Polymer heterogeneity in waterborne coatings
Source abstract
Abstract
An overview is presented of the progress in understanding polymer heterogeneity over the last 20 years and how this has contributed to the improvement of coatings. Solvent-based polymers are homogeneous in nature, since all polymeric materials tend to be dissolved in the same solvent mixture. This is different for most waterborne polymers, which tend to be present in a compartmentalized way. Most polymeric materials are present in particles, which are separated by the continuous aqueous phase. This gives excellent opportunities to create particle morphologies that form the basis for the film morphology after drying of the coating. This article gives an overview of the various types of heterogeneity which are accessible in waterborne polymers and will show how heterogeneity in the polymer can contribute to the solution of several persistent problems of the coating industry.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Polymer Synthesis and Characterization · Polymer Nanocomposites and Properties · Surfactants and Colloidal Systems
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Padget, JC, “Polymers for Water-Based Coatings—A Systematic Overview.” J. Coat. Technol., 66 (839) 89–105 (1994)
2. Hoover, WG, Ree, FH, “Melting Transition and Communal Entropy for Hard Spheres.” J. Chem. Phys., 49 3609–3617 (1968)10.1063/1.1670641 ↗
3. Pusey, PN, Van Megen, W, “Phase Behaviour of Concentrated Suspensions of Nearly Hard Colloidal Spheres.” Nature, 320 (6060) 340–342 (1986)10.1038/320340a0 ↗
4. Bolhuis, PG, Kofke, DA, “Monte Carlo Study of Freezing of Polydisperse Hard Spheres.” Phys. Rev. E, 54 (1) 634–643 (1996)10.1103/PhysRevE.54.634 ↗
5. Pedraza, EP, Soucek, MD, “Bimodal Particle Distribution for Emulsions: The Effect of Interstitial Functional Particles.” Eur. Polym. J., 43 (4) 1530–1540 (2007)10.1016/j.eurpolymj.2007.01.022 ↗
6. Kim, IT, Luckham, PF, “Some Rheological Properties of Bimodal Sized Particulates.” Powder Technol., 77 31–37 (1993)10.1016/0032-5910(93)85004-S ↗
7. Peters, ACIA, Overbeek, GC, Buckmann, AJP, Padget, JC, Annable, T, “Bimodal Dispersions in Coating Applications.” Prog. Org. Coat., 29 (1–4) 183–194 (1996)10.1016/S0300-9440(96)00629-7 ↗
8. Guyot, A, Chu, F, Schneider, M, Graillat, C, McKenna, TF, “High Solid Content Latexes.” Prog. Polym. Sci., 27 (8) 1573–1615 (2002)10.1016/S0079-6700(02)00014-X ↗
9. Schneider, M, Graillat, C, Guyot, A, McKenna, TF, “High Solids Content Emulsions. II. Preparation of Seed Lattices.” J. Appl. Polym. Sci., 84 (10) 1897–1915 (2002)10.1002/app.10512 ↗
10. Muller, H, “Preparation of Multimodal Polymer Dispersions Using Polymeric Stabilizer, and Use There of.” US Patent 7,358,297, 2008
11. Rodriguez, BE, Kaler, EW, Wolfe, MS, “Binary Mixtures of Monodisperse Latex Dispersions. 2. Viscosity.” Langmuir, 8 (10) 2382–2389 (1992)10.1021/la00046a008 ↗
12. Loehr, G, Reinecke, RF, “The Preparation is Described of Bimodal Dispersions by Blending Monomodal Polymer Dispersions Having Different Particle Sizes.” DE-A-3,036,969
