New waterborne acrylic binders for zero VOC paints
Source abstract
Abstract
The development of a waterborne acrylic binder that can be formulated into zero VOC paints requires the tuning of film formation under difficult conditions, hardness, and flexibility properties. To meet these requirements, a model of the ‘ideal’ film was developed and polymers were synthezised to comply with this model. The choice of particle size and glass transition temperature (T g) of the polymer phases were the key parameters in producing the desired film morphology. However, to ensure good mechanical properties, it was also crucial to optimize the interaction between the polymer phases by varying both the polymer composition and the stabilization of the latex.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Asphalt Pavement Performance Evaluation · Polymer Nanocomposites and Properties · Advanced Polymer Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (16)
Show source-provided references
1. Tzitzinou A, Keddie JL, Geurts JM, Peters ACIA, Satguru R (2000) Film Formation of Latex Blends with Bimodal Particle-size Distributions: Consideration of Particle Deformability and Continuity of the Dispersed Phase. Macromol, 33, 2695–270810.1021/ma991372z ↗
2. Keddie JL (1997) Film Formation of Latex. Mater. Sci. Eng. Rep., 21, (3), 101–17010.1016/S0927-796X(97)00011-9 ↗
3. Winnik MA, Feng J (1996) Latex Blends: An Approach to Zero VOC Coatings. J. Coat. Technol., 68(852), 39–50
4. Eckersley ST, Helmer BJ (1997) Mechanistic Considerations of Particle Size Effects on Film Properties of Hard/Soft Latex Blends. J. Coat. Technol., 69(864), 97–10710.1007/BF02696096 ↗
5. Geurts JM, Lammers M, German AL (1996) The Effect of Bimodality of the Particle-size Distribution on Film Formation of Lattices. Colloids Surf. A: Physicochem. Eng. Aspects, 108, (2–3), 295–30310.1016/0927-7757(95)03404-8 ↗
6. Hagen R, Salmen L, Karlsson O, Wesslen B (1996) Viscoelastic Properties and Film Morphology of Heterogeneous Styrene-Butadiene Latexe. J. Appl. Polym. Sci., 62, (7), 1067–107810.1002/(SICI)1097-4628(19961114)62:7<1067::AID-APP13>3.0.CO;2-3 ↗
7. Heuts MPJ, Le Fêbre RA, Van Hilst JLM, Overbeek GC (1996) Influence of Morphology on Film Formation of Acrylic Dispersions. Am. Chem. Soc. Symp. Ser., 648, 271–285
8. Juhue D, Lang J (1995) Film Formation from Dispersion of Core-Shell Latex Particles. Macromol., 28, 1306–130810.1021/ma00108a070 ↗
9. Lepizzera S, Lhommeau C, Dilger G, Pith T, Lambla M (1997) Film-forming Ability and Mechanical Properties of Coalesced Latex Blends. J. Polym. Sci. Part B: Polym. Phys., 35, (13), 2093–210110.1002/(SICI)1099-0488(19970930)35:13<2093::AID-POLB10>3.0.CO;2-# ↗
10. Vandezande GA, Rudin A (1994) Novel Composite Latex Particles for Use in Coatings. J. Coat. Technol., 66(828), 99–108
11. Geurts, JM, Satguru, R, Bouman, J, Overbeek, A, “Aqueous Vinyl Coating Compositions.” WO2006108570, 2006
12. Gerharz B, Butt HJ, Momper B (1996) Morpholoy of Heterogeneous Latex Particles Investigated by Atomic Force Microscopy. Trends Coll. Interf. Sci., 100, 91–9510.1007/BFb0115759 ↗
13. Patel AA, Feng J, Winnik MA, Vancso GJ, McBain CBD (1996) Characterization of Latex Blend Films by Atomic Force Microscopy. Polymer, 37, (25), 5577–558210.1016/S0032-3861(96)00677-5 ↗
14. Wang Y, Juhue D, Winnik MA, Leung OM, Goh MC (1992) Atomic Force Microscopy Study of Latex Film Formation. Langmuir, 8, 760–76210.1021/la00039a004 ↗
15. Colombini D, Hassander H, Karlsson OJ, Maurer FH (2004) Influence of the Particle Size and Particle Size Ratio on the Morphology and Viscoelastic Properties of Bimodal Hard/Soft Latex Blends. Macromol., 37, 6865–687310.1021/ma030455j ↗
16. Colombini D, Hassander H, Karlsson OJ, Maurer FH (2005) Effects of Thermal Annealing on the Viscoelastic Properties and Morphology of Bimodal Hard/Soft Latex Blends. J. Polym. Sci., Part B: Polym. Phys., 43, (17), 2289–230610.1002/polb.20461 ↗