Lignocellulose pretreatment by deep eutectic solvents and related technologies: A review
Source abstract
Abstract
Lignocellulose is the main component of plants and has a wide range of sources. The high-value production of lignocellulose lies in the biorefinery of lignin, cellulose and hemicellulose. The advantages and disadvantages of traditional lignocellulose pretreatment methods were summarized, and the effective pretreatment parameters were listed. As a green solvent system with excellent performance, deep eutectic solvents (DES) are considered to be the most potential biomass pretreatment system. Based on this, the new trend and progress of DES in lignocellulose pretreatment were reviewed, focusing on the effects of distinct kinds of lignocellulose raw materials, distinct components of DES, distinct reaction conditions and assisted by microwave ultrasound on the pretreatment of lignocellulose, and the recyclability of DES solution system was discussed. Finally, the application and development direction of DES in lignocellulose pretreatment are proposed and prospected.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Catalysis for Biomass Conversion · Biofuel production and bioconversion · Lignin and Wood Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (76)
Show source-provided references
1. Unique low-molecular-weight lignin with high purity extracted from wood by deep eutectic solvents (DES): a source of lignin for valorization10.1039/C6GC01007E ↗
2. Treatments to improve obtention of reducing sugars from agave leaves powder10.1016/j.indcrop.2017.12.039 ↗
3. Metal oxides and ultraviolet light-based photocatalytic pretreatment of biomass for biogas production and lignin oxidation10.15376/biores.15.1.1747-1762 ↗
4. Integrated hydrothermal and deep eutectic solvent-mediated fractionation of lignocellulosic biocomponents for enhanced accessibility and efficient conversion in anaerobic digestion10.1016/j.biortech.2022.127034 ↗
5. Effect of lignocellulose substrate on enzyme denaturation during joint mechanical treatment10.1007/s11172-015-0960-0 ↗
6. Comparative genome analysis of Bacillus velezensis reveals a potential for degrading lignocellulosic biomass10.1007/s13205-018-1270-7 ↗
7. A novel deep eutectic solvent from lignin-derived acids for improving the enzymatic digestibility of herbal residues from cellulose10.1007/s10570-018-2190-8 ↗
8. Effects of hydrothermal pretreatment on the structural characteristics of organosolv lignin from Triarrhena lutarioriparia10.3390/polym10101157 ↗
9. Deep eutectic solvent pretreatment enabling full utilization of switchgrass10.1016/j.biortech.2018.04.058 ↗
10. Ultrafast fractionation of lignocellulosic biomass by microwave-assisted deep eutectic solvent pretreatment10.1016/j.biortech.2017.11.066 ↗
11. Purification of Kraft cellulose under mild conditions using choline acetate based deep eutectic solvents10.1039/D0GC03375H ↗
12. Deep eutectic solvent extraction of high-purity lignin from a corn stover hydrolysate10.1002/cssc.202001243 ↗
13. Bioethanol production from steam-exploded barley straw by Co-fermentation with Escherichia coli SL10010.3390/agronomy12040874 ↗
14. Alkali/urea pretreatment of rice straw at low temperature for enhanced biological hydrogen production10.1016/j.biortech.2018.05.055 ↗
15. Benzenesulfonic acid-based hydrotropic system for achieving lignocellulose separation and utilization under mild conditions10.1016/j.biortech.2021.125379 ↗
16. Microwave-assisted acid pretreatment of alkali lignin: effect on characteristics and pyrolysis behavior10.1016/j.biortech.2017.12.022 ↗
17. Novel two-pot approach ultrasonication and deep eutectic solvent pretreatments for watermelon rind delignification: parametric screening and optimization via response surface methodology10.1016/j.energy.2020.117872 ↗
18. Chemical-mechanical pretreatment of wood: reducing downsizing energy and increasing enzymatic digestibility10.1016/j.biombioe.2015.04.011 ↗
19. A novel deep eutectic solvent-mediated Fenton-like system for pretreatment of water hyacinth and biobutanol production
