Processing and valorization of cellulose, lignin and lignocellulose using ionic liquids
Source abstract
Abstract
Cellulose, lignin and lignocellulose are important bioresources in the nature. Their effective and environmentally friendly utilization not only reduces dependence on fossil resources but also protects the environment. Recently, a class of novel eco-friendly solvents, ionic liquids, is employed to dissolve and process these bioresources. In this mini-review, we summarized the recent advances of processing and valorization of cellulose, lignin and lignocellulose in ionic liquids. It is expected that this up-to-date survey provides a comprehensive information of this field, and accelerates the development and utilization of the renewable plant biomass resources.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Lignin and Wood Chemistry · Catalysis for Biomass Conversion · Biofuel production and bioconversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Effects of dissolution of some lignocellulosic materials with ionic liquids as green solvents on mechanical and physical properties of composite films10.1016/j.carbpol.2013.02.040 ↗
2. Interactions between callose and cellulose revealed through the analysis of biopolymer mixtures10.1038/s41467-018-06820-y ↗
3. Ionic liquid-mediated technology to produce cellulose nanocrystals directly from wood10.1016/j.carbpol.2015.07.079 ↗
4. Induction of lignin solubility for a series of polar ionic liquids by the addition of a small amount of water10.1039/C7GC00626H ↗
5. Structural analysis of Ioncell-F fibres from birch wood10.1016/j.carbpol.2017.11.062 ↗
6. Natural sporopollenin microcapsules facilitated encapsulation of phase change material into cellulose composites for smart and biocompatible materials10.1021/acsami.9b15530 ↗
7. anniversary: high-molecular-weight chitin and cellulose hydrogels from biomass in ionic liquids without chemical crosslinking10.1021/acs.iecr.9b03078 ↗
8. Deconstruction of lignocellulosic biomass with ionic liquids10.1039/c2gc36364j ↗
9. Mechanical properties of cellulose aerogels and cryogels10.1039/C9SM01028A ↗
10. Enhancing the carbon yield of cellulose based carbon fibres with ionic liquid impregnates10.1039/C4TA04059G ↗
11. Controllable synthesis of cellulose benzoates for understanding of chiral recognition mechanism and fabrication of highly efficient chiral stationary phases10.1039/C8AY00162F ↗
12. Highly thermostable, flexible, and conductive films prepared from cellulose, graphite, and polypyrrole nanoparticles10.1021/acsami.5b04462 ↗
13. Conversion of lignin model compounds under mild conditions in pseudo-homogeneous systems10.1039/C5GC03121D ↗
14. Chiral separation abilities of homogeneously synthesized cellulose 3, 5-dimethylphenylcarbamates: influences of degree of substitution and molecular weight10.1007/s10118-015-1695-y ↗
15. Homogeneous synthesis of partially substituted cellulose phenylcarbamates aiming at chiral recognition10.1002/pi.4884 ↗
16. Novel thermoplastic cellulose esters containing bulky moieties and soft segments10.1021/acssuschemeng.7b04466 ↗
17. Oxygen enhances polyoxometalate-based catalytic dissolution and delignification of woody biomass in ionic liquids10.1021/sc500614m ↗
18. MoDoop: an automated computational approach for COSMO-RS prediction of biopolymer solubilities in ionic liquids10.1021/acsomega.8b03255 ↗
19. Oxidative depolymerization of lignin using a novel polyoxometalate-protic ionic liquid system10.1021/acssuschemeng.6b01339 ↗
20. Cellulose-silica aerogels10.1016/j.carbpol.2015.01.022 ↗
21. Synthesis and property study of cellulose methyl carbonate in DMSO/DBU/CO2 system via in situ organocatalysis10.1360/N032018-00012 ↗
22. Lignin/chitin films and their adsorption characteristics for heavy metal ions10.1021/acssuschemeng.8b00805 ↗
23. Supramolecular composite materials from cellulose, chitosan, and cyclodextrin: facile preparation and their selective inclusion complex formation with endocrine disruptors10.1021/la3050016 ↗
24. Enantiomeric selective adsorption of amino acid by polysaccharide composite materials10.1021/la404003t ↗
25. Engineering lignocellulose fibers with higher thermal stability through natural fiber welding10.1002/mame.201900042 ↗
26. Lignocellulose fiber- and welded fiber- supports for palladium-based catalytic hydrogenation: a natural fiber welding application for water treatment10.1021/acssuschemeng.6b01250 ↗
27. Lignin-containing cellulose nanomaterials: a promising new nanomaterial for numerous applications
28. Can ionic liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride10.1039/B607614A ↗
29. Highly water repellent aerogels based on cellulose stearoyl esters10.1039/c0py00309c ↗
