journal article·2011-11

Effect of TiO2 surface treatment on the mechanical properties of cured epoxy resin

Hamad A. Al-Turaif

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Abstract

Mechanical properties of epoxy resin toughened with two different submicron particles of TiO2 at different weight fractions (1, 3, and 5%, respectively) were investigated. The first TiO2 particles are surface treated with Al2O3–SiO2, and the second are surface treated with Al2O3–ZrO2. The composites were characterized by tensile, flexural, pull off and abrasion tests, followed by X-ray photoelectron spectroscopy and scanning electron spectroscopy of the fracture surfaces. A small amount of TiO2 (~1%) submicron particles improves the flexural, abrasion and pull-off strengths, while amounts up to 5% significantly enhance tensile properties only. TiO2 particles surface treated with Al2O3–ZrO2 produce an epoxy composite with higher strength and weight loss but lower pull off strength and more brittle than that prepared with Al2O3–SiO2 particles. The TiO2 particles surface treated with Al2O3–SiO2 have a higher adherence to the epoxy composite matrix than the particles treated with Al2O3–ZrO2 as shown by scanning electron spectroscopy.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Epoxy Resin Curing Processes · Mechanical Behavior of Composites · Polymer Science and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (15)

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1. Ng, CB, Schadler, LS, Siegel, RW, “Synthesis and Mechanical Properties of TiO2-Epoxy Nanocomposites.” Nanostruct. Mater., 12 507–510 (1999)10.1016/S0965-9773(99)00170-1 ↗
2. Wazzan, A, Al-Turaif, A, Abdelkader, A, “Influence of Submicron TiO2 Particles on the Mechanical Properties and Fracture Characteristics of Cured Epoxy Resin.” Polym. Plast. Technol. Eng., 45 1155–1161 (2006)10.1080/03602550600887285 ↗
3. Zhou, Y, White, E, Hosur, M, Jeelani, S, “Effect of Particle Size and Weight Fraction on the Flexural Strength and Failure Mode of TiO2 Particles Reinforced Epoxy.” Mater. Lett., 64 806–809 (2010)10.1016/j.matlet.2010.01.016 ↗
4. Al-Turaif, H, “Effect of Nano TiO2 Particle Size on Mechanical Properties of Cured Epoxy Resin.” Prog. Org. Coat., 69 241–246 (2010)10.1016/j.porgcoat.2010.05.011 ↗
5. Sabzi, M, Mirbedini, SM, Zohuriann-Mehr, J, Atai, M, “Surface Modification of TiO2 Nano-Particles with Silane Coupling Agent and Investigation of its Effect on the Properties of Polyurethane Composite Coating.” Prog. Org. Coat., 65 222–228 (2009)10.1016/j.porgcoat.2008.11.006 ↗
6. Mirmohseni, A, Zavareh, S, “Preparation and Characterization of an Epoxy Nanocomposite Toughened by a Combination of Thermoplastic, Layered and Particulate Nano-Fillers.” Mater. Des., 31 2699–2706 (2010)10.1016/j.matdes.2010.01.035 ↗
7. Buxbaum, G, Pfaff, G (eds.), Industrial Inorganic Pigments, Chapter 2, pp. 67–74. Wiley-VCH Verlag GmbH & Co., KGaA, Weinheim (2008)
8. Al-Masry, W, Trabzuni, F, “Effect of Inorganic Treatment on the Dispersability of TiO2 Pigment.” In: AlChE Spring National Meeting, Orlando, 2006, TWB03
9. Tyler, F, “Tailoring TiO2 Treatment Chemistry to Achieve Desired Performance Properties.” Paints Coat. Ind., (2010). http://pcimag.com
10. Klein, DH, Jörg, K, Dinnissen, T, “Epoxy Binders for the Protection of Concrete.” Surf. Coat. Int. B Coat. Trans., 81 (12) 588–593 (1998)10.1007/BF02693052 ↗
11. Dow Technical Literature, CH 22-011-E-18710.1353/chl.0.0267 ↗
12. ASTM D 638-91, Standard Test Methods for Tensile Properties of Plastics. American Society for Testing and Materials, 1992
13. ASTM D 790-03, Standard Test Methods for Flexural Properties of Unreinforced and Reinforced Plastics and Insulating Materials. American Society for Testing and Materials, 2003
14. ASTM D 4060-07, Test Method for Abrasion Resistance of Organic Coatings by the Taber Abraser. American Society for Testing and Materials, 2007
15. ASTM D 4541-95, Standard Test Methods for Pull-Off Strength of Coatings Using Portable Adhesion Testers. American Society for Testing and Materials, 1995