journal article·2023-06-19Open access

Low-Temperature-Aged Synthesis of CeO2-Coated Li-Rich Oxide as Cathode for Low-Cost High-Energy Density Li-Ion Batteries

Yanlin Liu, Bin Li, Min Chen, Weishan Li

Batteries· Volume 9· Issue 6

Abstract

Co-free Li-rich oxide shows promise as a cathode for low-cost high-energy density Li-ion batteries but presents poor cyclic stability. To address this issue, a novel CeO2-coated Li-rich oxide composite is developed by applying a layer of CeO2 onto Co-free Li-rich oxide through a low-temperature-aged process. With this uniform coating, the resulting composite presents improved cyclic stability as well as rate capability as the cathode of a Li-ion battery. The capacity retention of the resulting composite is increased from 67% to 85% after 100 cycles, and its capacity retention of 5 C/0.05 C is enhanced from 10% to 23% compared with the uncoated sample. Such significant improvements indicate that this low-temperature-aged process is promising for preparing Co-free Li-rich oxides as cathodes of low-cost high-energy density Li-ion batteries.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Automobile and Transportation Engineering, Guangdong Polytechnic Normal University, Guangzhou 510450, China

National and Local Joint Engineering Research Center of MPTES in High Energy and Safety LIBs, Engineering Research Center of MTEES (Ministry of Education), Key Laboratory of ETESPG (GHEI), South China Normal University, Guangzhou 510006, China

School of Material and Energy, Guangdong University of Technology, Guangzhou 510006, China

School of Chemistry, South China Normal University, Guangzhou 510006, China

Funding

National Natural Science Foundation of China · Department of Education of Guangdong Province

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