13. Moayed, SH, Fatemi, S, Pourmahdian, S, “Synthesis of a Latex with Bimodal Particle Size Distribution for Coating Applications Using Acrylic Monomers.” Prog. Org. Coat., 60 (4) 312–319 (2007)10.1016/j.porgcoat.2007.07.023 ↗
14. Piirma, I, Chang, M, “Emulsion Polymerization of Styrene: Nucleation Studies with Nonionic Emulsifier.” J. Polym. Sci.: Polym. Chem. Ed., 20 489–498 (1982)
15. Boutti, S, Graillat, C, McKenna, TF, “High Solids Content Emulsion Polymerisation Without Intermediate Seeds. Part II. In Situ Generation of Bimodal Lattices.” Polymer, 46 (4 Spec. Iss.) 1211–1222 (2005)10.1016/j.polymer.2004.11.044 ↗
16. Peters, ACIA, Overbeek, GC, Annable, T, “Bimodal Particle Size Distribution Polymer/Oligomer Combinations for Printing Ink Applications.” Prog. Org. Coat., 38 (3) 137–150 (2000)10.1016/S0300-9440(99)00074-0 ↗
17. Blum, H, Höhlein, P, Meixner, J, “Water-Thinnable, Saponification Resistant Binders.” Eur. Coat. J., 8–13 (1989)
18. Tomba, JP, Xiaodong, Y, Li, Fugang, Winnik, MA, Lau, W, “Polymer Blend Latex Films: Miscibility and Polymer Diffusion Studied by Energy Transfer.” Polymer, 49 (8) 2055–2064 (2008)10.1016/j.polymer.2008.02.024 ↗
19. Verkholantsev, VV, “Self-Stratifying Coatings for Industrial Applications.” Pigment Resin Technol., 32 (5) 300–306 (2003)10.1108/03699420310497445 ↗
20. Urban, MW, “Why Coatings Stratify?” Eur. Coat. J., 1–2 36 (2003)
21. Smith, GA, Boucher, SP, Grinstein, RH, “Latex for Heat-Resistant Inks.” US Patent 5,373,045, 1994; Heinz-Hilmar, B, Gyopar, RM, Karl-Heinz, S, “Process for Preparation of Emulsifier-Free Polymer Dispersions.” EP 511520, 1992; Heinz-Hilmar, B, Gyopar, RM, Karl-Heinz, S, “Process for Preparation of Emulsifier-Free Polymer Dispersions.” DE 4113839, 1992; Feustel, D, Meyer, M, Hoefer, R, Oberkobusch, D, Fristad, WE, “Oligomeric Carboxylic Acids as Stabilizers for Emulsion Polymerization.” DE 4026640, 1992; Ely, JK, “Fast Drying Water Inks.” EP 360212, 1990
22. Schlarb, B, Haremza, S, Heckmann, W, Morrison, B, Müller-Mall, R, Rau, MG, “Hydroresin Dispersions: Tailoring Morphology of Latex Particles and Films.” Prog. Org. Coat., 29 (14) 201–208 (1996)10.1016/S0300-9440(96)00619-4 ↗
23. Satgurunathan, R, Roelands, M, van Ginkel, M, “A Polyurethane and Vinyl Polymer Based Recyclable Aqueous Coating Composition.” EP 1694733, 2006
24. Tang, J, Daniels, ES, Dimonie, VL, Vratsanos, MS, Klein, A, El-Aasser, MS, “Mechanical Properties of Films Prepared from Model High-Glass-Transition-Temperature/Low-Glass-Transition-Temperature Latex Blends.” J. Appl. Polym. Sci., 86 (11) 2788–2801 (2002)10.1002/app.11248 ↗
25. Kivilevich, A, “A Paradigm Shift: The New Role of Heterogeneity and Interactions.” J. Coat. Technol., 1 (4) 38–48 (2004)
26. Vidovska, D, Maurer, FHJ, “Tensile Properties and Interfacial Interactions of Bimodal Hard/Soft Latex Blends.” Compos. Interfaces, 13 (8–9) 819–830 (2006)10.1163/156855406779366769 ↗
