A Nickel-Based Coordination Compound with Tunable Morphology for High-Performance Anode and the Lithium Storage Mechanism
Source abstract
Abstract
Metal-organic coordination compounds (MCCs) have received a lot of attention as anodes for lithium-ion batteries (LIBs) due to their abundant structural configuration, tunable morphology, high surface area, and low cost, but the lithium storage mechanism of MCCs is still a mystery. Herein, we synthesized a kind of nickel-based coordination compound (marked as Ni-PP-x, x = 1, 2, or 3) with tunable morphologies and different solvent ratios via a microwave irradiation solvothermal method and then applied them as anodes for LIBs. Among them, the Ni-PP-2 electrode, with a hollow and urchin-like structure, showed the longest lifespan and maintained a high capacity of 713 mAh g−1 at 2.0 A g−1 after 800 cycles. Measured by ex situ X-ray photoelectron spectroscopy (XPS) and ex situ Fourier transform infrared spectroscopy (FT-IR), the Ni-PP-2 electrode was confirmed by a redox reaction mechanism of Li+ cations with a benzene ring and O-Ni2+/O-Ni0 coordination bonds, and the cyclic voltammetry curves have exhibited a capacitive dominated lithium storage behavior. This work provides a new type of Ni-based coordination compound and an in-depth understanding of their lithium storage mechanism, paving the way for the application of MCC compounds in the future.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, Shangda Road 99, Shanghai 200444, China
Funding
Shanghai Municipal Education Commission：Innovation Program · National Natural Science Foundation of China
References (49)
Show source-provided references
1. Stabilizing oxygen by high-valance element doping for high-performance Li-rich layered oxides10.1002/bte2.20220030 ↗
2. A General Route for Encapsulating Monodispersed Transition Metal Phosphides into Carbon Multi-Chambers toward High-Efficient Lithium-Ion Storage with Underlying Mechanism Exploration10.1002/adfm.202212100 ↗
3. Recent advances of silicon, carbon composites and tin oxide as new anode materials for lithium-ion battery: A comprehensive review10.1016/j.est.2020.102096 ↗
4. Nanostructured anatase TiO2 as anode of high-performance lithium-ion batteries10.1002/bte2.20220018 ↗
5. Low-dimensional nanomaterial/Si heterostructure-based photodetectors10.1002/inf2.12014 ↗
6. Mechanistic insights into nanoparticle formation from bimetallic metal-organic frameworks10.1021/jacs.1c04269 ↗
7. A redox-active 2D metal-organic framework for efficient lithium storage with extraordinary high capacity10.1002/anie.201914395 ↗
8. Ultrathin manganese-based metal-organic framework nanosheets: Low-cost and energy-dense lithium storage anodes with the coexistence of metal and ligand redox activities10.1021/acsami.7b09363 ↗
9. A thermally activated manganese 1,4-benzenedicarboxylate metal organic framework with high anodic capability for Li-ion batteries10.1039/C6NJ02179D ↗
10. Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn4O(1,3,5-benzenetribenzoate)210.1016/j.jpowsour.2006.01.015 ↗
11. Lithium storage in a metal organic framework with diamondoid topology—A case study on metal formates10.1039/c0jm01671c ↗
12. Lead-Based Metal-Organic Framework with Stable Lithium Anodic Performance10.1021/acs.inorgchem.6b02663 ↗
13. Reversible Lithium Storage in Manganese 1,3,5-Benzenetricarboxylate Metal-Organic Framework with High Capacity and Rate Performance10.1021/acsami.5b03414 ↗
14. Design and Synthesis of Heterometallic Ni–Co Organic Frameworks as Anode Materials for High-Performance Lithium Storage10.1149/1945-7111/ac5ad6 ↗
15. A novel crystalline nanoporous iron phosphonate based metal-organic framework as an efficient anode material for lithium ion batteries10.1039/D1NJ02841C ↗
16. Controllable synthesis of a flower-like superstructure of nickel metal-organic phosphate and its derivatives for supercapacitors10.1016/j.apmt.2021.101048 ↗
17. Preparation, characterizaton, and catalytic aerobic oxidation by a vanadium phosphonate mesoporous material constructed from a dendritic tetraphosphonate10.1021/cm0603506 ↗
18. Hydrothermal synthesis, structural elucidation and electrochemical properties of three nickel and cobalt based phosphonates as anode materials for lithium ion batteries10.1016/j.electacta.2019.134647 ↗