30. Ionic liquid lignosulfonate: dispersant and binder for preparation of biocomposite materials10.1002/anie.201907385 ↗
31. A hierarchical model to understand the processing of polysaccharides/protein-based films in ionic liquids10.1021/acs.biomac.8b00903 ↗
32. A possible means of realizing a sacrifice-free three component separation of lignocellulose from wood biomass using an amino acid ionic liquid10.1039/c3gc40445e ↗
33. Ionic liquid induces flexibility and thermoplasticity in cellulose film10.1016/j.carbpol.2019.115058 ↗
34. Wet spun fibers from solutions of cellulose in an ionic liquid with suspended carbon nanoparticles10.1002/app.41417 ↗
35. The effect of changing the components of an ionic liquid upon the solubility of lignin10.1039/C4GC01888E ↗
36. Recycling of vat and reactive dyed textile waste to new colored man-made cellulose fibers10.1039/C9GC02776A ↗
37. Dry jet-wet spinning of strong cellulose filaments from ionic liquid solution10.1007/s10570-014-0414-0 ↗
38. Cellulose regeneration and spinnability from ionic liquids10.1039/C5SM02618K ↗
39. A critical review of all-cellulose composites10.1007/s10853-011-5774-3 ↗
40. Cellulosic nonwovens produced via efficient solution blowing technique.10.1002/app.48339 ↗
41. Amine-responsive cellulose-based ratiometric fluorescent materials for real-time and visual detection of shrimp and crab freshness10.1038/s41467-019-08675-3 ↗
42. Sunlight-driven wearable and robust antibacterial coatings with water-soluble cellulose-based photosensitizers10.1002/adhm.201801591 ↗
43. Cleaving the β;-O-4 bonds of lignin model compounds in an acidic ionic liquid, 1-H-3-methylimidazolium chloride: an optional strategy for the degradation of lignin10.1002/cssc.201000112 ↗
44. Decomposition of a phenolic lignin model compound over organic N-bases in an ionic liquid10.1515/hf.2010.075 ↗
45. Hydrolytic cleavage of β;-O-4 ether bonds of lignin model compounds in an ionic liquid with metal chlorides10.1021/ie101884h ↗
46. Hydrogels derived from lignocellulosic compounds: evaluation of the compositional, structural, mechanical and antimicrobial properties10.1016/j.indcrop.2018.11.002 ↗
47. The chemistry of acid catalyzed delignification of sugarcane bagasse in the ionic liquid trihexyl tetradecyl phosphonium chloride10.1080/02773813.2011.573120 ↗
48. Hydroxypropyl cellulose based non-volatile gel polymer electrolytes for dye-sensitized solar cell applications using 1-methyl-3-propylimidazolium iodide ionic liquid10.1038/srep18056 ↗
49. Dissolution of wood in ionic liquids10.1021/jf071692e ↗
50. Hydrophobic interactions determining functionalized lignocellulose solubility in dialkylimidazolium chlorides, as probed by31P NMR10.1021/bm8010159 ↗
51. Twenty-five years of cellulose chemistry: innovations in the dissolution of the biopolymer and its transformation into esters and ethers10.1007/s10570-018-2198-0 ↗
52. Superbase ionic liquids for effective cellulose processing from dissolution to carbonisation10.1039/C7GC02671D ↗
53. Screening cellulose spinning parameters for fabrication of novel carbon hollow fiber membranes for gas separation10.1021/acs.iecr.9b02480 ↗
54. Spinning cellulose hollow fibers using 1-ethyl-3-methylimidazolium acetate–dimethylsulfoxide Co-solvent10.3390/polym10090972 ↗
55. Direct and complete utilization of agricultural straw to fabricate all-biomass films with high-strength, high-haze and UV-shielding properties10.1016/j.carbpol.2019.115057 ↗
56. A lignin-epoxy resin derived from biomass as an alternative to formaldehyde-based wood adhesives10.1039/C7GC03026F ↗
57. Self-healing and injectable polysaccharide hydrogels with tunable mechanical properties10.1007/s10570-017-1546-9 ↗
58. Facile synthesis of cellulose derivatives based on cellulose acetoacetate10.1016/j.carbpol.2017.04.043 ↗
59. Facile fabrication of redox/pH dual stimuli responsive cellulose hydrogel10.1016/j.carbpol.2017.08.085 ↗
60. Self-healing polysaccharide hydrogel based on dynamic covalent enamine bonds10.1002/mame.201600042 ↗
61. Preparation of MWCNTs-graphene-cellulose fiber with ionic liquids10.1021/acssuschemeng.9b05489 ↗
62. Magnetic cellulose–chitosan hydrogels prepared from ionic liquids as reusable adsorbent for removal of heavy metal ions10.1039/c2cc17795a ↗
63. Intrinsically flexible electronic materials for smart device applications10.1039/C6GC00826G ↗
64. Fabrication of mesoporous lignocellulose aerogels from wood via cyclic liquid nitrogen freezing-thawing in ionic liquid solution10.1039/c2jm31310c ↗
65. Preparation and characterization of cellulose/curcumin composite films10.1039/c2ra21465b ↗