27. Feng, J, Winnik, MA, Shivers, RR, Clubb, B, “Polymer Blend Latex Films: Morphology and Transparency.” Macromolecules, 28 (23) 7671–7682 (1995)10.1021/ma00127a013 ↗
28. He, Y, Zhu, B, Inoue, Y, “Hydrogen Bonds in Polymer Blends.” Prog. Polym. Sci., 29 1021–1051 (2004)10.1016/j.progpolymsci.2004.07.002 ↗
29. Keddie, JL, Meredith, P, Jones, RAL, Donald, AM, “Film Formation of Acrylic Latices with Varying Concentrations of Non-Film-Forming Latex Particles.” Langmuir, 12 3793–3801 (1996)10.1021/la960046z ↗
30. Utrack, LA, Walsh, DJ, Weiss, RA, “Polymer Alloys, Blends and Ionomers.” ACS Symp. Ser., 395 1–38 (1989)10.1021/bk-1989-0395.ch001 ↗
31. Overbeek, A, Bückmann, F, Martin, E, Steenwinkel, P, Annable, T, “New Generation Decorative Paint Technology.” Prog. Org. Coat., 48 (2–4) 125–139 (2003)10.1016/S0300-9440(03)00101-2 ↗
32. Beetsma, J, “Alkyd Emulsion Paints: Properties, Challenges and Solutions.” Pigment Resin Technol., 27 (1) 12–19 (1998)10.1108/03699429810194401 ↗
33. Overbeek, A, Bückmann, F, Tennebroek, R, Bouman, J, “New Generation Decorative Paint Technology.” Macromol. Symp., 187 (1) 187–198 (2002)10.1002/1521-3900(200209)187:1<187::AID-MASY187>3.0.CO;2-Y ↗
34. Martin, E, Overbeek, GC, Steenwinkel, P, Tennebroek, R, “Aqueous Hyperbranched Macromolecule Coating Compositions.” US Patent 7,094,826, 2006; Buckmann, AJP, Martin, E, Overbeek, GC, Padget, JC, Scheerder, J, Annable, T, “Aqueous Vinyl Polymer Coating Compositions.” US Patent 7,223,813, 2007; Buckmann, AJP, Martin, E, Overbeek, GC, Padget, JC, Scheerder, J, Annable, T, “Aqueous Polyester Coating Compositions.” US Patent 7,022,759, 2007
35. Overbeek, A, Bückmann, F, Martin, E, Steenwinkel, P, Annable, T, Athens Conference on Coatings Science and Technology, pp. 199–216 (2002)
36. Tuck, N, Waterborne and Solvent Based Alkyds and Their End User Applications. Wiley/Sita Series in Surface Coatings Technology, Vol. VI, p. 277. Wiley, London, ISBN 471985910
37. Walsh, DJ, Booth, C, Price, C (eds.), Comprehensive Polymer Science, Vol. 2, p. 135. Pergamon, Oxford (1989)
38. Flick, EW, Water-Based Paint Formulations, Vol. 4. Elsevier (1998), ISBN-13: 978-0-8155-1415-2
39. Pianoforte, K, Coatings World, February 2005
40. Dieterich, D, “Aqueous Emulsions, Dispersions and Solutions of Polyurethanes; Synthesis and Properties.” Prog. Org. Coat., 9 (3) 281–340 (1981)10.1016/0033-0655(81)80002-7 ↗
41. van de Wiel, H, Zom, W, “Waterborne Acrylics and Urethanes for the Coatings Industry.” JOCCA, 64 (7) 263 (1981)
42. Okamoto, Y, Hasegawa, Y, Yoshino, F, “Urethane/Acrylic Composite Polymer Emulsions.” Prog. Org. Coat., 29 175 (1996)10.1016/S0300-9440(96)00660-1 ↗
43. Overbeek, GC, Heuts, MPJ, “Polyurethane Coating Compositions.” US Patent 4,983,662, 1991
44. Wang, C, Chu, F, Guyot, A, Gauthier, C, Boisson, F, “Hybrid Acrylic-Polyurethane Latexes: Emulsion versus Miniemulsion Polymerisation.” J. Appl. Polym. Sci., 101 (6) 3927–3941 (2006)10.1002/app.22889 ↗
45. Guyot, A, Landfester, K, Schork, FJ, Wang, C, “Hybrid Polymer Latexes.” Prog. Polym. Sci., 32 1439–1461 (2007)10.1016/j.progpolymsci.2007.07.003 ↗