19. How carbon coating or continuous carbon pitch matrix influence the silicon electrode/electrolyte interfaces and the performance in Li-ion batteries10.1002/bte2.20210009 ↗
20. Significantly fastened redox kinetics in single crystal layered oxide cathode by gradient doping10.1016/j.nanoen.2022.106961 ↗
21. N doped FeP nanospheres decorated carbon matrix as an efficient electrocatalyst for durable lithium-sulfur batteries10.1016/j.jcis.2022.09.126 ↗
22. Co3Se4 quantum dots as an ultrastable host material for potassium-ion intercalation10.1002/adma.202102164 ↗
23. Mesoporous manganese phosphonate nanorods as a prospective anode for lithium-ion batteries10.1021/acsami.8b05292 ↗
24. High-valence-state nickel-iron phosphonates with urchin-like hierarchical architecture for highly efficient oxygen evolution reaction10.1016/j.jallcom.2021.158614 ↗
25. One-step ultrasonic synthesis of Co/Ni-catecholates for improved performance in oxygen reduction reaction10.1016/j.ultsonch.2020.105179 ↗
26. One-pot synthesis of Co-based coordination polymer nanowire for Li-ion batteries with great capacity and stable cycling stability10.1007/s40820-017-0177-x ↗
27. A brand-new bimetallic copper-lithium HEDP complex of fast ion migration as a promising anode for lithium ion batteries10.1016/j.molstruc.2020.128223 ↗
28. Synthesis of mesostructured manganese phosphonate and its promising energy storage application10.1039/C7TA07034A ↗
29. An enabling strategy for ultra-fast lithium storage derived from micro-flower-structured NiX (X = O, S, Se)10.1016/j.electacta.2020.136138 ↗
30. High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework10.1038/ncomms6261 ↗
31. A kind of Co-based coordination compounds with tunable morphologies and its Li-storage mechanism10.1016/j.electacta.2022.140565 ↗
32. A flexible ligand-based wavy layered metal-organic framework for lithium-ion storage10.1016/j.jcis.2015.01.012 ↗
33. Construction of 1D conductive Ni-MOF nanorods with fast Li+ kinetic diffusion and stable high-rate capacities as an anode for lithium ion batteries10.1039/C9NA00616H ↗
34. Directly anchoring 2D NiCo metal-organic frameworks on few-layer black phosphorus for advanced lithium-ion batteries10.1039/C8TA09327J ↗
35. Synthesis of tostadas-shaped metal-organic frameworks for remitting capacity fading of Li-ion batteries10.1002/adfm.202109927 ↗
36. Three-dimensional MXene-encapsulated porous Ni-NDC nanosheets as anodes for enhanced lithium-ion batteries10.1007/s12274-022-5168-7 ↗
37. Cobalt- and cadmium-based metal-organic frameworks as high-performance anodes for sodium ion batteries and lithium ion batteries10.1021/acsami.6b15757 ↗
38. Electrolyte additive enabled fast charging and stable cycling lithium metal batteries10.1038/nenergy.2017.12 ↗
39. A coordination chemistry approach for lithium-ion batteries: The coexistence of metal and ligand redox activities in a one-dimensional metal-organic Material10.1021/acs.inorgchem.6b00450 ↗
40. Hierarchical cobalt-based metal-organic framework for high-performance lithium-Ion batteries10.1002/chem.201802629 ↗
41. Oxygen vacancies and N-doping in organic-inorganic pre-intercalated vanadium oxide for high-performance aqueous zinc-ion batteries10.1002/inf2.12346 ↗
42. Delicate synthesis of quasi-inverse opal structural Na3V2(PO4)3/N-C and Na4MnV(PO4)3/N-C as cathode for high-rate sodium-ion batteries10.1007/s12598-021-01900-3 ↗
43. Interfacial adsorption–insertion mechanism induced by phase boundary toward better aqueous Zn-ion battery10.1002/inf2.12223 ↗
44. High performance columnar-like Fe2O3@carbon composite anode via yolk@ shell structural design10.1016/j.jechem.2019.05.009 ↗
45. 3D hollow porous carbon microspheres derived from Mn-MOFs and their electrochemical behavior for sodium storage10.1039/C7TA08352A ↗
46. N-rich carbon-coated Co3S4 ultrafine nanocrystals derived from ZIF-67 as an advanced anode for sodium-ion batteries10.1039/C8NR05652H ↗
47. In-situ structural evolution analysis of Zr-doped Na3V2(PO4)2F3 coated by N-doped carbon layer as high-performance cathode for sodium-ion batteries10.1016/j.jechem.2021.06.015 ↗
48. Optimizing ultramicroporous hard carbon spheres in carbonate ester-based electrolytes for enhanced sodium storage in half-/full-cell sodium-ion batteries10.1002/bte2.20220007 ↗
49. Ultrafast Charge-Discharge Capable and Long-Life Na3.9Mn0.95Zr0.05V(PO4)3/C Cathode Material for Advanced Sodium-Ion Batteries10.1002/smll.202206987 ↗