20. A review on the environment-friendly emerging techniques for pretreatment of lignocellulosic biomass: mechanistic insight and advancements10.1016/j.chemosphere.2020.128523 ↗
21. Effect of Rhodococcus sp. pretreatment on cellulose hydrolysis of corn stalk10.1080/10826068.2020.1799391 ↗
22. Microwave irradiation assisted intensive and quick delignification of lignocellulosic biomass, and confirmation by spectral, morphological and crystallinity characterization10.1016/j.biortech.2022.127029 ↗
23. Biological pretreatment of lignocelluloses with white-rot fungi and its applications: a review10.15376/biores.6.4.5224-5259 ↗
24. A sequential pretreatment of lignocelluloses in bamboo biomass to fermentable sugars by acid/enzymatic hydrolysis10.1007/s13205-017-0892-5 ↗
25. Enhancement of lignin removal and enzymolysis of sugarcane bagasse by ultrasound-assisted ethanol synergized deep eutectic solvent pretreatment10.1016/j.renene.2021.03.050 ↗
26. High production yield and more thermally stable lignin-containing cellulose nanocrystals isolated using a ternary acidic deep eutectic solvent10.1021/acssuschemeng.0c01724 ↗
27. A novel ternary combination of deep eutectic solvent-alcohol (DES-OL) system for synergistic and efficient delignification of biomass10.1016/j.biortech.2018.06.002 ↗
28. Effect of hydrothermal pretreatment severity on lignin inhibition in enzymatic hydrolysis10.1016/j.biortech.2019.02.051 ↗
29. Biomass pretreatment using deep eutectic solvents from lignin derived phenols10.1039/C7GC03029K ↗
30. Secondary agriculture residues pretreatment using deep eutectic solvents10.1007/s12649-020-01176-1 ↗
31. Lignocellulosic materials as reinforcement and replacement for binders in masonry mortar
32. Effect of choline-based deep eutectic solvent pretreatment on the structure of cellulose and lignin in bagasse10.3390/pr9020384 ↗
33. Application of deep eutectic solvents in lignocellulosic biomass processing
34. Research progress of lignin degradation in deep eutectic solvents
35. Fractionation and characterization of lignin streams from unique high-lignin content endocarp feedstocks10.1186/s13068-018-1305-7 ↗
36. Insight into understanding the performance of deep eutectic solvent pretreatment on improving enzymatic digestibility of bamboo residues10.1016/j.biortech.2020.123163 ↗
37. Irradiation pretreatment facilitates the achievement of high total sugars concentration from lignocellulose biomass10.1016/j.biortech.2017.01.061 ↗
38. Enhanced enzymatic hydrolysis and lignin extraction of wheat straw by triethylbenzyl ammonium chloride/lactic acid-based deep eutectic solvent pretreatment10.1021/acsomega.9b02709 ↗
39. Characterization of lignin extracted from willow by deep eutectic solvent treatments10.3390/polym10080869 ↗
40. One-step lignocellulose fractionation using acid/pentanol pretreatment for enhanced fermentable sugar and reactive lignin production with efficient pentanol retrievability10.1016/j.biortech.2022.127503 ↗
41. Comparison of alkali and ionic liquid pretreatment methods on the biochemical methane potential of date palm waste biomass10.1016/j.biortech.2022.127505 ↗
42. Comparative analysis of lignin chemical structures of sugarcane bagasse pretreated by alkaline, hydrothermal, and dilute sulfuric acid methods10.1016/j.indcrop.2018.04.077 ↗
43. Development of sustainable biorefinery processes applying deep eutectic solvents to agrofood wastes10.3390/en15114101 ↗
44. Evaluation, applicability and optimization of advanced oxidation process for pretreatment of rice straw and its effect on cellulose digestibility10.1016/j.renene.2017.12.074 ↗
45. Effect of hydrogen bond donor on the choline chloride-based deep eutectic solvent-mediated extraction of lignin from pine wood10.1016/j.ijbiomac.2020.09.145 ↗
46. Investigation of pretreatment parameters in the delignification of paddy husks with deep eutectic solvents10.1016/j.biombioe.2020.105811 ↗
47. A combined pretreatment with ultrasound-assisted alkaline solution and aqueous deep eutectic solvent for enhancing delignification and enzymatic hydrolysis from oil palm fronds10.1016/j.indcrop.2020.112974 ↗
48. Deep eutectic solvents pretreatment of agro-industrial food waste10.1186/s13068-018-1034-y ↗