46. Sperling, LH, Introduction to Physical Polymer Science, p. 667. John Wiley & Sons, Inc, Hoboken, NJ (2006), ISBN 0-471-70606-X
47. Durant, YG, Sundberg, DC, “Latex Particle Morphology–– Fundamental Aspects: A Review.” Polym. React. Eng., 11 (3) 379–432 (2003)10.1081/PRE-120024421 ↗
48. Sundberg, DC, Casassa, AP, Pantozopoulos, J, Muscato, MR, “Morphology Development of Polymeric Microparticles in Aqueous Dispersions. I. Thermodynamic Considerations.” J. Appl. Polym. Sci., 41 1425 (1990)10.1002/app.1990.070410706 ↗
49. Dimonie, VL, El-Aasser, MS, Vanderhoff, JW, Polym. Mater. Sci. Eng., 58 821 (1988)
50. Winzor, CL, Sundberg, DC, “Conversion Dependent Morphology Predictions for Composite Emulsion Polymers: 1. Synthetic Lattices.” Polymer, 33 (18) 3797–3810 (1992)10.1016/0032-3861(92)90366-5 ↗
51. Stubbs, JM, Sundberg, DC, “Nonequilibrium Particle Morphology Development in Seeded Emulsion Polymerization. III. Effect of Initiator End Groups.” J. Appl. Polym. Sci., 91 (3) 1538–1551 (2004)10.1002/app.13043 ↗
52. Stubbs, JM, Sundberg, DC, “The Dynamics of Morphology Development in Multiphase Latex Particles.” Prog. Org. Coat., 61 156–165 (2008)10.1016/j.porgcoat.2007.09.038 ↗
53. Lee, S, Rudin, A, “Effects of Surfactants and Polymerization Methods on the Morphology of Particles Formed in ‘Core-Shell’ Emulsion Polymerization of Methyl Methacrylate and Styrene.” Macromol. Rapid Commun., 10 655–661 (1989)10.1002/marc.1989.030101208 ↗
54. Jönsson, J-EL, Hassander, H, Jansson, LH, Törnell, B, “Morphology of Two-Phase Polystyrene/Poly(Methyl Methacrylate) Latex Particles Prepared Under Different Polymerization Conditions.” Macromolecules, 24 (1) 126–131 (1991)10.1021/ma00001a021 ↗
55. Karlsson, LE, Karlsson, OJ, Sundberg, DC, “Nonequilibrium Particle Morphology Development in Seeded Emulsion Polymerization. II. Influence of Seed Polymer Tg.” J. Appl. Polym. Sci., 90 (4) 905–915 (2003)10.1002/app.12644 ↗
56. Heuts, M, LeFebre, R, Hilst, LV, Overbeek, G, “Influence of Morphology on Film Formation of Acrylic Dispersions.” Proc. PMSE Symposium on Latex Film Formation, Chicago, IL (1995)10.1021/bk-1996-0648.ch018 ↗
57. Devon, MJ, Gardon, JL, Roberts, GRA, “Effects of Core-Shell Latex Morphology on Film Forming Behavior.” J. Appl. Polym. Sci., 39 (10) 2119–2128 (1990)10.1002/app.1990.070391007 ↗
58. Coogan, RG, Vartan-Boghossian, R, “Aqueous Dispersions.” US Patent 4,927,876, 1990; Goos, HC, Overbeek, GC, “Aqueous Dispersions.” US Patent 5,137,961, 1992; Overbeek, GC, Heuts, MPJ, “Polyurethane Coating Compositions.” US Patent 4,983,662, 1991; Petschke, G, Yang, S, “Urethane-Acrylic Hybrid Polymer Dispersion.” US Patent 6,635,706, 2003; Yang, S, Petschke, G, “Air Curable Water-Borne Urethane-Acrylic Hybrids.” US Patent 6,239,209, 2001
59. Hu, YS, Tao, Y, Hu, CP, “Polyurethaneurea/Vinyl Polymer Hybrid Aqueous Dispersions Based on Renewable Material.” Biomacromolecules, 2 (1) 80–84 (2001)10.1021/bm0000687 ↗
