthesis and Properties of UV Curable Polyurethane Acrylates Based on Two Different Hydroxyethyl Acrylates.” J. Cent. S. Univ., 19 (4) 911–917 (2012)10.1007/s11771-012-1092-4 ↗
25. Tan, SZ, Wang, Y, Zhang, YF, Zhou, WL, “Preparation of a Novel Prepolymer of Polyurethane Acrylate.” In: Advanced Materials Research, pp. 153–156. Trans Tech Publication (2012)10.4028/www.scientific.net/AMR.554-556.153 ↗
26. Dong, Y, Mosquera-Giraldo, LI, Troutman, J, Skogstad, B, Taylor, LS, Edgar, KJ, “Amphiphilic Hydroxyalkyl Cellulose Derivatives for Amorphous Solid Dispersion Prepared by Olefin Cross-Metathesis.” Polym. Chem., 7 (30) 4953–4963 (2016)10.1039/C6PY00960C ↗
27. Kunwong, D, Sumanochitraporn, N, Kaewpirom, S, “Curing Behavior of a UV-Curable Coating Based on Urethane Acrylate Oligomer: The Influence of Reactive Monomers.” Sonklanakarin J. Sci. Technol., 33 (2) 201 (2011)
28. Dong, Y, Edgar, KJ, “Imparting Functional Variety to Cellulose Ethers via Olefin Cross-Metathesis.” Polym. Chem., 6 (20) 3816–3827 (2015)10.1039/C5PY00369E ↗
29. Sakai, W, Sadakane, T, Nishimoto, W, Nagata, M, Tsutsumi, N, “Photosensitized Degradation and Crosslinking of Linear Aliphatic Polyesters Studied by GPC and ESR.” Polymer, 43 (23) 6231–6238 (2002)10.1016/S0032-3861(02)00443-3 ↗
30. Tsai, Y, Fan, C-H, Wu, J-H, “Synthesis, Microstructures and Properties of Amorphous Poly(Ethylene Terephthalate-co-Tricyclodecanedimethylene Terephthalate).” J. Polym. Res., 23 (3) 42 (2016). https://doi.org/10.1007/s10965-016-0933-510.1007/s10965-016-0933-5 ↗
31. Tyagi, AK, Choudhary, V, Varma, I, “Effect of Reactive Diluents on Curing Behaviour and Thermal Stability of Urethane Methacrylate.” Angew. Makromol. Chem. Appl. Macromol. Chem. Phys., 189 (1) 105–115 (1991)10.1002/apmc.1991.051890110 ↗
32. Arvanitoyannis, IS, Bosnea, L, “Migration of Substances from Food Packaging Materials to Foods.” Crit. Rev. Food Sci. Nutr., 44 (2) 63–76 (2004)10.1080/10408690490424621 ↗
33. Finnigan, B, Barrier Polymers. The Wiley Encyclopedia of Packaging Technology, Vol. 109. Wiley, New York (2009)
34. Piringer, OG, Baner, AL, Plastic Packaging: Interactions with Food and Pharmaceuticals. Wiley, London (2008)10.1002/9783527621422 ↗
35. Robertson, GL, Food Packaging: Principles and Practice. CRC Press, Boca Raton (2005)10.1201/9781420056150 ↗