49. Enhanced cellulase accessibility using acid-based deep eutectic solvent in pretreatment of empty fruit bunches10.1007/s10570-019-02770-w ↗
50. Insights on the cellulose pretreatment at room temperature by choline-chloride-based deep eutectic solvents: an atomistic study10.1007/s10570-022-04671-x ↗
51. Natural deep eutectic solvents for lignocellulosic biomass pretreatment: recent developments, challenges and novel opportunities10.1016/j.biotechadv.2018.08.009 ↗
52. Dissolution of α-chitin in deep eutectic solvents10.1039/c3ra43404d ↗
53. Structural and morphological transformations of lignin macromolecules during bio-based deep eutectic solvent (DES) pretreatment10.1021/acssuschemeng.9b05106 ↗
54. Facile fractionation of lignocelluloses by biomass-derived deep eutectic solvent (DES) pretreatment for cellulose enzymatic hydrolysis and lignin valorization10.1039/C8GC03064B ↗
55. Influence of ultrasonic pretreatment on the yield of bio-oil prepared by thermo-chemical conversion of rice husk in hot-compressed water10.1016/j.biortech.2013.07.094 ↗
56. Lignocellulosic biomass based microbial fuel cells: performance and applications10.1016/j.jclepro.2022.132269 ↗
57. Valorization of agro-industrial residues for production of commercial biorefinery products
58. Deep eutectic solvent for lignocellulosic biomass fractionation and the subsequent conversion to bio-based products - a review10.1016/j.biortech.2019.122522 ↗
59. Evaluation of fractionation and delignification efficiencies of deep eutectic solvents on oil palm empty fruit bunch10.1016/j.indcrop.2018.06.091 ↗
60. Generation of highly amenable cellulose-Iβ via selective delignification of rice straw using a reusable cyclic ether-assisted deep eutectic solvent system10.1038/s41598-020-80719-x ↗
61. Kinetic study and pyrolysis characteristics of algal and lignocellulosic biomasses10.1016/j.biortech.2019.121496 ↗
62. The role of lignocellulosic composition and residual lipids in empty fruit bunches on the production of humic acids in submerged fermentations10.1007/s12010-018-2850-z ↗
63. Improving enzymatic hydrolysis of hybrid Pennisetum (Pennisetum americanum × P. purpureum) by dehydration combined with dry explosion pretreatment
64. Novel recyclable deep eutectic solvent boost biomass pretreatment for enzymatic hydrolysis10.1016/j.biortech.2020.123237 ↗
65. Comprehensive analysis of important parameters of choline chloride-based deep eutectic solvent pretreatment of lignocellulosic biomass10.1016/j.biortech.2020.124209 ↗
66. Mechanism of deep eutectic solvent delignification: insights from molecular dynamics simulations10.1021/acssuschemeng.1c01260 ↗
67. Tandem character of liquid hot water and deep eutectic solvent to enhance lignocellulose deconstruction10.1002/cssc.202100765 ↗
68. Synergistic effects of metal salt and ionic liquid on the pretreatment of sugarcane bagasse for enhanced enzymatic hydrolysis10.1016/j.biortech.2017.10.018 ↗
69. Recycling of deep eutectic solvent for sustainable and efficient pretreatment of corncob10.1016/j.indcrop.2022.115005 ↗
70. Using γ-valerolactone and toluenesulfonic acid to extract lignin efficiently with a combined hydrolysis factor and structure characteristics analysis of lignin10.1007/s10570-020-03023-x ↗
71. High-yield lipid production from lignocellulosic biomass using engineered xylose-utilizing Yarrowia lipolytica10.1111/gcbb.12699 ↗
72. Characterization of mechanical pulverization/phosphoric acid pretreatment of corn stover for enzymatic hydrolysis10.1016/j.biortech.2019.02.104 ↗
73. Enzyme immobilization as a strategy towards efficient and sustainable lignocellulosic biomass conversion into chemicals and biofuels: current status and perspectives10.1039/D1SE00747E ↗
74. Influence of ultrasonic/torrefaction assisted deep eutectic solvents on the upgrading of bio-oil from corn stalk10.1021/acssuschemeng.0c00837 ↗
75. Organosolv fractionation of a lignocellulosic biomass feedstock using a pilot scale microwave-heating reactor10.1016/j.indcrop.2022.114700 ↗
76. Recyclable deep eutectic solvent coupling sodium hydroxide post-treatment for boosting woody/herbaceous biomass conversion at mild condition10.1016/j.biortech.2020.124327 ↗