60. Pan, H, Chen, D, “A Strategy for Preparation of Anionic Polyurethane/Acrylate Emulsions.” Polym. Plast. Technol. Eng., 47 (6) 595–599 (2008)10.1080/03602550802059345 ↗
61. Zhu, X, Jiang, X, Zhang, Z, Kong, XZ, “Influence of Ingredients in Water-Based Polyurethane-Acrylic Hybrid Latexes on Latex Properties.” Prog. Org. Coat., 62 (3) 251–257 (2008)10.1016/j.porgcoat.2007.12.006 ↗
62. Satguru, G, McMahon, J, Padget, JC, Coogan, R, “Aqueous Polyurethanes-Polymer with Unusual Colloidal, Morphological and Application Characteristics.” Proceedings of the Waterborne, High-Solids, and Powder Coatings, Symposium, New Orleans (1993)
63. Chao, J, Zhang, XY, Dai, JB, Ge, Z, Feng, LL, “Synthesis of a Novel Core-Shell Type Acrylic-Polyurethane Hybrid Emulsion Containing Siloxane and Fluorine as well as Water and the Oil Resistances of Cured Film.” Chin. Chem. Lett., 17 (8) 1121–1124 (2006)
64. Šebenik, U, Krajnc, M, “Properties of Acrylic-Polyurethane Hybrid Emulsions Synthesized by the Semibatch Emulsion Copolymerization of Acrylates Using Different Polyurethane Particles.” J. Polym. Sci. A: Polym. Chem., 43 (18) 4050–4069 (2005)10.1002/pola.20896 ↗
65. Hirose, M, Kadowaki, F, Zhou, J, “The Structure and Properties of Core-Shell Type Acrylic-Polyurethane Hybrid Aqueous Emulsions.” Prog. Org. Coat., 31 (12) 157–169 (1997)10.1016/S0300-9440(97)00032-5 ↗
66. Dong, A, Feng, S, Sun, D, “Structure-Property Relationships of Core-Shell Type Waterborne Polyacrylate-Polyurethane Microemulsions.” Macromol. Chem. Phys., 199 (12) 2635–2640 (1998)10.1002/(SICI)1521-3935(19981201)199:12<2635::AID-MACP2635>3.0.CO;2-C ↗
67. Šebenik, U, Golob, J, Krajnc, M, “Comparison of Properties of Acrylic-Polyurethane Hybrid Emulsions Prepared by Batch and Semibatch Processes with Monomer Emulsion Feed.” Polym. Int., 52 (5) 740–748 (2003)10.1002/pi.1127 ↗
68. Kim, IH, Shin, JS, Cheong, IW, Kim, JI, Kim, JH, “Seeded Emulsion Polymerization of Methyl Methacrylate Using Aqueous Polyurethane Dispersion: Effect of Hard Segment on Grafting Efficiency.” Colloids Surf. A: Physicochem. Eng. Aspects, 207 (1–3) 169–176 (2002)10.1016/S0927-7757(02)00092-4 ↗
69. Hegedus, CR, Kloiber, KA, “Aqueous Acrylic-Polyurethane Hybrid Dispersion and Their Use in Industrial Coatings.” J. Coat. Technol., 860 39–48 (1996)
70. Kukanja, D, Golob, J, Zupancic-Valant, A, Krainc, MJ, “The Structure and Properties of Acrylic-Polyurethane Hybrid Emulsions and Comparison with Physical Blends.” J. Appl. Polym. Sci., 78 67–80 (2000)10.1002/1097-4628(20001003)78:1<67::AID-APP100>3.0.CO;2-4 ↗
71. Brown, RA, Coogan, GC, Fortier, DG, Reeve, MS, Rega, JD, “Comparing and Contrasting the Properties of Urethane/Acrylic Hybrids with those of Corresponding Blends of Urethane Dispersions and Acrylic Emulsions.” Prog. Org. Coat., 52 73 (2005)10.1016/j.porgcoat.2004.03.009 ↗
72. Wang, C, Chu, F, Guyot, A, “Mechanical Properties of Films from Hybrid Acrylic-Polyurethane Polymer Colloids.” J. Dispers. Sci. Technol., 27 325–330 (2006)10.1080/01932690500358030 ↗
