Unlocking the High Rate Performance of Na_0.44MnO₂ with a Boron Doping Strategy

As the cathode material of sodium‐ion battery, sodium manganese oxide has attracted considerable critical attention due to its abundant resources and low cost. However, due to the disproportionation of manganese, sodium manganese oxide often suffers from significant capacity degradation and low rate performance, which hinders its practical application. Here, the electrochemical performance of Na_0.44MnO₂ is significantly improved by an appropriate amount of B doping. The Na_0.44Mn_0.95B_0.05O₂ shows outstanding rate capability and excellent cycle performance, which could deliver a capacity of 61.0 mAh g⁻¹ at 60 C and a capacity retention of 84.7% for 400 cycles at 30 C. B doping could effectively improve the electronic/ionic conductivity of Na_0.44MnO₂, which has been demonstrated.