Protein-Based Strategies for Non-Alkali Metal-Ion Batteries
Source abstract
Abstract
Batteries are a cornerstone of modern technology that supports a wide range of applications including portable electronics, electric vehicles and large-scale energy storage for renewable power systems. Despite their widespread use, commercial Li-ion batteries are limited by the mineral resources of Li. The rapidly growing battery market demands alternative battery systems, such as non-alkali metal-ion batteries, that are capable of delivering comparative energy densities. In the meantime, improving the performance of the batteries via generating sustainable strategies has been broadly studied. Proteins, as re naturally evolved macromolecules that possess diverse structures and functional groups, have been demonstrated to be able to transport various metallic ions inside bio-organisms. Therefore, active studies have been carried out on the use of natural proteins (e.g., zein, soy, fibroin, bovine serum albumin, etc.) to enhance the electrochemical performance of non-alkali metal-ion batteries. This review provides a comprehensive summary of recent advances on the studies of protein-based strategies for non-alkali metal-ion batteries and outlines perspectives for future sustainable electrochemical energy storage systems.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced battery technologies research · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Mechanical Engineering, The University of Texas at Dallas, Richardson, TX 75080, USA
School of Mechanical and Materials Engineering, Washington State University, Pullman, WA 99164, USA
Funding
USDA NIFA
References (80)
Show source-provided references
1. The Renewable Energy Role in the Global Energy Transformations10.1016/j.ref.2024.100545 ↗
2. Comprehensive Review of Energy Storage Systems Technologies, Objectives, Challenges, and Future Trends10.1016/j.esr.2024.101482 ↗
3. 30 Years of Lithium-Ion Batteries10.1002/adma.201800561 ↗
4. Open Challenges and Good Experimental Practices in the Research Field of Aqueous Zn-Ion Batteries10.1038/s41467-022-28381-x ↗
5. Rechargeable Zn-Air Batteries: Recent Trends and Future Perspectives10.1016/j.rser.2021.111771 ↗
6. Assessment Methods and Performance Metrics for Redox Flow Batteries10.1038/s41560-020-00772-8 ↗
7. Bio Based Batteries10.1002/aenm.202003713 ↗
8. Zn-Based Batteries for Sustainable Energy Storage: Strategies and Mechanisms10.1039/D3CS00295K ↗
9. Redox Flow Batteries: Status and Perspective towards Sustainable Stationary Energy Storage10.1016/j.jpowsour.2020.228804 ↗
10. Untangling the Respective Effects of Heteroatom-Doped Carbon Materials in Batteries, Supercapacitors and the ORR to Design High Performance Materials10.1039/D1EE00166C ↗
11. Synthesis of β-FeOOH Nanorods Adhered to Pine-Biomass Carbon as a Low-Cost Anode Material for Li-Ion Batteries10.1016/j.jallcom.2019.04.074 ↗
12. Mixed Transition-Metal Oxides: Design, Synthesis, and Energy-Related Applications10.1002/anie.201303971 ↗
13. Cu Ion Induced Morphology Change of Hematite Microspheres as Lithium Ion Battery Anode Material by Solvothermal Synthesis10.1016/j.ceramint.2018.09.222 ↗
14. Incorporating SnO2 Nanodots into Wood Flour-Derived Hierarchically Porous Carbon as Low-Cost Anodes for Superior Lithium Storage10.1016/j.jelechem.2019.113654 ↗
15. Highly Dispersed SnO2 Nanoparticles Confined on Xylem Fiber-Derived Carbon Frameworks as Anodes for Lithium-Ion Batteries10.1016/j.jelechem.2020.114753 ↗
16. Transition Metal Sulfides Based on Graphene for Electrochemical Energy Storage10.1002/aenm.201703259 ↗
17. A Water-Soluble Binary Conductive Binder for Si Anode Lithium Ion Battery10.1016/j.electacta.2019.02.080 ↗
18. Nanostructured Conductive Polymers for Advanced Energy Storage10.1039/C5CS00362H ↗
19. Metal-Organic Frameworks for Batteries10.1016/j.joule.2018.09.019 ↗
20. Metal-Organic Frameworks for Energy Storage Devices: Batteries and Supercapacitors10.1016/j.est.2018.12.025 ↗