73. Tsavalas, JG, Gooch, JW, Schork, FJ, “Water-Based Crosslinkable Coatings via Miniemulsion Polymerization of Acrylic Monomers in the Presence of Unsaturated Polyester Resin.” J. Appl. Polym. Sci., 75 (7) 916–927 (2000)10.1002/(SICI)1097-4628(20000214)75:7<916::AID-APP8>3.0.CO;2-Z ↗
74. Turpin, ET, “Hydrolysis of Water-Dispersible Resins.” J. Paint Technol., 47 (602), 40–46 (1975)
75. Bender, ML, Chloupek, F, Neveu, MC, “Intramolecular Catalysis of Hydrolytic Reactions. III. Intramolecular Catalysis by Carboxylate Ion in the Hydrolysis of Methyl Hydrogen Phthalate.” J. Am. Chem. Soc., 80 (20) 5384–5387 (1958)10.1021/ja01553a016 ↗
76. O’Neill, G, Rothwell, AR, “Hair Grooming Method Using Linear Polyesters.” US Patent 4,300,580, Eastman Kodak Company, 1981
77. Geurink, PJA, Scherer, T, Buter, R, Steenbergen, A, Henderiks, H, “A Complete New Design for Waterborne 2-Pack PUR Coatings with Robust Application Properties.” Prog. Org. Coat., 55 (2) 119–127 (2006)10.1016/j.porgcoat.2005.08.014 ↗
78. Blount, WW, “Water-Dissipatable Polyester Resins and Coatings Prepared Therefrom.” US Patent 4,910,292, 1990; US Patent 4,973,656, 1990; US Patent 4,990,593, 1991
79. Clark, MD, Phan, HD, Salisbury, JR, Shields, GD, “Small Particle Size Polyester/Acrylic Hybrid Latexes.” US Patent 6,001,922, 1999
80. Anderson, JL, Pekarik, AJ, Tokas, E, “Polymeric Compositions, and the Preparation and Use Thereof.” WO9924485, 1999; Anderson, JL, Pekarik, AJ, Tokas, E, “Polymeric Compositions, and the Preparation and Use Thereof.” EP1030889, 2000; Anderson, JL, Pekarik, AJ, Tokas, E, “Polymeric Compositions, and the Preparation and Use Thereof.” US Patent 6,894,117, 2004
81. Shimizu, T, Higashiura, S, Ohguchi, M, Murase, H, Akitomo, Y, “Water-Borne Polyester for Inks and Coatings: Structural Elucidation of Acrylic-Grafted Polyester and the Particle of Its Aqueous Dispersion.” Polym. Adv. Technol., 10 446–454 (1999)10.1002/(SICI)1099-1581(199907)10:7<446::AID-PAT894>3.0.CO;2-F ↗
82. Schork, FJ, Tsavalas, J, “The Morphology of Alkyd/Acrylate Latexes Produced via Hybrid Miniemulsion Polymerization: Grafting Mechanisms.” Prog. Colloid Polym. Sci., 124 126–130 (2003)
83. Nabuurs, T, “Alkyd-Acrylic Composite Emulsions. Polymerization and Morphology.” PhD Thesis, Eindhoven University of Technology (1997)
84. Schork, FJ, Bechtold, N, Tiarks, F, Antonietti, M, “Waterborne Alkyd Coatings by Miniemulsion Polymerization.” US Patent 6,369,135, 1999
85. Dong, H, Gooch, JW, Schork, FJ, “Waterborne Oil-Modified Polyurethane Coatings via Hybrid Miniemulsion Polymerization.” J. Appl. Polym. Sci., 76 105 (2000)10.1002/(SICI)1097-4628(20000628)76:14<2057::AID-APP8>3.0.CO;2-I ↗
86. van Hamersveld, E, van Es, J, Cuperus, FP, “Oil Acrylate Hybrid Emulsions, Mini-Emulsion Polymerization and Characterization.” Colloid Surf. A: Physicochem. Eng. Aspects, 153 285 (1999)10.1002/(SICI)1097-4628(20000404)76:1<105::AID-APP14>3.0.CO;2-8 ↗
87. Shoaf, GL, Stockl, RR, “Alkyd/Acrylic Hybrid Latexes with Enhanced Oxidative Curing.” Polym. React. Eng., 11 (3) 319–334 (2003)10.1081/PRE-120024417 ↗
