journal article·2016-07-13Open access

The influence of phthalocyanine aggregation in complexes with CdSe/ZnS quantum dots on the photophysical properties of the complexes

Irina V Martynenko, Anna O Orlova, Vladimir G Maslov, Anatoly V Fedorov, Kevin Berwick, Alexander V Baranov

Abstract

The formation of nonluminescent aggregates of aluminium sulfonated phthalocyanine in complexes with CdSe/ZnS quantum dots causes a decrease of the intracomplex energy transfer efficiency with increasing phthalocyanine concentration. This was confirmed by steady-state absorption and photoluminescent spectroscopy. A corresponding physical model was developed that describes well the experimental data. The results can be used at designing of QD/molecule systems with the desired spatial arrangement for photodynamic therapy.
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Research context

OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Quantum Dots Synthesis And Properties · Photochemistry and Electron Transfer Studies

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