21. Natural Protein as Novel Additive of a Commercial Electrolyte for Long-Cycling Lithium Metal Batteries10.1016/j.cej.2022.135283 ↗
22. A Protein-Enabled Protective Film with Functions of Self-Adapting and Anion-Anchoring for Stabilizing Lithium-Metal Batteries10.1016/j.jechem.2021.05.014 ↗
23. Protein-Modified SEI Formation and Evolution in Li Metal Batteries10.1016/j.jechem.2022.06.017 ↗
24. Protein-Engineered Functional Materials10.1002/adhm.201801374 ↗
25. An Amino Acid-Enabled Separator for Effective Stabilization of Li Anodes10.1021/acsami.4c01256 ↗
26. Interface-Tailored Forces Fluffing Protein Fiber Membranes for High-Performance Filtration10.1016/j.seppur.2021.119570 ↗
27. A Robust and Ion-Conductive Protein-Based Binder Enabling Strong Polysulfide Anchoring for High-Energy Lithium-Sulfur Batteries10.1039/C8TA11384J ↗
28. Dual Anchoring Mechanism of Protein-Based Binder for Lithium-Sulfur Batteries10.1021/acs.jpcc.4c03939 ↗
29. Eco-Friendly Soy Protein-Based Solid-State Electrolyte Exhibiting Stable High-Rate Cyclic Performances by Molecular Regulation Design10.1002/aenm.202501056 ↗
30. Effects of Anions and Protein Structures on Protein-Based Solid Electrolytes10.1002/admt.202201875 ↗
31. Soybean Protein Fiber Enabled Controllable Li Deposition and a LiF-Nanocrystal-Enriched Interface for Stable Li Metal Batteries10.1021/acs.nanolett.1c04775 ↗
32. Soy Protein as a Dual-Functional Bridge Enabling High Performance Solid Electrolyte for Li Metal Batteries10.1016/j.jpowsour.2024.235260 ↗
33. Dendrite Suppression Enabled Longevous Sodium Metal Batteries by Sodiophilic Zein/MXene Nanofiber Modulated Polypropylene Separator10.1016/j.ensm.2024.103591 ↗
34. Zein Protein-Functionalized Separator through a Viable Method for Trapping Polysulfides and Regulating Ion Transport in Li-S Batteries10.1016/j.est.2024.113547 ↗
35. Let It Catch: A Short-Branched Protein for Efficiently Capturing Polysulfides in Lithium–Sulfur Batteries10.1002/aenm.201903642 ↗
36. An Ultra-Durable Gel Electrolyte Stabilizing Ion Deposition and Trapping Polysulfides for Lithium-Sulfur Batteries10.1016/j.ensm.2020.01.007 ↗
37. An Interpenetrated Protein-Polar Polymer Interlayer for Suppressing Shuttle Effect in Li-S Batteries10.1016/j.jpowsour.2024.236145 ↗
38. Bovine Serum Albumin Assisted Synthesis of Fe3O4@C@Mn3O4 Multilayer Core-Shell Porous Spheres as Anodes for Lithium Ion Battery10.1016/j.cej.2016.01.106 ↗
39. A Bioinspired Coating for Stabilizing Li Metal Batteries10.1021/acsami.2c10667 ↗
40. Silk Fibroin Separators: A Step Toward Lithium-Ion Batteries with Enhanced Sustainability10.1021/acsami.7b13802 ↗
41. Low-Temperature Carbonized MXene/Protein-Based Eggshell Membrane Composite as Free-Standing Electrode for Flexible Supercapacitors10.1016/j.ijbiomac.2022.12.062 ↗
42. Calcined Chicken Eggshell Electrode for Battery and Supercapacitor Applications10.1039/C9RA04289J ↗
43. Wang, C., and Zhong, W.-H. (2023). Natural Protein-Based Strategies for Batteries, World Scientific.10.1142/13610 ↗
44. Versatile Protein and Its Subunit Biomolecules for Advanced Rechargeable Batteries10.1002/adma.202305063 ↗
45. Promising Sustainable Technology for Energy Storage Devices: Natural Protein-Derived Active Materials10.1016/j.electacta.2023.141860 ↗
46. Biomass-Derived Carbon for High-Performance Batteries: From Structure to Properties10.1002/adfm.202201584 ↗
47. Silk-Derived Highly Active Oxygen Electrocatalysts for Flexible and Rechargeable Zn-Air Batteries10.1021/acs.chemmater.8b04572 ↗
48. In Situ Self-Doped Biomass-Derived Porous Carbon as an Excellent Oxygen Reduction Electrocatalyst for Fuel Cells and Metal-Air Batteries10.1039/D1TA01417J ↗
49. Silk Protein-Derived Carbon Fabric as an Electrode with High Electro-Catalytic Activity for All-Vanadium Redox Flow Batteries10.1016/j.apsusc.2021.150810 ↗
