journal article·2023-08-01Open access

In-situ polymerization of lignocelluloses of autohydrolysis process with acrylamide

Haosong Zhao, Weijue Gao, Pedram Fatehi

Abstract

In the present study, the hydrolysates generated via autohydrolysis of spruce wood chips were directly used as feedstock for producing coagulants. The in-situ polymerization of acrylamide (AM) and lignocellulose (LC) of hydrolysates was successfully conducted. The reaction was optimized to generate lignocellulose-acrylamide (LC-AM) with the highest molecular weight (41,060 g/mol) and charge density (–0.25 meq/g) under the optimum conditions, which were 3 h, 60 ℃, 4% (w) initiator based on the dried mass of hydrolysate, and an AM/LC molar ratio of 5.63. A nuclear magnetic resonance (NMR) spectroscopy confirmed the grafting of acrylamide on LC. Other properties of LC-AM were characterized by the elemental analyzer, zeta potential analyzer, gel permeation chromatography (GPC), and particle charge detector (PCD). The LC-AM was applied as a coagulant for removing ethyl violet dye from a simulated dye solution. The results indicated that 47.2% dye was removed from the solution at a low dosage of 0.2 g/g. The dual flocculation of LC-AM with other polymers for dye removal is suggested to further improve its effectiveness.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Enzyme-mediated dye degradation · Lignin and Wood Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. PolyDADMAC and polyacrylamide as a hybrid flocculation system in the treatment of pulp and paper mills waste water10.1016/j.cej.2011.10.067 ↗
2. Characterization of whole biomasses in pyridine based ionic liquid at low temperature by 31P NMR: an approach to quantitatively measure hydroxyl groups in biomass as their original structures10.3389/fenrg.2018.00013 ↗
3. Effect of dosing method and pH on color removal performance and floc aggregation of polyferric chloride-polyamine dual-coagulant in synthetic dyeing wastewater treatment10.1016/j.colsurfa.2009.12.008 ↗
4. Cationic xylan-(2-methacryloyloxyethyl trimethyl ammonium chloride) polymer as a flocculant for pulping wastewater10.1016/j.carbpol.2018.01.068 ↗
5. Exopolysaccharides produced by Burkholderia cenocepacia recA lineages IIIA and IIIB10.1016/j.jcf.2004.04.004 ↗
6. Enhanced production of xylitol from poplar wood hydrolysates through a sustainable process using immobilized new strain Candida tropicalis UFMG BX 12-a10.1007/s12010-016-2381-4 ↗
7. Grafted copolymerization modification of hemicellulose directly in the alkaline peroxide mechanical pulping (APMP) effluent and its surface sizing effects on corrugated paper10.1021/ie4044423 ↗
8. Performance of different coagulants in the coagulation/flocculation process of textile wastewater10.1016/j.jclepro.2018.10.112 ↗
9. Research on the graft copolymerization of EH-lignin with acrylamide
10. Evaluation of molecular weight, chain architectures and charge densities of various lignin-based flocculants for dye wastewater treatment10.1016/j.chemosphere.2018.10.048 ↗
11. Hydroxypropyl sulfonated kraft lignin as a coagulant for cationic dye10.1016/j.indcrop.2018.07.078 ↗
12. Preparation and characterization of lignin graft copolymer as a filtrate loss control agent for the hydrocarbon drilling industry
13. Graft copolymerization of acrylamide onto oil palm empty fruit bunch (OPEFB) fiber10.1007/s10965-004-1865-z ↗
14. Removal of methylene blue (basic dye) by coagulation-flocculation with biomaterials (bentonite and Opuntia ficus indica)10.1016/j.jwpe.2022.102952 ↗
15. Efficiency of various recent wastewater dye removal methods: a review10.1016/j.jece.2018.06.060 ↗
16. Water soluble kraft lignin-acrylic acid copolymer: synthesis and characterization10.1039/C5GC00228A ↗
17. A review on the modification of polysaccharide through graft copolymerization for various potential applications10.2174/1874104501711010109 ↗
18. Dual starch-polyacrylamide polymer system for improved flocculation10.1016/j.watres.2017.07.044 ↗
19. Synthesis, characterization of a novel lignin-based polymer and its behavior as a coagulant aid in coagulation/ultrafiltration hybrid process10.1016/j.ibiod.2016.02.002 ↗
20. Modification of the water-insoluble hemicelluloses via free radical copolymerization in diluted alkali aqueous medium10.1080/02773813.2016.1271434 ↗
21. Preparation and application of phosphorylated xylan as a flocculant for cationic ethyl violet dye10.3390/polym10030317 ↗
22. Study of the reaction of grafting acrylamide onto xanthan gum10.1016/j.carbpol.2012.05.059 ↗
23. Effect of dye structure on color removal efficiency by coagulation10.1016/j.cej.2020.126674 ↗
24. Application of response surface methodology (RSM) for optimization of cassava starch grafted polyDADMAC synthesis for cationic properties10.1002/star.201200007 ↗
25. Comparison of hemicelluloses isolated from soda cooking black liquor with commercial and bacterial xylan
26. Evaluation of hardwood and softwood fractionation using autohydrolysis and ionic liquid microwave pretreatment10.1016/j.biombioe.2018.07.014 ↗
27. Coagulation-flocculation treatment of high-strength agro-industrial wastewater using natural Cassia obtusifolia seed gum: treatment efficiencies and flocs characterization10.1016/j.cej.2014.06.093 ↗
28. Production of biofuel precursors and value-added chemicals from hydrolysates resulting from hydrothermal processing of biomass: a review10.1016/j.biombioe.2019.105397 ↗
29. Effectiveness of biopolymer coagulants in agricultural wastewater treatment at two contrasting levels of pollution10.1007/s42452-019-0225-x ↗
30. Effect of fermentation conditions on L-lactic acid production from soybean straw hydrolysate10.4014/jmb.1405.05025 ↗
31. Synthesis and characterization of a novel cationic chitosan-based flocculant with a high water-solubility for pulp mill wastewater treatment10.1016/j.watres.2009.08.040 ↗
32. Preparation and characterization of lignin-acrylamide copolymer as a paper strength additive
33. Effect of dosing method on color removal performance and flocculation dynamics of polyferric-organic polymer dual-coagulant in synthetic dyeing solution10.1016/j.cej.2009.02.012 ↗
34. The potential of pre-hydrolysis liquor from the dissolving pulp process as recovery source of xylooligosaccharide: a mini-review10.15376/biores.11.3.Wu ↗
35. Enzymatic hydrolysis lignin (EHL) and its applications for value-added products, a quick review
36. Potato starch as a coagulant for dye removal from textile wastewater10.1007/s11270-015-2499-y ↗
37. Organic/inorganic superabsorbent hydrogels based on xylan and montmorillonite10.1155/2014/675035 ↗
38. Lignin extraction and recovery in hydrothermal pretreatment of bamboo