88. Zueckert, B, “Process for Producing Improved Alkyd Resin Emulsions.” US Patent 4,333,864, 1982; Zueckert, B, “Aqueous Emulsion of Air Drying and Stoving Alkyd Resins and Process for Producing Said Resins.” US Patent 4,333,865, 1982; Zueckert, B, Awad, R, Weger, W, “Water-Dilutable Brushing Paint Based on Water-Soluble Alkyd Resins.” US Patent 6,489,398, 2002; Awad, R, Dworak, G, Zueckert, B, Weger, W, “Water-Dilutable Air-Drying Protective Coating Compositions.” US Patent 4,996,250, 1991; Billiani, J, Gobec, M, “Process for the Preparation of Water-Dilutable Air-Drying Coating Binders, and the Use Thereof.” US Patent 5,698,625, 1997
89. Zuckert, B, “Aqueous Emulsion of Air Drying and Stoving Alkyd Resins and Process for Producing Said Resins.” US Patent 4,333,865, 1982
90. Landfester, K, Pawelzik, U, Antonietti, M, “Polydimethylsiloxane Latexes and Copolymers by Polymerization and Polyaddition in Miniemulsion.” Polymer, 46 (23) 9892–9898 (2005)10.1016/j.polymer.2005.07.080 ↗
91. Kong, XZ, Ruckenstein, E, “Core-Shell Latex Particles Consisting of Polysiloxane-Poly(Styrene-Methyl Methacrylate-Acrylic Acid): Preparation and Pore Generation.” J. Appl. Polym. Sci., 73 2235–2245 (1999)10.1002/(SICI)1097-4628(19990912)73:11<2235::AID-APP21>3.0.CO;2-0 ↗
92. Kan, CY, Zhu, XL, Yuan, Q, Kong, XZ, “Graft Emulsion Copolymerization of Acrylates and Siloxane.” Polym. Adv. Technol., 8 631–633 (1997)10.1002/(SICI)1099-1581(199711)8:11<631::AID-PAT691>3.0.CO;2-K ↗
93. Pan, G, Wu, L, Zhang, Z, Li, D, “Synthesis and Characterization of Epoxy-Acrylate Composite Latex.” J. Appl. Polym. Sci., 83 (8) 1736–1743 (2002)10.1002/app.10100 ↗
94. De Wet-Roos, D, Knoetze, JH, Cooray, B, Sanderson, RD, “Emulsion Polymerization of an Epoxy-Acrylate Emulsion Stabilized with Polyacrylate. I. Influence of Salt, Initiator, Neutralizing Amine, and Stirring Speed.” J. Appl. Polym. Sci., 71 (8) 1347–1360 (1999)10.1002/(SICI)1097-4628(19990222)71:8<1347::AID-APP14>3.0.CO;2-1 ↗
95. Li, S-X, Wang, W-F, Liu, L-M, Liu, G-Y, “Morphology and Characterization of Epoxy-Acrylate Composite Particles.” Polym. Bull., 61 (6) 749–757 (2008)10.1007/s00289-008-1000-0 ↗
96. Hanrahan, K, Wood, KA, Hedhli, L, Gupta, RR, Skilton, W, “Highly Weatherable Roof Coatings Containing Aqueous Fluoropolymer Dispersions.” WIPO Patent Application WO/2007/030152, 2007
97. Jeong, P, Dimonie, VL, Daniels, ES, El-Aasser, MS, “Hybrid Composite Latexes.” ACS Symp. Ser., 801 357–373 (2002)10.1021/bk-2002-0801.ch024 ↗
98. ASTM D4946-89, “Standard Test Method for Blocking Resistance of Architectural Paints.” ASTM, Philadelphia, PA (2008)
99. Bückmann, F, Overbeek, A, Nabuurs, T, “Self-Crosslinking Surfactant Free Acrylic Dispersions.” Eur. Coat. J., 6 53–60 (2001)
100. Tamai, T, Wanatabe, M, “Acrylic Polymer/Silica Hybrids Prepared by Emulsifier-Free Emulsion Polymerization and the Sol-Gel Process.” J. Polym. Sci. A: Polym. Chem., 44 273–280 (2006)10.1002/pola.21155 ↗