50. Twin-Cocoon-Derived Self-Standing Nitrogen-Oxygen-Rich Monolithic Carbon Material as the Cost-Effective Electrode for Redox Flow Batteries10.1016/j.jpowsour.2019.03.023 ↗
51. Synergistic Catalytic Effects of Oxygen and Nitrogen Functional Groups on Active Carbon Electrodes for All-Vanadium Redox Flow Batteries10.1039/C7RA08334C ↗
52. Corn Protein-Derived Nitrogen-Doped Carbon Materials with Oxygen-Rich Functional Groups: A Highly Efficient Electrocatalyst for All-Vanadium Redox Flow Batteries10.1039/C4EE02123A ↗
53. Vanadium Redox Flow Battery: Review and Perspective of 3D Electrodes10.1021/acsnano.4c06675 ↗
54. Waste Pig Blood-Derived 2D Fe Single-Atom Porous Carbon as an Efficient Electrocatalyst for Zinc–Air Batteries and AEMFCs10.1016/j.apsusc.2021.150208 ↗
55. A Robust Bifunctional Catalyst for Rechargeable Zn-Air Batteries: Ultrathin NiFe-LDH Nanowalls Vertically Anchored on Soybean-Derived Fe-N-C Matrix10.1007/s12274-020-3168-z ↗
56. “simple-Stir” Heterolayered MoS2/Graphene Nanosheets for Zn-Air Batteries10.1021/acsanm.1c01792 ↗
57. Biomolecule-Guided Cation Regulation for Dendrite-Free Metal Anodes10.1126/sciadv.abb1342 ↗
58. In Situ Construction of Protective Films on Zn Metal Anodes via Natural Protein Additives Enabling High-Performance Zinc Ion Batteries10.1021/acsnano.2c05285 ↗
59. Interface Reversible Electric Field Regulated by Amphoteric Charged Protein-Based Coating Toward High-Rate and Robust Zn Anode10.1007/s40820-022-00969-4 ↗
60. Self-Assembled Protein Nanofilm Regulating Uniform Zn Nucleation and Deposition Enabling Long-Life Zn Anodes10.1002/smll.202300895 ↗
61. Protein Interfacial Gelation toward Shuttle-Free and Dendrite-Free Zn–Iodine Batteries10.1002/adma.202404011 ↗
62. Tailoring Localized Electrolyte via a Dual-Functional Protein Membrane toward Stable Zn Anodes10.1021/acsnano.4c02740 ↗
63. Mimicking Ion and Water Management in Poultry Breeding for Highly Reversible Zinc Ion Batteries10.1039/D3EE03045H ↗
64. A Dynamically Assembled Bionic Ion Pump Interface towards High-Rate and Stable-Cycling Zinc Metal Batteries10.1039/D4EE05028B ↗
65. In Situ Buildup of Zinc Anode Protection Films with Natural Protein Additives for High-Performance Zinc Battery Cycling10.1021/acsami.3c06907 ↗
66. Zein Improved GF Separator for Dendrite-Free Aqueous Zinc-Ion Batteries10.1039/D4TA06336H ↗
67. Towards More Sustainable Aqueous Zinc-Ion Batteries10.1002/ange.202403712 ↗
68. Antifreeze Protein Mimics Realizing Stable Low-Temperature-Resistant Aqueous Zn-Ion Batteries with High Water Content10.1002/anie.202505325 ↗
69. Humidity-Sensitive, Shape-Controllable, and Transient Zinc-Ion Batteries Based on Plasticizing Gelatin-Silk Protein Electrolytes10.1016/j.mtener.2021.100712 ↗
70. A Bioinspired Flexible Hydrogel Electrolyte with β-Sheet–Directed Interphase for Dendrite-Free Zn Metal Batteries10.1016/j.ensm.2025.104464 ↗
71. Peptide Gel Electrolytes for Stabilized Zn Metal Anodes10.1021/acsnano.3c04414 ↗
72. Biodegradable Pea Protein Fibril Hydrogel-Based Quasi-Solid-State Zn-Ion Battery10.1021/acsami.3c07749 ↗
73. Superelastic Hydrogel Electrolyte Incorporating Helical Protein Molecules as Zinc Ion Transport Pathways to Enhance the Cycling Stability of Zinc Metal Batteries10.1039/D4EE02510E ↗
74. Biodegradable Electrolyte toward Green Flexible Zinc-Air Batteries10.1021/acssuschemeng.4c05450 ↗
75. De Cachinho Cordeiro, I.M., Li, A., Lin, B., Ma, D.X., Xu, L., Eh, A.L.S., and Wang, W. (2023). Solid Polymer Electrolytes for Zinc-Ion Batteries. Batteries, 9.10.20944/preprints202306.0115.v1 ↗
76. A Protein-Based Ferritin Bio-Nanobattery10.1155/2012/516309 ↗
77. Powering up the Future: Radical Polymers for Battery Applications10.1002/adma.201203119 ↗
78. Stable Organic Radical Polymers: Synthesis and Applications10.1039/C6PY00996D ↗
79. Polypeptide Organic Radical Batteries10.1038/s41586-021-03399-1 ↗
80. Artificial α-Amino Acid Based on Cysteine Grafted Natural Aloe-Emodin for Aqueous Organic Redox Flow Batteries10.1038/s41467-025-58165-y ↗