66. Liquid crystalline phase behavior and fiber spinning of cellulose/ionic liquid/halloysite nanotubes dispersions10.1039/c4ta00225c ↗
67. Preparation of cellulose hollow fiber membrane from bamboo pulp/1-butyl-3-methylimidazolium chloride/dimethylsulfoxide system10.1021/ie401097d ↗
68. High performance man-made cellulosic fibres from recycled newsprint10.1039/C7GC02896B ↗
69. Upcycling of waste paper and cardboard to textiles10.1039/C5GC01679G ↗
70. High-strength composite fibers from cellulose-lignin blends regenerated from ionic liquid solution10.1002/cssc.201501094 ↗
71. Filament spinning of unbleached birch kraft pulps: effect of pulping intensity on the processability and the fiber properties10.1016/j.carbpol.2017.09.079 ↗
72. Pretreatment of oil palm biomass with ionic liquids: a new approach for fabrication of green composite board10.1016/j.jclepro.2016.02.138 ↗
73. Particulate composites based on ionic liquid-treated oil palm fiber and thermoplastic starch adhesive10.1007/s10098-016-1132-0 ↗
74. Ionic liquids pretreatment for fabrication of agro-residue/thermoplastic starch based composites: a comparative study with other pretreatment technologies10.1016/j.jclepro.2017.05.110 ↗
75. Bionanocomposite fibers based on cellulose and montmorillonite using ionic liquid 1-ethyl-3-methylimidazolium acetate10.1007/s10853-014-8679-0 ↗
76. Preparation of cellulose nanocrystals using an ionic liquid10.1007/s10924-011-0323-3 ↗
77. Strong highly anisotropic magnetocellulose nanocomposite films made by chemical peeling and in situ welding at the interface using an ionic liquid.10.1021/am500709t ↗
78. Ionic liquid stabilized gelatin-lignin films: a potential UV-shielding material with excellent mechanical and antimicrobial properties10.1002/chem.201803763 ↗
79. Flexible and transparent cellulose aerogels with uniform nanoporous structure by a controlled regeneration process10.1021/acssuschemeng.5b01079 ↗
80. Influence of molar mass distribution on the final properties of fibers regenerated from cellulose dissolved in ionic liquid by dry-jet wet spinning10.1016/j.polymer.2015.08.017 ↗
81. Preparation of lignocellulose aerogels from cotton stalks in the ionic liquid-based co-solvent system10.1016/j.indcrop.2018.01.025 ↗
82. Preparation of epoxy resins derived from lignin solubilized in tetrabutylphosphonium hydroxide aqueous solutions10.1016/j.ijbiomac.2019.03.152 ↗
83. Cellulose-based sensor containing phenanthroline for the highly selective and rapid detection of Fe2+ ions with naked eye and fluorescent dual modes10.1021/acsami.7b17342 ↗
84. Visual and precise detection of pH values under extreme acidic and strong basic environments by cellulose-based superior sensor10.1021/acs.analchem.8b05554 ↗
85. Cellulose-based fluorescent sensor for visual and versatile detection of amines and anions10.1016/j.jhazmat.2019.121719 ↗
86. A fundamental understanding of whole biomass dissolution in ionic liquid for regeneration of fiber by solution-spinning10.1039/C9GC00774A ↗
87. Detailed understanding of the DBU/CO2 switchable solvent system for cellulose solubilization and derivatization10.1021/acssuschemeng.7b04053 ↗
88. Synthesis of water-soluble, fully biobased cellulose levulinate esters through the reaction of cellulose and alpha-Angelica lactone in a DBU/CO2/DMSO solvent system10.1039/C9GC03149A ↗
89. Nanoporous magnetic cellulose-chitosan composite microspheres: preparation, characterization, and application for Cu(II) adsorption10.1021/ie402855t ↗
90. Synthesis of novel magnetic cellulose-chitosan composite microspheres and their application in laccase immobilization10.1166/jnn.2014.8933 ↗
91. Extracting wood lignin without dissolving or degrading cellulose: investigations on the use of food additive-derived ionic liquids10.1039/c1gc15671c ↗
92. Self-assembly of cellulose in super-cooled ionic liquid under the impact of decelerated antisolvent infusion: an approach toward anisotropic gels and aerogels10.1021/acs.biomac.8b01278 ↗
93. Lignin oxidation and depolymerisation in ionic liquids10.1039/C5GC01950H ↗
94. Willow lignin oxidation and depolymerization under low cost ionic liquid10.1021/acssuschemeng.6b00642 ↗
95. Ionic liquid as a green solvent for lignin10.1080/02773810701282330 ↗
96. Lignin: a nature-inspired Sun blocker for broad-spectrum sunscreens10.1039/C4GC01333F ↗
97. Lignin valorization: improving lignin processing in the biorefinery10.1126/science.1246843 ↗
98. Dissolution of kraft lignin using Protic Ionic Liquids and characterization10.1016/j.indcrop.2016.02.017 ↗
99. Characterization of physically crosslinked ionic liquid-lignocellulose hydrogels
100. Chemical modifications of lignin for the preparation of macromers containing cyclic carbonates10.1039/C6GC01028H ↗