Na_{3.5}(MnVFeTi)_{0.5}(PO₄)₃: A Multi‐Transition‐Metal‐Ion‐Engineered NASICON‐Type Cathodes for Sodium Ion Batteries

Vaiyapuri Soundharrajan; Ghalib Alfaza; Anindityo Arifiadi; Demelash Feleke; Subramanian Nithiananth; JunJi Piao; Zhiyuan Zeng; Duong Tung Pham; Chunjoong Kim; Jaekook Kim

doi:10.1002/batt.202400526

journal article·2025-03

Na_3.5(MnVFeTi)_0.5(PO₄)₃: A Multi‐Transition‐Metal‐Ion‐Engineered NASICON‐Type Cathodes for Sodium Ion Batteries

Vaiyapuri Soundharrajan, Ghalib Alfaza, Anindityo Arifiadi, Demelash Feleke, Subramanian Nithiananth, JunJi Piao, Zhiyuan Zeng, Duong Tung Pham, Chunjoong Kim, Jaekook Kim

Batteries & Supercaps· Volume 8· Issue 3

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Abstract

Abstract Electrochemically active Na‐superionic conductor (NASICON)‐type cathodes have the structural flexibility to include various transition elements, thus enabling high power outputs benefited by multi‐electron redox reactions. This study amalgamated multiple transition metal ions to construct a new NASICON‐type cathode i. e., carbon coated Na_3.5(MnVFeTi)_0.5(PO₄)₃ (NMVFTP/C) for Na‐ion batteries (NIBs). The NMVFTP/C cathode engineered in this study demonstrated stable Na⁺‐storage capacity, including long‐term cycling stability up to 4000 cycles at 3000 mA g⁻¹ with 96 % capacity retention and a high‐rate output capacity of 85.16 mAh g⁻¹ at 2500 mA g⁻¹. To elucidate the ion transport process within the cathode, density functional theory modeling was employed. The low energy barrier for the diffusion of Na⁺ in the NMVFTP/C materials was proved to be a key factor supporting our material's superior electrochemical performances.

Source: crossref · Quality: baseline

Research context

Energy storage

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Zeolite Catalysis and Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering Chungnam National University Daejeon 34134 Republic of Korea

Department of Materials Science and Engineering Chonnam National University 77 Yongbong-ro, Bukgu Gwangju 61186 Republic of Korea

MEET Battery Research Center Institute of Physical Chemistry Westfalische Wilhelms-Universitat Munster Münster Corrensstraße 46 48149 Germany

Graduate School of Science and Technology Shizuoka University 3-5-1 Johoku, Naka-ku Hamamatsu, Shizuoka 432–8011 Japan

Department of Materials Science and Engineering City University of Hong Kong 83 Tat Chee Avenue Kowloon, Hong Kong 999077 China

School of Engineering Physics Hanoi University of Science and Technology No 1 Dai Co Viet Street 100000 Hanoi Viet Nam.

Research Center for Artificial Intelligence Assisted Ionics Based Materials Development Platform Chonnam National University Gwangju 61186 Republic of Korea

Funding

National Research Foundation of Korea

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